Academic Bibliography

 Search 200 years of publications by Ghent University researchers.
Advanced search
1 file | 150.52 KB
Add to list
  1. Search results
  2. Preparation of star block co-polymers...

Preparation of star block co-polymers by combination of cationic ring opening polymerization and atom transfer radical polymerization

T Erdogan, Katrien Bernaerts (UGent) , Lieven Van Renterghem, Filip Du Prez (UGent) and Eric Goethals (UGent)
(2005) DESIGNED MONOMERS AND POLYMERS. 8(6). p.705-714
Author
Organization
Abstract
The synthesis of star block co-polymers with polytetrahydrofuran (PTHF) core and poly(tert-butyl acrylate) (PtBA) shell was performed using a dual initiator, 4-hydroxy butyl bromoisobutyrate, by combination of cationic ring-opening polymerization (CROP) and atom transfer radical polymerization (ATRP). The in situ reaction of the hydroxyl groups originating from the dual initiator with trifluoromethane sulfonic anhydride provides a triflate ester initiating group for the CROP of THF PTHF star polymers having three arms with tertiary bromide end groups (PTHF)(3) have been prepared by reaction of living PTHF chains with tris(2-aminoethyl)amine (TAEA) in the presence of 2,2,6,6-tetramethylpiperidine (TMP) as a proton trap. Subsequently, the star polymers were used as macroinitiators for the ATRP of tBA using the CuBr/N,N,N',N",N"-pentamethyldiethylenetriamine (PMDETA) catalyst system to obtain the tri-armed star block copolymers (PTHF-b-PtBA)(3). The polymers were characterized with gel-permeation chromatography (GPC) and H-1-NMR. Both techniques demonstrated the formation of tri-armed star block copolymers.
Keywords
poly(tert-butyl acrylate), polytetrahydrofuran, star block co-polymer, cationic ring-opening polymerization (CROP), atom transfer radical polymerization (ATRP)

Downloads

  • Download
    325658.pdf
    • full text (Published version)
    • |
    • open access
    • |
    • PDF
    • |
    • 150.52 KB

Citation

Please use this url to cite or link to this publication:

MLA
Erdogan, T., et al. “Preparation of Star Block Co-Polymers by Combination of Cationic Ring Opening Polymerization and Atom Transfer Radical Polymerization.” DESIGNED MONOMERS AND POLYMERS, vol. 8, no. 6, VSP BV, 2005, pp. 705–14, doi:10.1163/156855505774597812.
APA
Erdogan, T., Bernaerts, K., Van Renterghem, L., Du Prez, F., & Goethals, E. (2005). Preparation of star block co-polymers by combination of cationic ring opening polymerization and atom transfer radical polymerization. DESIGNED MONOMERS AND POLYMERS, 8(6), 705–714. https://doi.org/10.1163/156855505774597812
Chicago author-date
Erdogan, T, Katrien Bernaerts, Lieven Van Renterghem, Filip Du Prez, and Eric Goethals. 2005. “Preparation of Star Block Co-Polymers by Combination of Cationic Ring Opening Polymerization and Atom Transfer Radical Polymerization.” DESIGNED MONOMERS AND POLYMERS 8 (6): 705–14. https://doi.org/10.1163/156855505774597812.
Chicago author-date (all authors)
Erdogan, T, Katrien Bernaerts, Lieven Van Renterghem, Filip Du Prez, and Eric Goethals. 2005. “Preparation of Star Block Co-Polymers by Combination of Cationic Ring Opening Polymerization and Atom Transfer Radical Polymerization.” DESIGNED MONOMERS AND POLYMERS 8 (6): 705–714. doi:10.1163/156855505774597812.
Vancouver
1.
Erdogan T, Bernaerts K, Van Renterghem L, Du Prez F, Goethals E. Preparation of star block co-polymers by combination of cationic ring opening polymerization and atom transfer radical polymerization. DESIGNED MONOMERS AND POLYMERS. 2005;8(6):705–14.
IEEE
[1]
T. Erdogan, K. Bernaerts, L. Van Renterghem, F. Du Prez, and E. Goethals, “Preparation of star block co-polymers by combination of cationic ring opening polymerization and atom transfer radical polymerization,” DESIGNED MONOMERS AND POLYMERS, vol. 8, no. 6, pp. 705–714, 2005.
@article{325658,
  abstract     = {{The synthesis of star block co-polymers with polytetrahydrofuran (PTHF) core and poly(tert-butyl acrylate) (PtBA) shell was performed using a dual initiator, 4-hydroxy butyl bromoisobutyrate, by combination of cationic ring-opening polymerization (CROP) and atom transfer radical polymerization (ATRP). The in situ reaction of the hydroxyl groups originating from the dual initiator with trifluoromethane sulfonic anhydride provides a triflate ester initiating group for the CROP of THF PTHF star polymers having three arms with tertiary bromide end groups (PTHF)(3) have been prepared by reaction of living PTHF chains with tris(2-aminoethyl)amine (TAEA) in the presence of 2,2,6,6-tetramethylpiperidine (TMP) as a proton trap. Subsequently, the star polymers were used as macroinitiators for the ATRP of tBA using the CuBr/N,N,N',N",N"-pentamethyldiethylenetriamine (PMDETA) catalyst system to obtain the tri-armed star block copolymers (PTHF-b-PtBA)(3). The polymers were characterized with gel-permeation chromatography (GPC) and H-1-NMR. Both techniques demonstrated the formation of tri-armed star block copolymers.}},
  author       = {{Erdogan, T and Bernaerts, Katrien and Van Renterghem, Lieven and Du Prez, Filip and Goethals, Eric}},
  issn         = {{1385-772X}},
  journal      = {{DESIGNED MONOMERS AND POLYMERS}},
  keywords     = {{poly(tert-butyl acrylate),polytetrahydrofuran,star block co-polymer,cationic ring-opening polymerization (CROP),atom transfer radical polymerization (ATRP)}},
  language     = {{eng}},
  number       = {{6}},
  pages        = {{705--714}},
  publisher    = {{VSP BV}},
  title        = {{Preparation of star block co-polymers by combination of cationic ring opening polymerization and atom transfer radical polymerization}},
  url          = {{http://doi.org/10.1163/156855505774597812}},
  volume       = {{8}},
  year         = {{2005}},
}
Altmetric
View in Altmetric
Web of Science
Times cited: