Advanced search
1 file | 697.24 KB

Accurate determination of S in organic matrices using isotope dilution ICP-MS/MS

Author
Organization
Abstract
Accurate determination of low levels of S in organic matrices by means of isotope dilution ICP-single quadrupole MS (e.g., for quantification of S components in reverse phase HPLC-ICP-MS experiments) is often not feasible. This work describes an accurate, sensitive and fast analytical method for the determination of S in organic matrices by means of a recently developed 'triple quadrupole' ICP-MS instrument, operated in MS/MS mode. The added value of the MS/MS approach for this application has been clearly visualised by varying the width of the bandpass of the first quadrupole analyzer from "fully open" (standard mode) down to single mass width (MS/MS mode). As a proof-of-concept, a biodiesel reference material has been analysed for its S content with the proposed method, using isotope dilution for calibration, and the results obtained were in excellent agreement with the certified value (within experimental uncertainty).
Keywords
DYNAMIC REACTION CELL, CONTAINING DRUG METABOLITES, INTERFERENCE STANDARD, IN-VIVO, PLASMA-MASS SPECTROMETRY, SULFUR, MS, SAMPLES, HPLC, PHOSPHORUS

Downloads

  • (...).pdf
    • full text
    • |
    • UGent only
    • |
    • PDF
    • |
    • 697.24 KB

Citation

Please use this url to cite or link to this publication:

Chicago
Balcaen, Lieve, Glenn Woods, Martín Resano, and Frank Vanhaecke. 2013. “Accurate Determination of S in Organic Matrices Using Isotope Dilution ICP-MS/MS.” Journal of Analytical Atomic Spectrometry 28 (1): 33–39.
APA
Balcaen, Lieve, Woods, G., Resano, M., & Vanhaecke, F. (2013). Accurate determination of S in organic matrices using isotope dilution ICP-MS/MS. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 28(1), 33–39.
Vancouver
1.
Balcaen L, Woods G, Resano M, Vanhaecke F. Accurate determination of S in organic matrices using isotope dilution ICP-MS/MS. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY. 2013;28(1):33–9.
MLA
Balcaen, Lieve, Glenn Woods, Martín Resano, et al. “Accurate Determination of S in Organic Matrices Using Isotope Dilution ICP-MS/MS.” JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY 28.1 (2013): 33–39. Print.
@article{3174710,
  abstract     = {Accurate determination of low levels of S in organic matrices by means of isotope dilution ICP-single quadrupole MS (e.g., for quantification of S components in reverse phase HPLC-ICP-MS experiments) is often not feasible. This work describes an accurate, sensitive and fast analytical method for the determination of S in organic matrices by means of a recently developed 'triple quadrupole' ICP-MS instrument, operated in MS/MS mode. The added value of the MS/MS approach for this application has been clearly visualised by varying the width of the bandpass of the first quadrupole analyzer from {\textacutedbl}fully open{\textacutedbl} (standard mode) down to single mass width (MS/MS mode). As a proof-of-concept, a biodiesel reference material has been analysed for its S content with the proposed method, using isotope dilution for calibration, and the results obtained were in excellent agreement with the certified value (within experimental uncertainty).},
  author       = {Balcaen, Lieve and Woods, Glenn and Resano, Mart{\'i}n and Vanhaecke, Frank},
  issn         = {0267-9477},
  journal      = {JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY},
  keyword      = {DYNAMIC REACTION CELL,CONTAINING DRUG METABOLITES,INTERFERENCE STANDARD,IN-VIVO,PLASMA-MASS SPECTROMETRY,SULFUR,MS,SAMPLES,HPLC,PHOSPHORUS},
  language     = {eng},
  number       = {1},
  pages        = {33--39},
  title        = {Accurate determination of S in organic matrices using isotope dilution ICP-MS/MS},
  url          = {http://dx.doi.org/10.1039/c2ja30265a},
  volume       = {28},
  year         = {2013},
}

Altmetric
View in Altmetric
Web of Science
Times cited: