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Copper-catalyzed dehydrogenative polycondensation of a bis-aniline hexylthiophene-based monomer : a kinetically controlled air-tolerant process

(2012) MACROMOLECULES. 45(23). p.9547-9550
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Organization
Abstract
Aerobic oxidative dehydrogenative polycondensation of the new monomer 4,4'-(3-hexylthiophene-2,5-diyl)bis(2-octylaniline) has proved very effective under mild conditions using an inexpensive copper bromide/pyridine complex and dioxygen acting as catalyst and oxidant, respectively. Such kinetically controlled process allowed preparing elec-troconjugated photosensitive polymers with high molar weight (Mn > 15000 g.mol-1).
Keywords
POLY(3-HEXYLTHIOPHENE), CHAIN, POLYMERS, LIGHT

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Citation

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Chicago
Nguyen, Ha Tran, Olivier Coulembier, Katelijne Gheysen, José Martins, and Philippe Dubois. 2012. “Copper-catalyzed Dehydrogenative Polycondensation of a Bis-aniline Hexylthiophene-based Monomer : a Kinetically Controlled Air-tolerant Process.” Macromolecules 45 (23): 9547–9550.
APA
Nguyen, H. T., Coulembier, O., Gheysen, K., Martins, J., & Dubois, P. (2012). Copper-catalyzed dehydrogenative polycondensation of a bis-aniline hexylthiophene-based monomer : a kinetically controlled air-tolerant process. MACROMOLECULES, 45(23), 9547–9550.
Vancouver
1.
Nguyen HT, Coulembier O, Gheysen K, Martins J, Dubois P. Copper-catalyzed dehydrogenative polycondensation of a bis-aniline hexylthiophene-based monomer : a kinetically controlled air-tolerant process. MACROMOLECULES. 2012;45(23):9547–50.
MLA
Nguyen, Ha Tran, Olivier Coulembier, Katelijne Gheysen, et al. “Copper-catalyzed Dehydrogenative Polycondensation of a Bis-aniline Hexylthiophene-based Monomer : a Kinetically Controlled Air-tolerant Process.” MACROMOLECULES 45.23 (2012): 9547–9550. Print.
@article{3236438,
  abstract     = {Aerobic oxidative dehydrogenative polycondensation of the new monomer 4,4'-(3-hexylthiophene-2,5-diyl)bis(2-octylaniline) has proved very effective under mild conditions using an inexpensive copper bromide/pyridine complex and dioxygen acting as catalyst and oxidant, respectively. Such kinetically controlled process allowed preparing elec-troconjugated photosensitive polymers with high molar weight (Mn {\textrangle} 15000 g.mol-1).},
  author       = {Nguyen, Ha Tran and Coulembier, Olivier and Gheysen, Katelijne and Martins, Jos{\'e} and Dubois, Philippe},
  issn         = {0024-9297},
  journal      = {MACROMOLECULES},
  keyword      = {POLY(3-HEXYLTHIOPHENE),CHAIN,POLYMERS,LIGHT},
  language     = {eng},
  number       = {23},
  pages        = {9547--9550},
  title        = {Copper-catalyzed dehydrogenative polycondensation of a bis-aniline hexylthiophene-based monomer : a kinetically controlled air-tolerant process},
  url          = {http://dx.doi.org/10.1021/ma301881y},
  volume       = {45},
  year         = {2012},
}

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