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From NMP to RAFT and thiol-ene chemistry by in situ functionalization of nitroxide chain ends

Lionel Petton UGent, Andrés E Ciolino, Milan M. Stamenović UGent, Pieter Espeel UGent and Filip Du Prez UGent (2012) MACROMOLECULAR RAPID COMMUNICATIONS. 33(15). p.1310-1315
abstract
A straightforward, novel strategy based on the in situ functionalization of polymers prepared by nitroxide-mediated polymerization (NMP), for the use as an extension toward block copolymers and post-polymerization modifications, has been investigated. The nitroxide end group is exchanged for a thiocarbonylthio end group by a rapid transfer reaction with bis(thiobenzoyl) disulfide to generate in situ reversible additionfragmentation chain transfer (RAFT) macroinitiators. Moreover, not only have these macroinitiators been used in chain extension and block copolymerization experiments by the RAFT process but also a thiol-terminated polymer is synthesized by aminolysis of the RAFT end group and subsequently reacted with dodecyl vinyl ether by thiol-ene chemistry.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
MEDIATED POLYMERIZATION, METHYL-METHACRYLATE, FREE-RADICAL POLYMERIZATIONS, POLYMERS, DISULFIDES, AGENTS, COPOLYMERIZATION, ALKOXYAMINE, ISOPRENE, STYRENE
journal title
MACROMOLECULAR RAPID COMMUNICATIONS
Macromol. Rapid Commun.
volume
33
issue
15
pages
1310 - 1315
Web of Science type
Article
Web of Science id
000307009700012
JCR category
POLYMER SCIENCE
JCR impact factor
4.929 (2012)
JCR rank
6/82 (2012)
JCR quartile
1 (2012)
ISSN
1022-1336
DOI
10.1002/marc.201200207
language
English
UGent publication?
yes
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
3065309
handle
http://hdl.handle.net/1854/LU-3065309
date created
2012-12-05 08:59:32
date last changed
2012-12-05 09:18:35
@article{3065309,
  abstract     = {A straightforward, novel strategy based on the in situ functionalization of polymers prepared by nitroxide-mediated polymerization (NMP), for the use as an extension toward block copolymers and post-polymerization modifications, has been investigated. The nitroxide end group is exchanged for a thiocarbonylthio end group by a rapid transfer reaction with bis(thiobenzoyl) disulfide to generate in situ reversible additionfragmentation chain transfer (RAFT) macroinitiators. Moreover, not only have these macroinitiators been used in chain extension and block copolymerization experiments by the RAFT process but also a thiol-terminated polymer is synthesized by aminolysis of the RAFT end group and subsequently reacted with dodecyl vinyl ether by thiol-ene chemistry.},
  author       = {Petton, Lionel and Ciolino, Andr{\'e}s E and Stamenovi\'{c}, Milan M. and Espeel, Pieter and Du Prez, Filip},
  issn         = {1022-1336},
  journal      = {MACROMOLECULAR RAPID COMMUNICATIONS},
  keyword      = {MEDIATED POLYMERIZATION,METHYL-METHACRYLATE,FREE-RADICAL POLYMERIZATIONS,POLYMERS,DISULFIDES,AGENTS,COPOLYMERIZATION,ALKOXYAMINE,ISOPRENE,STYRENE},
  language     = {eng},
  number       = {15},
  pages        = {1310--1315},
  title        = {From NMP to RAFT and thiol-ene chemistry by in situ functionalization of nitroxide chain ends},
  url          = {http://dx.doi.org/10.1002/marc.201200207},
  volume       = {33},
  year         = {2012},
}

Chicago
Petton, Lionel, Andrés E Ciolino, Milan M. Stamenović, Pieter Espeel, and Filip Du Prez. 2012. “From NMP to RAFT and Thiol-ene Chemistry by in Situ Functionalization of Nitroxide Chain Ends.” Macromolecular Rapid Communications 33 (15): 1310–1315.
APA
Petton, L., Ciolino, A. E., Stamenović, M. M., Espeel, P., & Du Prez, F. (2012). From NMP to RAFT and thiol-ene chemistry by in situ functionalization of nitroxide chain ends. MACROMOLECULAR RAPID COMMUNICATIONS, 33(15), 1310–1315.
Vancouver
1.
Petton L, Ciolino AE, Stamenović MM, Espeel P, Du Prez F. From NMP to RAFT and thiol-ene chemistry by in situ functionalization of nitroxide chain ends. MACROMOLECULAR RAPID COMMUNICATIONS. 2012;33(15):1310–5.
MLA
Petton, Lionel, Andrés E Ciolino, Milan M. Stamenović, et al. “From NMP to RAFT and Thiol-ene Chemistry by in Situ Functionalization of Nitroxide Chain Ends.” MACROMOLECULAR RAPID COMMUNICATIONS 33.15 (2012): 1310–1315. Print.