Imidazolium end-functionalized ATRP polymers as directing agents for CNT dispersion and confinement
- Author
- Bart Dervaux (UGent) , Franck Meyer, Jean-Marie Raquez, Aurore Olivier, Filip Du Prez (UGent) and Philippe Dubois
- Organization
- Abstract
- Imidazolium end-functionalized poly(butyl acrylate) and polystyrene (co)polymers (Im-PnBuA, Im-PSty, and Im-PnBuA-b-PSty are synthesized via ATRP. The controlled character of the polymerization reactions is highlighted by SEC and MALDI-TOF MS analyses. Subsequently, the polymers are tested as dispersing/compatibilizing agents for CNTs in polymer matrices. When CNTs are challenged with a mixture of Im-PnBuA and Im-PSty, the CNTs are mainly located in the PnBuA phase. In contrast, the Im-PnBuA-b-PSty block copolymer enables CNT confinement in the PSty phase. By selecting the proper ?-imidazolium polymer, it is possible to direct the CNT confinement toward a specific polymer phase within polymer mixtures.
- Keywords
- poly(butyl acrylate), polystyrene, ionic liquid, supramolecular structures, carbon nanotubes, METHYL-METHACRYLATE, WALLED CARBON NANOTUBES, IONIC LIQUID, POLYMERIZATION
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Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-2980318
- MLA
- Dervaux, Bart, et al. “Imidazolium End-Functionalized ATRP Polymers as Directing Agents for CNT Dispersion and Confinement.” MACROMOLECULAR CHEMISTRY AND PHYSICS, vol. 213, no. 12, 2012, pp. 1259–65, doi:10.1002/macp.201200103.
- APA
- Dervaux, B., Meyer, F., Raquez, J.-M., Olivier, A., Du Prez, F., & Dubois, P. (2012). Imidazolium end-functionalized ATRP polymers as directing agents for CNT dispersion and confinement. MACROMOLECULAR CHEMISTRY AND PHYSICS, 213(12), 1259–1265. https://doi.org/10.1002/macp.201200103
- Chicago author-date
- Dervaux, Bart, Franck Meyer, Jean-Marie Raquez, Aurore Olivier, Filip Du Prez, and Philippe Dubois. 2012. “Imidazolium End-Functionalized ATRP Polymers as Directing Agents for CNT Dispersion and Confinement.” MACROMOLECULAR CHEMISTRY AND PHYSICS 213 (12): 1259–65. https://doi.org/10.1002/macp.201200103.
- Chicago author-date (all authors)
- Dervaux, Bart, Franck Meyer, Jean-Marie Raquez, Aurore Olivier, Filip Du Prez, and Philippe Dubois. 2012. “Imidazolium End-Functionalized ATRP Polymers as Directing Agents for CNT Dispersion and Confinement.” MACROMOLECULAR CHEMISTRY AND PHYSICS 213 (12): 1259–1265. doi:10.1002/macp.201200103.
- Vancouver
- 1.Dervaux B, Meyer F, Raquez J-M, Olivier A, Du Prez F, Dubois P. Imidazolium end-functionalized ATRP polymers as directing agents for CNT dispersion and confinement. MACROMOLECULAR CHEMISTRY AND PHYSICS. 2012;213(12):1259–65.
- IEEE
- [1]B. Dervaux, F. Meyer, J.-M. Raquez, A. Olivier, F. Du Prez, and P. Dubois, “Imidazolium end-functionalized ATRP polymers as directing agents for CNT dispersion and confinement,” MACROMOLECULAR CHEMISTRY AND PHYSICS, vol. 213, no. 12, pp. 1259–1265, 2012.
@article{2980318,
abstract = {{Imidazolium end-functionalized poly(butyl acrylate) and polystyrene (co)polymers (Im-PnBuA, Im-PSty, and Im-PnBuA-b-PSty are synthesized via ATRP. The controlled character of the polymerization reactions is highlighted by SEC and MALDI-TOF MS analyses. Subsequently, the polymers are tested as dispersing/compatibilizing agents for CNTs in polymer matrices. When CNTs are challenged with a mixture of Im-PnBuA and Im-PSty, the CNTs are mainly located in the PnBuA phase. In contrast, the Im-PnBuA-b-PSty block copolymer enables CNT confinement in the PSty phase. By selecting the proper ?-imidazolium polymer, it is possible to direct the CNT confinement toward a specific polymer phase within polymer mixtures.}},
author = {{Dervaux, Bart and Meyer, Franck and Raquez, Jean-Marie and Olivier, Aurore and Du Prez, Filip and Dubois, Philippe}},
issn = {{1022-1352}},
journal = {{MACROMOLECULAR CHEMISTRY AND PHYSICS}},
keywords = {{poly(butyl acrylate),polystyrene,ionic liquid,supramolecular structures,carbon nanotubes,METHYL-METHACRYLATE,WALLED CARBON NANOTUBES,IONIC LIQUID,POLYMERIZATION}},
language = {{eng}},
number = {{12}},
pages = {{1259--1265}},
title = {{Imidazolium end-functionalized ATRP polymers as directing agents for CNT dispersion and confinement}},
url = {{http://dx.doi.org/10.1002/macp.201200103}},
volume = {{213}},
year = {{2012}},
}
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