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Mn-salen@MIL101(Al): a heterogeneous, enantioselective catalyst synthesized using a 'bottle around the ship' approach

(2013) CHEMICAL COMMUNICATIONS. 49(73). p.8021-8023
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Organization
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ERC grant agreement no.\240483
Project
UGent GOA grant 01G00710
Abstract
An enantioselective catalyst, consisting of a chiral Mn(III) salen complex entrapped in the MIL-101 metal organic framework, is reported. For the first time, we assemble a robust MOF-cage around a chiral complex. The heterogeneous catalyst shows the same selectivity as the homogeneous complex and is fully recyclable. Theoretical calculations provide insight into this retention of selectivity.
Keywords
OLEFINS, COMPLEXES, ASYMMETRIC EPOXIDATION, ALKENE EPOXIDATION

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Citation

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Chicago
Bogaerts, Thomas, Andy Van Yperen-De Deyne, Ying-Ya Liu, Frederic Lynen, Veronique Van Speybroeck, and Pascal Van Der Voort. 2013. “Mn-salen@MIL101(Al): a Heterogeneous, Enantioselective Catalyst Synthesized Using a ‘Bottle Around the Ship’ Approach.” Chemical Communications 49 (73): 8021–8023.
APA
Bogaerts, Thomas, Van Yperen-De Deyne, A., Liu, Y.-Y., Lynen, F., Van Speybroeck, V., & Van Der Voort, P. (2013). Mn-salen@MIL101(Al): a heterogeneous, enantioselective catalyst synthesized using a “bottle around the ship” approach. CHEMICAL COMMUNICATIONS, 49(73), 8021–8023.
Vancouver
1.
Bogaerts T, Van Yperen-De Deyne A, Liu Y-Y, Lynen F, Van Speybroeck V, Van Der Voort P. Mn-salen@MIL101(Al): a heterogeneous, enantioselective catalyst synthesized using a “bottle around the ship” approach. CHEMICAL COMMUNICATIONS. 2013;49(73):8021–3.
MLA
Bogaerts, Thomas, Andy Van Yperen-De Deyne, Ying-Ya Liu, et al. “Mn-salen@MIL101(Al): a Heterogeneous, Enantioselective Catalyst Synthesized Using a ‘Bottle Around the Ship’ Approach.” CHEMICAL COMMUNICATIONS 49.73 (2013): 8021–8023. Print.
@article{4131031,
  abstract     = {An enantioselective catalyst, consisting of a chiral Mn(III) salen complex entrapped in the MIL-101 metal organic framework, is reported. For the first time, we assemble a robust MOF-cage around a chiral complex. The heterogeneous catalyst shows the same selectivity as the homogeneous complex and is fully recyclable. Theoretical calculations provide insight into this retention of selectivity.},
  author       = {Bogaerts, Thomas and Van Yperen-De Deyne, Andy and Liu, Ying-Ya and Lynen, Frederic and Van Speybroeck, Veronique and Van Der Voort, Pascal},
  issn         = {1359-7345},
  journal      = {CHEMICAL COMMUNICATIONS},
  language     = {eng},
  number       = {73},
  pages        = {8021--8023},
  title        = {Mn-salen@MIL101(Al): a heterogeneous, enantioselective catalyst synthesized using a 'bottle around the ship' approach},
  url          = {http://dx.doi.org/10.1039/c3cc44473b},
  volume       = {49},
  year         = {2013},
}

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