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Quality of Brazilian vegetable oils evaluated by (modulated) differential scanning calorimetry

Pieter Samyn UGent, Gustaaf Schoukens, Leo Vonck, Dirk Stanssens and Henk Van den Abbeele (2012) JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY. 110(3). p.1353-1365
abstract
Vegetable oils are increasingly replacing fossil-oil-based polymers, and therefore aimed at being used in polymerization reactions from -20 to 100 A degrees C. Therefore, phase transitions and heat capacities in this temperature range should be well characterized to optimize processing conditions and energy inputs. By using the DSC analysis, only small primary correspondence or divergence between different oil types are seen as a function of their degree of unsaturation, but it does not clearly distinguish detailed features such as shoulder bands related to the separate melting processes of single fatty acid components. By using modulated DSC analysis, the combined analysis of reversing and non-reversing heat signals provides better results. The latter confirms that the melting is not a physical one-step process, but equilibrates between phase transitions and enthalpic reorganizations of the fatty acids that can be monitored separately. The specific heat capacities measured during modulated DSC are somewhat lower than traditional calorimetric measurements, but relate to the degree of unsaturation. The thermal behavior of palm-, soy-, sunflower-, corn-, castor-, and rapeseed-oil is discussed in relation to their composition, by applying a first or second heating scan.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
THERMAL-ANALYSIS, HEAT-CAPACITY, PALM KERNEL OIL, VIRGIN OLIVE OIL, TRANSFORM INFRARED-SPECTROSCOPY, SUNFLOWER OIL, EDIBLE OILS, DSC, CRYSTALLIZATION, BLENDS, Thermal analysis, Heat Flow, Heat capacity, Modulated DSC, Vegetable oil
journal title
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
J. Therm. Anal. Calorim.
volume
110
issue
3
pages
1353 - 1365
publisher
Springer
Web of Science type
Article
Web of Science id
000311510500041
JCR category
CHEMISTRY, ANALYTICAL
JCR impact factor
1.982 (2012)
JCR rank
36/74 (2012)
JCR quartile
2 (2012)
ISSN
1388-6150
DOI
10.1007/s10973-011-2132-2
project
Production of imidized styrene-maleic anhydride (SMI) nanoparticles and surface interactions with different substrates
language
English
UGent publication?
yes
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
3228577
handle
http://hdl.handle.net/1854/LU-3228577
date created
2013-05-29 13:18:59
date last changed
2017-03-09 12:15:27
@article{3228577,
  abstract     = {Vegetable oils are increasingly replacing fossil-oil-based polymers, and therefore aimed at being used in polymerization reactions from -20 to 100 A degrees C. Therefore, phase transitions and heat capacities in this temperature range should be well characterized to optimize processing conditions and energy inputs. By using the DSC analysis, only small primary correspondence or divergence between different oil types are seen as a function of their degree of unsaturation, but it does not clearly distinguish detailed features such as shoulder bands related to the separate melting processes of single fatty acid components. By using modulated DSC analysis, the combined analysis of reversing and non-reversing heat signals provides better results. The latter confirms that the melting is not a physical one-step process, but equilibrates between phase transitions and enthalpic reorganizations of the fatty acids that can be monitored separately. The specific heat capacities measured during modulated DSC are somewhat lower than traditional calorimetric measurements, but relate to the degree of unsaturation. The thermal behavior of palm-, soy-, sunflower-, corn-, castor-, and rapeseed-oil is discussed in relation to their composition, by applying a first or second heating scan.},
  author       = {Samyn, Pieter and Schoukens, Gustaaf and Vonck, Leo and Stanssens, Dirk and Van den Abbeele, Henk},
  issn         = {1388-6150},
  journal      = {JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY},
  keyword      = {THERMAL-ANALYSIS,HEAT-CAPACITY,PALM KERNEL OIL,VIRGIN OLIVE OIL,TRANSFORM INFRARED-SPECTROSCOPY,SUNFLOWER OIL,EDIBLE OILS,DSC,CRYSTALLIZATION,BLENDS,Thermal analysis,Heat Flow,Heat capacity,Modulated DSC,Vegetable oil},
  language     = {eng},
  number       = {3},
  pages        = {1353--1365},
  publisher    = {Springer},
  title        = {Quality of Brazilian vegetable oils evaluated by (modulated) differential scanning calorimetry},
  url          = {http://dx.doi.org/10.1007/s10973-011-2132-2},
  volume       = {110},
  year         = {2012},
}

Chicago
Samyn, Pieter, Gustaaf Schoukens, Leo Vonck, Dirk Stanssens, and Henk Van den Abbeele. 2012. “Quality of Brazilian Vegetable Oils Evaluated by (modulated) Differential Scanning Calorimetry.” Journal of Thermal Analysis and Calorimetry 110 (3): 1353–1365.
APA
Samyn, Pieter, Schoukens, G., Vonck, L., Stanssens, D., & Van den Abbeele, H. (2012). Quality of Brazilian vegetable oils evaluated by (modulated) differential scanning calorimetry. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 110(3), 1353–1365.
Vancouver
1.
Samyn P, Schoukens G, Vonck L, Stanssens D, Van den Abbeele H. Quality of Brazilian vegetable oils evaluated by (modulated) differential scanning calorimetry. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY. Springer; 2012;110(3):1353–65.
MLA
Samyn, Pieter, Gustaaf Schoukens, Leo Vonck, et al. “Quality of Brazilian Vegetable Oils Evaluated by (modulated) Differential Scanning Calorimetry.” JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 110.3 (2012): 1353–1365. Print.