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An efficient synthesis of γ-imino- and γ-amino-β-enamino esters

(2006) ARKIVOC. p.202-209
Author
Organization
Abstract
Condensation of ethyl 3-azido-4-oxopentanoate, easily accessible from ethyl 3-chloro-4-oxopentanoate, with primary amines was found to produce ethyl 4-imino-3-amino-2-pentenoates. In addition, ethyl 4-imino-3-amino-2-pentenoates were reduced chemoselectively to the corresponding ethyl 4-alkylamino-3-amino-2-pentenoates upon hydrogenation.
Keywords
functionalized enamino esters, 1-aza-1, 3-butadienes, gamma-amino esters, functionalized ketimines, ALPHA-AZIDO KETONES, HETEROCYCLIC SYNTHESIS, DECOMPOSITION, NITROGEN

Citation

Please use this url to cite or link to this publication:

MLA
Mangelinckx, Sven, Pieter Van Vooren, David De Clerck, et al. “An Efficient Synthesis of Γ-imino- and Γ-amino-β-enamino Esters.” ARKIVOC 3 (2006): 202–209. Print.
APA
Mangelinckx, S., Van Vooren, P., De Clerck, D., Fülöp, F., & De Kimpe, N. (2006). An efficient synthesis of γ-imino- and γ-amino-β-enamino esters. ARKIVOC, (3), 202–209.
Chicago author-date
Mangelinckx, Sven, Pieter Van Vooren, David De Clerck, Ferenc Fülöp, and Norbert De Kimpe. 2006. “An Efficient Synthesis of Γ-imino- and Γ-amino-β-enamino Esters.” Arkivoc (3): 202–209.
Chicago author-date (all authors)
Mangelinckx, Sven, Pieter Van Vooren, David De Clerck, Ferenc Fülöp, and Norbert De Kimpe. 2006. “An Efficient Synthesis of Γ-imino- and Γ-amino-β-enamino Esters.” Arkivoc (3): 202–209.
Vancouver
1.
Mangelinckx S, Van Vooren P, De Clerck D, Fülöp F, De Kimpe N. An efficient synthesis of γ-imino- and γ-amino-β-enamino esters. ARKIVOC. 2006;(3):202–9.
IEEE
[1]
S. Mangelinckx, P. Van Vooren, D. De Clerck, F. Fülöp, and N. De Kimpe, “An efficient synthesis of γ-imino- and γ-amino-β-enamino esters,” ARKIVOC, no. 3, pp. 202–209, 2006.
@article{367800,
  abstract     = {Condensation of ethyl 3-azido-4-oxopentanoate, easily accessible from ethyl 3-chloro-4-oxopentanoate, with primary amines was found to produce ethyl 4-imino-3-amino-2-pentenoates. In addition, ethyl 4-imino-3-amino-2-pentenoates were reduced chemoselectively to the corresponding ethyl 4-alkylamino-3-amino-2-pentenoates upon hydrogenation.},
  author       = {Mangelinckx, Sven and Van Vooren, Pieter and De Clerck, David and Fülöp, Ferenc and De Kimpe, Norbert},
  issn         = {1551-7004},
  journal      = {ARKIVOC},
  keywords     = {functionalized enamino esters,1-aza-1,3-butadienes,gamma-amino esters,functionalized ketimines,ALPHA-AZIDO KETONES,HETEROCYCLIC SYNTHESIS,DECOMPOSITION,NITROGEN},
  language     = {eng},
  number       = {3},
  pages        = {202--209},
  title        = {An efficient synthesis of γ-imino- and γ-amino-β-enamino esters},
  url          = {http://dx.doi.org/10.3998/ark.5550190.0007.316},
  year         = {2006},
}

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