Advanced search
1 file | 1.96 MB Add to list

Homoselenacalix[4]arenes : synthetic exploration and metallosupramolecular chemistry

(2012) ORGANIC & BIOMOLECULAR CHEMISTRY. 10(32). p.6526-6536
Author
Organization
Abstract
Homoselenacalix[4]arenes were synthesized by a [2 + 2] reductive coupling protocol favouring the cyclotetramers. The inner and outer-rim decoration was varied and a bicyclic derivative was prepared by a similar one-pot procedure. Conformational analysis in solution and the solid state showed noticeable differences between the homoselenacalix[4]arenes and the analogous homothiacalix[4]arenes and provided insight into the metal binding potential of the Se-bridged macrocycles. The homoselenacalix[4]arenes were found to bind Ag(I). Complexation was visualized in the solid state and different packing networks were formed depending on the counter ions applied.
Keywords
HETEROATOM-BRIDGED CALIXARENES, QUATERNARY AMMONIUM-IONS, STRUCTURAL-PROPERTIES, CRYSTAL-STRUCTURE, COMPLEXATION PROPERTIES, BINDING-PROPERTIES, EXCHANGE-REACTIONS, ETHER DERIVATIVES, PI INTERACTIONS, SOLID-STATE

Downloads

  • (...).pdf
    • full text
    • |
    • UGent only
    • |
    • PDF
    • |
    • 1.96 MB

Citation

Please use this url to cite or link to this publication:

MLA
Thomas, Joice, et al. “Homoselenacalix[4]Arenes : Synthetic Exploration and Metallosupramolecular Chemistry.” ORGANIC & BIOMOLECULAR CHEMISTRY, vol. 10, no. 32, 2012, pp. 6526–36.
APA
Thomas, J., Dobrzanska, L., Van Hecke, K., Sonawane, M. P., Robeyns, K., Van Meervelt, L., … Dehaen, W. (2012). Homoselenacalix[4]arenes : synthetic exploration and metallosupramolecular chemistry. ORGANIC & BIOMOLECULAR CHEMISTRY, 10(32), 6526–6536.
Chicago author-date
Thomas, Joice, Liliana Dobrzanska, Kristof Van Hecke, Mahendra P Sonawane, Koen Robeyns, Luc Van Meervelt, Krzysztof Wozniak, Mario Smet, Wouter Maes, and Wim Dehaen. 2012. “Homoselenacalix[4]Arenes : Synthetic Exploration and Metallosupramolecular Chemistry.” ORGANIC & BIOMOLECULAR CHEMISTRY 10 (32): 6526–36.
Chicago author-date (all authors)
Thomas, Joice, Liliana Dobrzanska, Kristof Van Hecke, Mahendra P Sonawane, Koen Robeyns, Luc Van Meervelt, Krzysztof Wozniak, Mario Smet, Wouter Maes, and Wim Dehaen. 2012. “Homoselenacalix[4]Arenes : Synthetic Exploration and Metallosupramolecular Chemistry.” ORGANIC & BIOMOLECULAR CHEMISTRY 10 (32): 6526–6536.
Vancouver
1.
Thomas J, Dobrzanska L, Van Hecke K, Sonawane MP, Robeyns K, Van Meervelt L, et al. Homoselenacalix[4]arenes : synthetic exploration and metallosupramolecular chemistry. ORGANIC & BIOMOLECULAR CHEMISTRY. 2012;10(32):6526–36.
IEEE
[1]
J. Thomas et al., “Homoselenacalix[4]arenes : synthetic exploration and metallosupramolecular chemistry,” ORGANIC & BIOMOLECULAR CHEMISTRY, vol. 10, no. 32, pp. 6526–6536, 2012.
@article{3103424,
  abstract     = {Homoselenacalix[4]arenes were synthesized by a [2 + 2] reductive coupling protocol favouring the cyclotetramers. The inner and outer-rim decoration was varied and a bicyclic derivative was prepared by a similar one-pot procedure. Conformational analysis in solution and the solid state showed noticeable differences between the homoselenacalix[4]arenes and the analogous homothiacalix[4]arenes and provided insight into the metal binding potential of the Se-bridged macrocycles. The homoselenacalix[4]arenes were found to bind Ag(I). Complexation was visualized in the solid state and different packing networks were formed depending on the counter ions applied.},
  author       = {Thomas, Joice and Dobrzanska, Liliana and Van Hecke, Kristof and Sonawane, Mahendra P and Robeyns, Koen and Van Meervelt, Luc and Wozniak, Krzysztof and Smet, Mario and Maes, Wouter and Dehaen, Wim},
  issn         = {1477-0520},
  journal      = {ORGANIC & BIOMOLECULAR CHEMISTRY},
  keywords     = {HETEROATOM-BRIDGED CALIXARENES,QUATERNARY AMMONIUM-IONS,STRUCTURAL-PROPERTIES,CRYSTAL-STRUCTURE,COMPLEXATION PROPERTIES,BINDING-PROPERTIES,EXCHANGE-REACTIONS,ETHER DERIVATIVES,PI INTERACTIONS,SOLID-STATE},
  language     = {eng},
  number       = {32},
  pages        = {6526--6536},
  title        = {Homoselenacalix[4]arenes : synthetic exploration and metallosupramolecular chemistry},
  url          = {http://dx.doi.org/10.1039/c2ob25760b},
  volume       = {10},
  year         = {2012},
}

Altmetric
View in Altmetric
Web of Science
Times cited: