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N-Heterocyclic carbene transition metal complexes for catalysis in aqueous media

(2012) CHEMICAL SOCIETY REVIEWS. 41(21). p.7032-7060
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Organization
Abstract
Last decade has seen an increasing number of reports on the use of NHC-metal complexes for catalysis in water, therefore this review is aimed to introduce the whole research on this area, in which the use of water or aqueous/organic media is to be applied. Since the first discover of the NHC carbenes by Arduengo, work on the synthesis of NHC-metal organometallic compounds have revolutionized the field of catalysis, gradually displacing the typical phosphine and amine-type ligands in view of their higher stability and reactivity. Aqueous catalysis has become a hot topic in Green Chemistry due to the positive implications in the use of water as reaction media.
Keywords
RUTHENIUM ALKYLIDENE, RING-CLOSING METATHESIS, PALLADIUM COMPLEX, ASYMMETRIC CATALYSIS, EFFICIENT CATALYSTS, ROOM-TEMPERATURE, PALLADIUM/IMIDAZOLIUM SALT SYSTEMS, OPENING METATHESIS POLYMERIZATION, MIYAURA COUPLING REACTION, OLEFIN-METATHESIS, NHC-Metal complexes, water-soluble organometallic catalysts, Catalysis

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Citation

Please use this url to cite or link to this publication:

MLA
Díaz Velázquez, Heriberto, and Francis Verpoort. “N-Heterocyclic Carbene Transition Metal Complexes for Catalysis in Aqueous Media.” CHEMICAL SOCIETY REVIEWS, vol. 41, no. 21, 2012, pp. 7032–60.
APA
Díaz Velázquez, H., & Verpoort, F. (2012). N-Heterocyclic carbene transition metal complexes for catalysis in aqueous media. CHEMICAL SOCIETY REVIEWS, 41(21), 7032–7060.
Chicago author-date
Díaz Velázquez, Heriberto, and Francis Verpoort. 2012. “N-Heterocyclic Carbene Transition Metal Complexes for Catalysis in Aqueous Media.” CHEMICAL SOCIETY REVIEWS 41 (21): 7032–60.
Chicago author-date (all authors)
Díaz Velázquez, Heriberto, and Francis Verpoort. 2012. “N-Heterocyclic Carbene Transition Metal Complexes for Catalysis in Aqueous Media.” CHEMICAL SOCIETY REVIEWS 41 (21): 7032–7060.
Vancouver
1.
Díaz Velázquez H, Verpoort F. N-Heterocyclic carbene transition metal complexes for catalysis in aqueous media. CHEMICAL SOCIETY REVIEWS. 2012;41(21):7032–60.
IEEE
[1]
H. Díaz Velázquez and F. Verpoort, “N-Heterocyclic carbene transition metal complexes for catalysis in aqueous media,” CHEMICAL SOCIETY REVIEWS, vol. 41, no. 21, pp. 7032–7060, 2012.
@article{4119563,
  abstract     = {Last decade has seen an increasing number of reports on the use of NHC-metal complexes for catalysis in water, therefore this review is aimed to introduce the whole research on this area, in which the use of water or aqueous/organic media is to be applied. Since the first discover of the NHC carbenes by Arduengo, work on the synthesis of NHC-metal organometallic compounds have revolutionized the field of catalysis, gradually displacing the typical phosphine and amine-type ligands in view of their higher stability and reactivity. Aqueous catalysis has become a hot topic in Green Chemistry due to the positive implications in the use of water as reaction media.},
  author       = {Díaz Velázquez, Heriberto and Verpoort, Francis},
  issn         = {0306-0012},
  journal      = {CHEMICAL SOCIETY REVIEWS},
  keywords     = {RUTHENIUM ALKYLIDENE,RING-CLOSING METATHESIS,PALLADIUM COMPLEX,ASYMMETRIC CATALYSIS,EFFICIENT CATALYSTS,ROOM-TEMPERATURE,PALLADIUM/IMIDAZOLIUM SALT SYSTEMS,OPENING METATHESIS POLYMERIZATION,MIYAURA COUPLING REACTION,OLEFIN-METATHESIS,NHC-Metal complexes,water-soluble organometallic catalysts,Catalysis},
  language     = {eng},
  number       = {21},
  pages        = {7032--7060},
  title        = {N-Heterocyclic carbene transition metal complexes for catalysis in aqueous media},
  url          = {http://dx.doi.org/10.1039/C2CS35102A},
  volume       = {41},
  year         = {2012},
}

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