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Copper-catalyzed dehydrogenative polycondensation of a bis-aniline hexylthiophene-based monomer: a kinetically controlled air-tolerant process

Ha Tran Nguyen, Olivier Coulembier, Katelijne Gheysen, José Martins UGent and Philippe Dubois (2012) MACROMOLECULES. 45(23). p.9547-9550
abstract
Aerobic oxidative dehydrogenative polycondensation of the new monomer 4,4'-(3-hexylthiophene-2,5-diyl)bis(2-octylaniline) has proved very effective under mild conditions using an inexpensive copper bromide/pyridine complex and dioxygen acting as catalyst and oxidant, respectively. Such kinetically controlled process allowed preparing elec-troconjugated photosensitive polymers with high molar weight (Mn > 15000 g.mol-1).
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
POLY(3-HEXYLTHIOPHENE), CHAIN, POLYMERS, LIGHT
journal title
MACROMOLECULES
Macromolecules
volume
45
issue
23
pages
9547 - 9550
Web of Science type
Article
Web of Science id
000312122600036
JCR category
POLYMER SCIENCE
JCR impact factor
5.521 (2012)
JCR rank
3/82 (2012)
JCR quartile
1 (2012)
ISSN
0024-9297
DOI
10.1021/ma301881y
language
English
UGent publication?
yes
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
3236438
handle
http://hdl.handle.net/1854/LU-3236438
date created
2013-06-06 00:27:25
date last changed
2016-12-19 15:45:43
@article{3236438,
  abstract     = {Aerobic oxidative dehydrogenative polycondensation of the new monomer 4,4'-(3-hexylthiophene-2,5-diyl)bis(2-octylaniline) has proved very effective under mild conditions using an inexpensive copper bromide/pyridine complex and dioxygen acting as catalyst and oxidant, respectively. Such kinetically controlled process allowed preparing elec-troconjugated photosensitive polymers with high molar weight (Mn {\textrangle} 15000 g.mol-1).},
  author       = {Nguyen, Ha Tran and Coulembier, Olivier and Gheysen, Katelijne and Martins, Jos{\'e} and Dubois, Philippe},
  issn         = {0024-9297},
  journal      = {MACROMOLECULES},
  keyword      = {POLY(3-HEXYLTHIOPHENE),CHAIN,POLYMERS,LIGHT},
  language     = {eng},
  number       = {23},
  pages        = {9547--9550},
  title        = {Copper-catalyzed dehydrogenative polycondensation of a bis-aniline hexylthiophene-based monomer: a kinetically controlled air-tolerant process},
  url          = {http://dx.doi.org/10.1021/ma301881y},
  volume       = {45},
  year         = {2012},
}

Chicago
Nguyen, Ha Tran, Olivier Coulembier, Katelijne Gheysen, José Martins, and Philippe Dubois. 2012. “Copper-catalyzed Dehydrogenative Polycondensation of a Bis-aniline Hexylthiophene-based Monomer: a Kinetically Controlled Air-tolerant Process.” Macromolecules 45 (23): 9547–9550.
APA
Nguyen, H. T., Coulembier, O., Gheysen, K., Martins, J., & Dubois, P. (2012). Copper-catalyzed dehydrogenative polycondensation of a bis-aniline hexylthiophene-based monomer: a kinetically controlled air-tolerant process. MACROMOLECULES, 45(23), 9547–9550.
Vancouver
1.
Nguyen HT, Coulembier O, Gheysen K, Martins J, Dubois P. Copper-catalyzed dehydrogenative polycondensation of a bis-aniline hexylthiophene-based monomer: a kinetically controlled air-tolerant process. MACROMOLECULES. 2012;45(23):9547–50.
MLA
Nguyen, Ha Tran, Olivier Coulembier, Katelijne Gheysen, et al. “Copper-catalyzed Dehydrogenative Polycondensation of a Bis-aniline Hexylthiophene-based Monomer: a Kinetically Controlled Air-tolerant Process.” MACROMOLECULES 45.23 (2012): 9547–9550. Print.