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Accurate determination of S in organic matrices using isotope dilution ICP-MS/MS

Lieve Balcaen UGent, Glenn Woods, Martín Resano and Frank Vanhaecke UGent (2013) JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY. 28(1). p.33-39
abstract
Accurate determination of low levels of S in organic matrices by means of isotope dilution ICP-single quadrupole MS (e.g., for quantification of S components in reverse phase HPLC-ICP-MS experiments) is often not feasible. This work describes an accurate, sensitive and fast analytical method for the determination of S in organic matrices by means of a recently developed 'triple quadrupole' ICP-MS instrument, operated in MS/MS mode. The added value of the MS/MS approach for this application has been clearly visualised by varying the width of the bandpass of the first quadrupole analyzer from "fully open" (standard mode) down to single mass width (MS/MS mode). As a proof-of-concept, a biodiesel reference material has been analysed for its S content with the proposed method, using isotope dilution for calibration, and the results obtained were in excellent agreement with the certified value (within experimental uncertainty).
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
DYNAMIC REACTION CELL, CONTAINING DRUG METABOLITES, INTERFERENCE STANDARD, IN-VIVO, PLASMA-MASS SPECTROMETRY, SULFUR, MS, SAMPLES, HPLC, PHOSPHORUS
journal title
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY
J. Anal. At. Spectrom.
volume
28
issue
1
pages
33 - 39
Web of Science type
Article
Web of Science id
000314903400002
JCR category
SPECTROSCOPY
JCR impact factor
3.396 (2013)
JCR rank
5/44 (2013)
JCR quartile
1 (2013)
ISSN
0267-9477
DOI
10.1039/c2ja30265a
language
English
UGent publication?
yes
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
3174710
handle
http://hdl.handle.net/1854/LU-3174710
date created
2013-03-26 11:03:49
date last changed
2016-12-19 15:45:59
@article{3174710,
  abstract     = {Accurate determination of low levels of S in organic matrices by means of isotope dilution ICP-single quadrupole MS (e.g., for quantification of S components in reverse phase HPLC-ICP-MS experiments) is often not feasible. This work describes an accurate, sensitive and fast analytical method for the determination of S in organic matrices by means of a recently developed 'triple quadrupole' ICP-MS instrument, operated in MS/MS mode. The added value of the MS/MS approach for this application has been clearly visualised by varying the width of the bandpass of the first quadrupole analyzer from {\textacutedbl}fully open{\textacutedbl} (standard mode) down to single mass width (MS/MS mode). As a proof-of-concept, a biodiesel reference material has been analysed for its S content with the proposed method, using isotope dilution for calibration, and the results obtained were in excellent agreement with the certified value (within experimental uncertainty).},
  author       = {Balcaen, Lieve and Woods, Glenn and Resano, Mart{\'i}n and Vanhaecke, Frank},
  issn         = {0267-9477},
  journal      = {JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY},
  keyword      = {DYNAMIC REACTION CELL,CONTAINING DRUG METABOLITES,INTERFERENCE STANDARD,IN-VIVO,PLASMA-MASS SPECTROMETRY,SULFUR,MS,SAMPLES,HPLC,PHOSPHORUS},
  language     = {eng},
  number       = {1},
  pages        = {33--39},
  title        = {Accurate determination of S in organic matrices using isotope dilution ICP-MS/MS},
  url          = {http://dx.doi.org/10.1039/c2ja30265a},
  volume       = {28},
  year         = {2013},
}

Chicago
Balcaen, Lieve, Glenn Woods, Martín Resano, and Frank Vanhaecke. 2013. “Accurate Determination of S in Organic Matrices Using Isotope Dilution ICP-MS/MS.” Journal of Analytical Atomic Spectrometry 28 (1): 33–39.
APA
Balcaen, Lieve, Woods, G., Resano, M., & Vanhaecke, F. (2013). Accurate determination of S in organic matrices using isotope dilution ICP-MS/MS. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 28(1), 33–39.
Vancouver
1.
Balcaen L, Woods G, Resano M, Vanhaecke F. Accurate determination of S in organic matrices using isotope dilution ICP-MS/MS. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY. 2013;28(1):33–9.
MLA
Balcaen, Lieve, Glenn Woods, Martín Resano, et al. “Accurate Determination of S in Organic Matrices Using Isotope Dilution ICP-MS/MS.” JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY 28.1 (2013): 33–39. Print.