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Synthesis, crystal structures, and luminescence properties of carboxylate based rare-earth coordination polymers

Roel Decadt UGent, Kristof Van Hecke UGent, Diederik Depla UGent, Karen Leus UGent, David Weinberger UGent, Isabel Van Driessche UGent, Pascal Van Der Voort UGent and Rik Van Deun UGent (2012) INORGANIC CHEMISTRY. 51(21). p.11623-11634
abstract
Rare-earth coordination polymers or lanthanide-organic frameworks with hitherto unreported crystal structures have been obtained on the basis of the "light" lanthanides Pr, Nd, Sm, and Eu in combination with terephthalic acid and using a slightly altered literature synthesis procedure. Rietveld refinement has shown that powder XRD patterns of such compounds are largely dominated by the positions of the heavy elements, pointing to isostructural networks for all four terephthalate-based materials. An in-depth luminescence study has been performed on the reported MOFs, showing rare praseodymium and samarium emission in the visible spectrum, aside from the strong europium luminescence and the near-infrared emission from both a terephthalate and 2,5-pyridinedicarboxylate based neodymium-MOF.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
STORAGE, SOLIDS, COMPLEXES, DESIGN, PHOTOLUMINESCENCE, RETICULAR CHEMISTRY, LANTHANIDE AQUO IONS, ELECTRONIC ENERGY LEVELS, SECONDARY BUILDING UNITS, METAL-ORGANIC FRAMEWORKS
journal title
INORGANIC CHEMISTRY
Inorg. Chem.
volume
51
issue
21
pages
11623 - 11634
Web of Science type
Article
Web of Science id
000313220200050
JCR category
CHEMISTRY, INORGANIC & NUCLEAR
JCR impact factor
4.593 (2012)
JCR rank
5/43 (2012)
JCR quartile
1 (2012)
ISSN
0020-1669
DOI
10.1021/ic301544q
project
EFECTS (Efficient Environmental-Friendly Electro-Ceramics Coating Technology and Synthesis)
language
English
UGent publication?
yes
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
3047660
handle
http://hdl.handle.net/1854/LU-3047660
date created
2012-11-05 22:31:15
date last changed
2013-02-18 13:11:16
@article{3047660,
  abstract     = {Rare-earth coordination polymers or lanthanide-organic frameworks with hitherto unreported crystal structures have been obtained on the basis of the {\textacutedbl}light{\textacutedbl} lanthanides Pr, Nd, Sm, and Eu in combination with terephthalic acid and using a slightly altered literature synthesis procedure. Rietveld refinement has shown that powder XRD patterns of such compounds are largely dominated by the positions of the heavy elements, pointing to isostructural networks for all four terephthalate-based materials. An in-depth luminescence study has been performed on the reported MOFs, showing rare praseodymium and samarium emission in the visible spectrum, aside from the strong europium luminescence and the near-infrared emission from both a terephthalate and 2,5-pyridinedicarboxylate based neodymium-MOF.},
  author       = {Decadt, Roel and Van Hecke, Kristof and Depla, Diederik and Leus, Karen and Weinberger, David and Van Driessche, Isabel and Van Der Voort, Pascal and Van Deun, Rik},
  issn         = {0020-1669},
  journal      = {INORGANIC CHEMISTRY},
  keyword      = {STORAGE,SOLIDS,COMPLEXES,DESIGN,PHOTOLUMINESCENCE,RETICULAR CHEMISTRY,LANTHANIDE AQUO IONS,ELECTRONIC ENERGY LEVELS,SECONDARY BUILDING UNITS,METAL-ORGANIC FRAMEWORKS},
  language     = {eng},
  number       = {21},
  pages        = {11623--11634},
  title        = {Synthesis, crystal structures, and luminescence properties of carboxylate based rare-earth coordination polymers},
  url          = {http://dx.doi.org/10.1021/ic301544q},
  volume       = {51},
  year         = {2012},
}

Chicago
Decadt, Roel, Kristof Van Hecke, Diederik Depla, Karen Leus, David Weinberger, Isabel Van Driessche, Pascal Van Der Voort, and Rik Van Deun. 2012. “Synthesis, Crystal Structures, and Luminescence Properties of Carboxylate Based Rare-earth Coordination Polymers.” Inorganic Chemistry 51 (21): 11623–11634.
APA
Decadt, R., Van Hecke, K., Depla, D., Leus, K., Weinberger, D., Van Driessche, I., Van Der Voort, P., et al. (2012). Synthesis, crystal structures, and luminescence properties of carboxylate based rare-earth coordination polymers. INORGANIC CHEMISTRY, 51(21), 11623–11634.
Vancouver
1.
Decadt R, Van Hecke K, Depla D, Leus K, Weinberger D, Van Driessche I, et al. Synthesis, crystal structures, and luminescence properties of carboxylate based rare-earth coordination polymers. INORGANIC CHEMISTRY. 2012;51(21):11623–34.
MLA
Decadt, Roel, Kristof Van Hecke, Diederik Depla, et al. “Synthesis, Crystal Structures, and Luminescence Properties of Carboxylate Based Rare-earth Coordination Polymers.” INORGANIC CHEMISTRY 51.21 (2012): 11623–11634. Print.