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Modelling of the reaction-phase interaction of γ-aminopropyltriethoxysilane with silica

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Abstract
The coating formed in the reaction phase of the modification of silica with gamma-aminopropyltriethoxysilane was modelled using the freeze sampling method with a classical N-determination. The formation of a monolayer coating in the reaction phase is confirmed. Within the selected region of silane : silica ratio, the monolayer capacity value was determined to be 1.02 mmol g-1 on dehydrated silica gel and 0.63 mmol g-1 on the dehydroxylated substrate. The obtained monolayer structure is described and related to the specific surface area of the substrate used. APTS molecules are distributed over the silica surface with each molecule covering 64 angstrom2.
Keywords
IMMOBILIZATION, 3-AMINOPROPYL TRIETHOXY SILANE, SURFACES

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MLA
Vrancken, Karl C., et al. “Modelling of the Reaction-Phase Interaction of γ-Aminopropyltriethoxysilane with Silica.” JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, vol. 89, no. 12, 1993, pp. 2037–40, doi:10.1039/ft9938902037.
APA
Vrancken, K. C., Casteleyn, E., Possemiers, K., Van Der Voort, P., & Vansant, E. F. (1993). Modelling of the reaction-phase interaction of γ-aminopropyltriethoxysilane with silica. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 89(12), 2037–2040. https://doi.org/10.1039/ft9938902037
Chicago author-date
Vrancken, Karl C, Eddy Casteleyn, Karl Possemiers, Pascal Van Der Voort, and Etienne F Vansant. 1993. “Modelling of the Reaction-Phase Interaction of γ-Aminopropyltriethoxysilane with Silica.” JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS 89 (12): 2037–40. https://doi.org/10.1039/ft9938902037.
Chicago author-date (all authors)
Vrancken, Karl C, Eddy Casteleyn, Karl Possemiers, Pascal Van Der Voort, and Etienne F Vansant. 1993. “Modelling of the Reaction-Phase Interaction of γ-Aminopropyltriethoxysilane with Silica.” JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS 89 (12): 2037–2040. doi:10.1039/ft9938902037.
Vancouver
1.
Vrancken KC, Casteleyn E, Possemiers K, Van Der Voort P, Vansant EF. Modelling of the reaction-phase interaction of γ-aminopropyltriethoxysilane with silica. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS. 1993;89(12):2037–40.
IEEE
[1]
K. C. Vrancken, E. Casteleyn, K. Possemiers, P. Van Der Voort, and E. F. Vansant, “Modelling of the reaction-phase interaction of γ-aminopropyltriethoxysilane with silica,” JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, vol. 89, no. 12, pp. 2037–2040, 1993.
@article{364935,
  abstract     = {{The coating formed in the reaction phase of the modification of silica with gamma-aminopropyltriethoxysilane was modelled using the freeze sampling method with a classical N-determination. The formation of a monolayer coating in the reaction phase is confirmed. Within the selected region of silane : silica ratio, the monolayer capacity value was determined to be 1.02 mmol g-1 on dehydrated silica gel and 0.63 mmol g-1 on the dehydroxylated substrate. The obtained monolayer structure is described and related to the specific surface area of the substrate used. APTS molecules are distributed over the silica surface with each molecule covering 64 angstrom2.}},
  author       = {{Vrancken, Karl C and Casteleyn, Eddy and Possemiers, Karl and Van Der Voort, Pascal and Vansant, Etienne F}},
  issn         = {{0956-5000}},
  journal      = {{JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS}},
  keywords     = {{IMMOBILIZATION,3-AMINOPROPYL TRIETHOXY SILANE,SURFACES}},
  language     = {{eng}},
  number       = {{12}},
  pages        = {{2037--2040}},
  title        = {{Modelling of the reaction-phase interaction of γ-aminopropyltriethoxysilane with silica}},
  url          = {{http://doi.org/10.1039/ft9938902037}},
  volume       = {{89}},
  year         = {{1993}},
}

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