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Mn-salen@MIL101(Al): a heterogeneous, enantioselective catalyst synthesized using a 'bottle around the ship' approach

Thomas Bogaerts, Andy Van Yperen-De Deyne, Ying-Ya Liu UGent, Frederic Lynen UGent, Veronique Van Speybroeck UGent and Pascal Van Der Voort UGent (2013) CHEMICAL COMMUNICATIONS. 49(73). p.8021-8023
abstract
An enantioselective catalyst, consisting of a chiral Mn(III) salen complex entrapped in the MIL-101 metal organic framework, is reported. For the first time, we assemble a robust MOF-cage around a chiral complex. The heterogeneous catalyst shows the same selectivity as the homogeneous complex and is fully recyclable. Theoretical calculations provide insight into this retention of selectivity.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
OLEFINS, COMPLEXES, ASYMMETRIC EPOXIDATION, ALKENE EPOXIDATION
journal title
CHEMICAL COMMUNICATIONS
Chem. Commun.
volume
49
issue
73
pages
8021 - 8023
Web of Science type
Article
Web of Science id
000323195600010
JCR category
CHEMISTRY, MULTIDISCIPLINARY
JCR impact factor
6.718 (2013)
JCR rank
20/148 (2013)
JCR quartile
1 (2013)
ISSN
1359-7345
DOI
10.1039/c3cc44473b
project
ERC grant agreement no.\240483
project
UGent GOA grant 01G00710
language
English
UGent publication?
yes
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
4131031
handle
http://hdl.handle.net/1854/LU-4131031
date created
2013-09-12 12:14:42
date last changed
2016-12-19 15:46:04
@article{4131031,
  abstract     = {An enantioselective catalyst, consisting of a chiral Mn(III) salen complex entrapped in the MIL-101 metal organic framework, is reported. For the first time, we assemble a robust MOF-cage around a chiral complex. The heterogeneous catalyst shows the same selectivity as the homogeneous complex and is fully recyclable. Theoretical calculations provide insight into this retention of selectivity.},
  author       = {Bogaerts, Thomas and Van Yperen-De Deyne, Andy and Liu, Ying-Ya and Lynen, Frederic and Van Speybroeck, Veronique and Van Der Voort, Pascal},
  issn         = {1359-7345},
  journal      = {CHEMICAL COMMUNICATIONS},
  keyword      = {OLEFINS,COMPLEXES,ASYMMETRIC EPOXIDATION,ALKENE EPOXIDATION},
  language     = {eng},
  number       = {73},
  pages        = {8021--8023},
  title        = {Mn-salen@MIL101(Al): a heterogeneous, enantioselective catalyst synthesized using a 'bottle around the ship' approach},
  url          = {http://dx.doi.org/10.1039/c3cc44473b},
  volume       = {49},
  year         = {2013},
}

Chicago
Bogaerts, Thomas, Andy Van Yperen-De Deyne, Ying-Ya Liu, Frederic Lynen, Veronique Van Speybroeck, and Pascal Van Der Voort. 2013. “Mn-salen@MIL101(Al): a Heterogeneous, Enantioselective Catalyst Synthesized Using a ‘Bottle Around the Ship’ Approach.” Chemical Communications 49 (73): 8021–8023.
APA
Bogaerts, Thomas, Van Yperen-De Deyne, A., Liu, Y.-Y., Lynen, F., Van Speybroeck, V., & Van Der Voort, P. (2013). Mn-salen@MIL101(Al): a heterogeneous, enantioselective catalyst synthesized using a “bottle around the ship” approach. CHEMICAL COMMUNICATIONS, 49(73), 8021–8023.
Vancouver
1.
Bogaerts T, Van Yperen-De Deyne A, Liu Y-Y, Lynen F, Van Speybroeck V, Van Der Voort P. Mn-salen@MIL101(Al): a heterogeneous, enantioselective catalyst synthesized using a “bottle around the ship” approach. CHEMICAL COMMUNICATIONS. 2013;49(73):8021–3.
MLA
Bogaerts, Thomas, Andy Van Yperen-De Deyne, Ying-Ya Liu, et al. “Mn-salen@MIL101(Al): a Heterogeneous, Enantioselective Catalyst Synthesized Using a ‘Bottle Around the Ship’ Approach.” CHEMICAL COMMUNICATIONS 49.73 (2013): 8021–8023. Print.