N-Heterocyclic carbene transition metal complexes for catalysis in aqueous media
- Author
- Heriberto Díaz Velázquez (UGent) and Francis Verpoort (UGent)
- Organization
- Abstract
- Last decade has seen an increasing number of reports on the use of NHC-metal complexes for catalysis in water, therefore this review is aimed to introduce the whole research on this area, in which the use of water or aqueous/organic media is to be applied. Since the first discover of the NHC carbenes by Arduengo, work on the synthesis of NHC-metal organometallic compounds have revolutionized the field of catalysis, gradually displacing the typical phosphine and amine-type ligands in view of their higher stability and reactivity. Aqueous catalysis has become a hot topic in Green Chemistry due to the positive implications in the use of water as reaction media.
- Keywords
- RUTHENIUM ALKYLIDENE, RING-CLOSING METATHESIS, PALLADIUM COMPLEX, ASYMMETRIC CATALYSIS, EFFICIENT CATALYSTS, ROOM-TEMPERATURE, PALLADIUM/IMIDAZOLIUM SALT SYSTEMS, OPENING METATHESIS POLYMERIZATION, MIYAURA COUPLING REACTION, OLEFIN-METATHESIS, NHC-Metal complexes, water-soluble organometallic catalysts, Catalysis
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Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-4119563
- MLA
- Díaz Velázquez, Heriberto, and Francis Verpoort. “N-Heterocyclic Carbene Transition Metal Complexes for Catalysis in Aqueous Media.” CHEMICAL SOCIETY REVIEWS, vol. 41, no. 21, 2012, pp. 7032–60.
- APA
- Díaz Velázquez, H., & Verpoort, F. (2012). N-Heterocyclic carbene transition metal complexes for catalysis in aqueous media. CHEMICAL SOCIETY REVIEWS, 41(21), 7032–7060.
- Chicago author-date
- Díaz Velázquez, Heriberto, and Francis Verpoort. 2012. “N-Heterocyclic Carbene Transition Metal Complexes for Catalysis in Aqueous Media.” CHEMICAL SOCIETY REVIEWS 41 (21): 7032–60.
- Chicago author-date (all authors)
- Díaz Velázquez, Heriberto, and Francis Verpoort. 2012. “N-Heterocyclic Carbene Transition Metal Complexes for Catalysis in Aqueous Media.” CHEMICAL SOCIETY REVIEWS 41 (21): 7032–7060.
- Vancouver
- 1.Díaz Velázquez H, Verpoort F. N-Heterocyclic carbene transition metal complexes for catalysis in aqueous media. CHEMICAL SOCIETY REVIEWS. 2012;41(21):7032–60.
- IEEE
- [1]H. Díaz Velázquez and F. Verpoort, “N-Heterocyclic carbene transition metal complexes for catalysis in aqueous media,” CHEMICAL SOCIETY REVIEWS, vol. 41, no. 21, pp. 7032–7060, 2012.
@article{4119563,
abstract = {Last decade has seen an increasing number of reports on the use of NHC-metal complexes for catalysis in water, therefore this review is aimed to introduce the whole research on this area, in which the use of water or aqueous/organic media is to be applied. Since the first discover of the NHC carbenes by Arduengo, work on the synthesis of NHC-metal organometallic compounds have revolutionized the field of catalysis, gradually displacing the typical phosphine and amine-type ligands in view of their higher stability and reactivity. Aqueous catalysis has become a hot topic in Green Chemistry due to the positive implications in the use of water as reaction media.},
author = {Díaz Velázquez, Heriberto and Verpoort, Francis},
issn = {0306-0012},
journal = {CHEMICAL SOCIETY REVIEWS},
keywords = {RUTHENIUM ALKYLIDENE,RING-CLOSING METATHESIS,PALLADIUM COMPLEX,ASYMMETRIC CATALYSIS,EFFICIENT CATALYSTS,ROOM-TEMPERATURE,PALLADIUM/IMIDAZOLIUM SALT SYSTEMS,OPENING METATHESIS POLYMERIZATION,MIYAURA COUPLING REACTION,OLEFIN-METATHESIS,NHC-Metal complexes,water-soluble organometallic catalysts,Catalysis},
language = {eng},
number = {21},
pages = {7032--7060},
title = {N-Heterocyclic carbene transition metal complexes for catalysis in aqueous media},
url = {http://dx.doi.org/10.1039/C2CS35102A},
volume = {41},
year = {2012},
}
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