Accurate determination of S in organic matrices using isotope dilution ICP-MS/MS
- Author
- Lieve Balcaen (UGent) , Glenn Woods, Martín Resano and Frank Vanhaecke (UGent)
- Organization
- Abstract
- Accurate determination of low levels of S in organic matrices by means of isotope dilution ICP-single quadrupole MS (e.g., for quantification of S components in reverse phase HPLC-ICP-MS experiments) is often not feasible. This work describes an accurate, sensitive and fast analytical method for the determination of S in organic matrices by means of a recently developed 'triple quadrupole' ICP-MS instrument, operated in MS/MS mode. The added value of the MS/MS approach for this application has been clearly visualised by varying the width of the bandpass of the first quadrupole analyzer from "fully open" (standard mode) down to single mass width (MS/MS mode). As a proof-of-concept, a biodiesel reference material has been analysed for its S content with the proposed method, using isotope dilution for calibration, and the results obtained were in excellent agreement with the certified value (within experimental uncertainty).
- Keywords
- DYNAMIC REACTION CELL, CONTAINING DRUG METABOLITES, INTERFERENCE STANDARD, IN-VIVO, PLASMA-MASS SPECTROMETRY, SULFUR, MS, SAMPLES, HPLC, PHOSPHORUS
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Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-3174710
- MLA
- Balcaen, Lieve, et al. “Accurate Determination of S in Organic Matrices Using Isotope Dilution ICP-MS/MS.” JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, vol. 28, no. 1, 2013, pp. 33–39, doi:10.1039/c2ja30265a.
- APA
- Balcaen, L., Woods, G., Resano, M., & Vanhaecke, F. (2013). Accurate determination of S in organic matrices using isotope dilution ICP-MS/MS. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 28(1), 33–39. https://doi.org/10.1039/c2ja30265a
- Chicago author-date
- Balcaen, Lieve, Glenn Woods, Martín Resano, and Frank Vanhaecke. 2013. “Accurate Determination of S in Organic Matrices Using Isotope Dilution ICP-MS/MS.” JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY 28 (1): 33–39. https://doi.org/10.1039/c2ja30265a.
- Chicago author-date (all authors)
- Balcaen, Lieve, Glenn Woods, Martín Resano, and Frank Vanhaecke. 2013. “Accurate Determination of S in Organic Matrices Using Isotope Dilution ICP-MS/MS.” JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY 28 (1): 33–39. doi:10.1039/c2ja30265a.
- Vancouver
- 1.Balcaen L, Woods G, Resano M, Vanhaecke F. Accurate determination of S in organic matrices using isotope dilution ICP-MS/MS. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY. 2013;28(1):33–9.
- IEEE
- [1]L. Balcaen, G. Woods, M. Resano, and F. Vanhaecke, “Accurate determination of S in organic matrices using isotope dilution ICP-MS/MS,” JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, vol. 28, no. 1, pp. 33–39, 2013.
@article{3174710,
abstract = {{Accurate determination of low levels of S in organic matrices by means of isotope dilution ICP-single quadrupole MS (e.g., for quantification of S components in reverse phase HPLC-ICP-MS experiments) is often not feasible. This work describes an accurate, sensitive and fast analytical method for the determination of S in organic matrices by means of a recently developed 'triple quadrupole' ICP-MS instrument, operated in MS/MS mode. The added value of the MS/MS approach for this application has been clearly visualised by varying the width of the bandpass of the first quadrupole analyzer from "fully open" (standard mode) down to single mass width (MS/MS mode). As a proof-of-concept, a biodiesel reference material has been analysed for its S content with the proposed method, using isotope dilution for calibration, and the results obtained were in excellent agreement with the certified value (within experimental uncertainty).}},
author = {{Balcaen, Lieve and Woods, Glenn and Resano, Martín and Vanhaecke, Frank}},
issn = {{0267-9477}},
journal = {{JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY}},
keywords = {{DYNAMIC REACTION CELL,CONTAINING DRUG METABOLITES,INTERFERENCE STANDARD,IN-VIVO,PLASMA-MASS SPECTROMETRY,SULFUR,MS,SAMPLES,HPLC,PHOSPHORUS}},
language = {{eng}},
number = {{1}},
pages = {{33--39}},
title = {{Accurate determination of S in organic matrices using isotope dilution ICP-MS/MS}},
url = {{http://doi.org/10.1039/c2ja30265a}},
volume = {{28}},
year = {{2013}},
}
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