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Copper-catalyzed dehydrogenative polycondensation of a bis-aniline hexylthiophene-based monomer : a kinetically controlled air-tolerant process

(2012) MACROMOLECULES. 45(23). p.9547-9550
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Organization
Abstract
Aerobic oxidative dehydrogenative polycondensation of the new monomer 4,4'-(3-hexylthiophene-2,5-diyl)bis(2-octylaniline) has proved very effective under mild conditions using an inexpensive copper bromide/pyridine complex and dioxygen acting as catalyst and oxidant, respectively. Such kinetically controlled process allowed preparing elec-troconjugated photosensitive polymers with high molar weight (Mn > 15000 g.mol-1).
Keywords
POLY(3-HEXYLTHIOPHENE), CHAIN, POLYMERS, LIGHT

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Citation

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MLA
Nguyen, Ha Tran, Olivier Coulembier, Katelijne Gheysen, et al. “Copper-catalyzed Dehydrogenative Polycondensation of a Bis-aniline Hexylthiophene-based Monomer : a Kinetically Controlled Air-tolerant Process.” MACROMOLECULES 45.23 (2012): 9547–9550. Print.
APA
Nguyen, H. T., Coulembier, O., Gheysen, K., Martins, J., & Dubois, P. (2012). Copper-catalyzed dehydrogenative polycondensation of a bis-aniline hexylthiophene-based monomer : a kinetically controlled air-tolerant process. MACROMOLECULES, 45(23), 9547–9550.
Chicago author-date
Nguyen, Ha Tran, Olivier Coulembier, Katelijne Gheysen, José Martins, and Philippe Dubois. 2012. “Copper-catalyzed Dehydrogenative Polycondensation of a Bis-aniline Hexylthiophene-based Monomer : a Kinetically Controlled Air-tolerant Process.” Macromolecules 45 (23): 9547–9550.
Chicago author-date (all authors)
Nguyen, Ha Tran, Olivier Coulembier, Katelijne Gheysen, José Martins, and Philippe Dubois. 2012. “Copper-catalyzed Dehydrogenative Polycondensation of a Bis-aniline Hexylthiophene-based Monomer : a Kinetically Controlled Air-tolerant Process.” Macromolecules 45 (23): 9547–9550.
Vancouver
1.
Nguyen HT, Coulembier O, Gheysen K, Martins J, Dubois P. Copper-catalyzed dehydrogenative polycondensation of a bis-aniline hexylthiophene-based monomer : a kinetically controlled air-tolerant process. MACROMOLECULES. 2012;45(23):9547–50.
IEEE
[1]
H. T. Nguyen, O. Coulembier, K. Gheysen, J. Martins, and P. Dubois, “Copper-catalyzed dehydrogenative polycondensation of a bis-aniline hexylthiophene-based monomer : a kinetically controlled air-tolerant process,” MACROMOLECULES, vol. 45, no. 23, pp. 9547–9550, 2012.
@article{3236438,
  abstract     = {{Aerobic oxidative dehydrogenative polycondensation of the new monomer 4,4'-(3-hexylthiophene-2,5-diyl)bis(2-octylaniline) has proved very effective under mild conditions using an inexpensive copper bromide/pyridine complex and dioxygen acting as catalyst and oxidant, respectively. Such kinetically controlled process allowed preparing elec-troconjugated photosensitive polymers with high molar weight (Mn > 15000 g.mol-1).}},
  author       = {{Nguyen, Ha Tran and Coulembier, Olivier and Gheysen, Katelijne and Martins, José and Dubois, Philippe}},
  issn         = {{0024-9297}},
  journal      = {{MACROMOLECULES}},
  keywords     = {{POLY(3-HEXYLTHIOPHENE),CHAIN,POLYMERS,LIGHT}},
  language     = {{eng}},
  number       = {{23}},
  pages        = {{9547--9550}},
  title        = {{Copper-catalyzed dehydrogenative polycondensation of a bis-aniline hexylthiophene-based monomer : a kinetically controlled air-tolerant process}},
  url          = {{http://dx.doi.org/10.1021/ma301881y}},
  volume       = {{45}},
  year         = {{2012}},
}

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