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Imidazolium end-functionalized ATRP polymers as directing agents for CNT dispersion and confinement

Bart Dervaux (UGent) , Franck Meyer, Jean-Marie Raquez, Aurore Olivier, Filip Du Prez (UGent) and Philippe Dubois
(2012) MACROMOLECULAR CHEMISTRY AND PHYSICS. 213(12). p.1259-1265
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Abstract
Imidazolium end-functionalized poly(butyl acrylate) and polystyrene (co)polymers (Im-PnBuA, Im-PSty, and Im-PnBuA-b-PSty are synthesized via ATRP. The controlled character of the polymerization reactions is highlighted by SEC and MALDI-TOF MS analyses. Subsequently, the polymers are tested as dispersing/compatibilizing agents for CNTs in polymer matrices. When CNTs are challenged with a mixture of Im-PnBuA and Im-PSty, the CNTs are mainly located in the PnBuA phase. In contrast, the Im-PnBuA-b-PSty block copolymer enables CNT confinement in the PSty phase. By selecting the proper ?-imidazolium polymer, it is possible to direct the CNT confinement toward a specific polymer phase within polymer mixtures.
Keywords
poly(butyl acrylate), polystyrene, ionic liquid, supramolecular structures, carbon nanotubes, METHYL-METHACRYLATE, WALLED CARBON NANOTUBES, IONIC LIQUID, POLYMERIZATION

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MLA
Dervaux, Bart et al. “Imidazolium End-functionalized ATRP Polymers as Directing Agents for CNT Dispersion and Confinement.” MACROMOLECULAR CHEMISTRY AND PHYSICS 213.12 (2012): 1259–1265. Print.
APA
Dervaux, B., Meyer, F., Raquez, J.-M., Olivier, A., Du Prez, F., & Dubois, P. (2012). Imidazolium end-functionalized ATRP polymers as directing agents for CNT dispersion and confinement. MACROMOLECULAR CHEMISTRY AND PHYSICS, 213(12), 1259–1265.
Chicago author-date
Dervaux, Bart, Franck Meyer, Jean-Marie Raquez, Aurore Olivier, Filip Du Prez, and Philippe Dubois. 2012. “Imidazolium End-functionalized ATRP Polymers as Directing Agents for CNT Dispersion and Confinement.” Macromolecular Chemistry and Physics 213 (12): 1259–1265.
Chicago author-date (all authors)
Dervaux, Bart, Franck Meyer, Jean-Marie Raquez, Aurore Olivier, Filip Du Prez, and Philippe Dubois. 2012. “Imidazolium End-functionalized ATRP Polymers as Directing Agents for CNT Dispersion and Confinement.” Macromolecular Chemistry and Physics 213 (12): 1259–1265.
Vancouver
1.
Dervaux B, Meyer F, Raquez J-M, Olivier A, Du Prez F, Dubois P. Imidazolium end-functionalized ATRP polymers as directing agents for CNT dispersion and confinement. MACROMOLECULAR CHEMISTRY AND PHYSICS. 2012;213(12):1259–65.
IEEE
[1]
B. Dervaux, F. Meyer, J.-M. Raquez, A. Olivier, F. Du Prez, and P. Dubois, “Imidazolium end-functionalized ATRP polymers as directing agents for CNT dispersion and confinement,” MACROMOLECULAR CHEMISTRY AND PHYSICS, vol. 213, no. 12, pp. 1259–1265, 2012.
@article{2980318,
  abstract     = {Imidazolium end-functionalized poly(butyl acrylate) and polystyrene (co)polymers (Im-PnBuA, Im-PSty, and Im-PnBuA-b-PSty are synthesized via ATRP. The controlled character of the polymerization reactions is highlighted by SEC and MALDI-TOF MS analyses. Subsequently, the polymers are tested as dispersing/compatibilizing agents for CNTs in polymer matrices. When CNTs are challenged with a mixture of Im-PnBuA and Im-PSty, the CNTs are mainly located in the PnBuA phase. In contrast, the Im-PnBuA-b-PSty block copolymer enables CNT confinement in the PSty phase. By selecting the proper ?-imidazolium polymer, it is possible to direct the CNT confinement toward a specific polymer phase within polymer mixtures.},
  author       = {Dervaux, Bart and Meyer, Franck and Raquez, Jean-Marie and Olivier, Aurore and Du Prez, Filip and Dubois, Philippe},
  issn         = {1022-1352},
  journal      = {MACROMOLECULAR CHEMISTRY AND PHYSICS},
  keywords     = {poly(butyl acrylate),polystyrene,ionic liquid,supramolecular structures,carbon nanotubes,METHYL-METHACRYLATE,WALLED CARBON NANOTUBES,IONIC LIQUID,POLYMERIZATION},
  language     = {eng},
  number       = {12},
  pages        = {1259--1265},
  title        = {Imidazolium end-functionalized ATRP polymers as directing agents for CNT dispersion and confinement},
  url          = {http://dx.doi.org/10.1002/macp.201200103},
  volume       = {213},
  year         = {2012},
}
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