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Enhanced selectivity for the hydrolysis of block copoly(2-oxazoline)s in ethanol-water resulting in linear poly(ethylene imine) copolymers

Huub PC van Kuringen, Victor Retamero De La Rosa UGent, Martin WM Fijten, Johan PA Heuts and Richard Hoogenboom UGent (2012) MACROMOLECULAR RAPID COMMUNICATIONS. 33(9). p.827-832
abstract
The ability of merging the properties of poly(2-oxazoline)s and poly(ethylene imine) is of high interest for various biomedical applications, including gene delivery, biosensors, and switchable surfaces and nanoparticles. In the present research, a methodology for the controlled and selective hydrolysis of (co)poly(2-oxazoline)s is developed in an ethanolwater solvent mixture, opening the path toward a wide range of block poly(2-oxazoline-co-ethylene imine) (POx-PEI) copolymers with tunable properties. The unexpected influence of the selected ethanolwater binary solvent mixture on the hydrolysis kinetics and selectivity is highlighted in the pursue of well-defined POx-PEI block copolymers.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
block copolymers, biological applications of polymers, controlled hydrolysis, linear poly(ethylenimine)s, poly(2-oxazoline)s, DNA TRANSFECTION, IN-VIVO, POLYETHYLENIMINE, MIXTURES, DERIVATIVES, GENE, POLY(2-OXAZOLINE)S, POLYMERIZATION, DELIVERY, VECTOR
journal title
MACROMOLECULAR RAPID COMMUNICATIONS
Macromol. Rapid Commun.
volume
33
issue
9
pages
827 - 832
Web of Science type
Article
Web of Science id
000303743600016
JCR category
POLYMER SCIENCE
JCR impact factor
4.929 (2012)
JCR rank
6/82 (2012)
JCR quartile
1 (2012)
ISSN
1022-1336
DOI
10.1002/marc.201200046
language
English
UGent publication?
yes
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
2912887
handle
http://hdl.handle.net/1854/LU-2912887
date created
2012-06-20 08:54:07
date last changed
2012-07-05 15:12:13
@article{2912887,
  abstract     = {The ability of merging the properties of poly(2-oxazoline)s and poly(ethylene imine) is of high interest for various biomedical applications, including gene delivery, biosensors, and switchable surfaces and nanoparticles. In the present research, a methodology for the controlled and selective hydrolysis of (co)poly(2-oxazoline)s is developed in an ethanolwater solvent mixture, opening the path toward a wide range of block poly(2-oxazoline-co-ethylene imine) (POx-PEI) copolymers with tunable properties. The unexpected influence of the selected ethanolwater binary solvent mixture on the hydrolysis kinetics and selectivity is highlighted in the pursue of well-defined POx-PEI block copolymers.},
  author       = {van Kuringen, Huub PC and Retamero De La Rosa, Victor and Fijten, Martin WM and Heuts, Johan PA and Hoogenboom, Richard},
  issn         = {1022-1336},
  journal      = {MACROMOLECULAR RAPID COMMUNICATIONS},
  keyword      = {block copolymers,biological applications of polymers,controlled hydrolysis,linear poly(ethylenimine)s,poly(2-oxazoline)s,DNA TRANSFECTION,IN-VIVO,POLYETHYLENIMINE,MIXTURES,DERIVATIVES,GENE,POLY(2-OXAZOLINE)S,POLYMERIZATION,DELIVERY,VECTOR},
  language     = {eng},
  number       = {9},
  pages        = {827--832},
  title        = {Enhanced selectivity for the hydrolysis of block copoly(2-oxazoline)s in ethanol-water resulting in linear poly(ethylene imine) copolymers},
  url          = {http://dx.doi.org/10.1002/marc.201200046},
  volume       = {33},
  year         = {2012},
}

Chicago
van Kuringen, Huub PC, Victor Retamero De La Rosa, Martin WM Fijten, Johan PA Heuts, and Richard Hoogenboom. 2012. “Enhanced Selectivity for the Hydrolysis of Block Copoly(2-oxazoline)s in Ethanol-water Resulting in Linear Poly(ethylene Imine) Copolymers.” Macromolecular Rapid Communications 33 (9): 827–832.
APA
van Kuringen, H. P., Retamero De La Rosa, V., Fijten, M. W., Heuts, J. P., & Hoogenboom, R. (2012). Enhanced selectivity for the hydrolysis of block copoly(2-oxazoline)s in ethanol-water resulting in linear poly(ethylene imine) copolymers. MACROMOLECULAR RAPID COMMUNICATIONS, 33(9), 827–832.
Vancouver
1.
van Kuringen HP, Retamero De La Rosa V, Fijten MW, Heuts JP, Hoogenboom R. Enhanced selectivity for the hydrolysis of block copoly(2-oxazoline)s in ethanol-water resulting in linear poly(ethylene imine) copolymers. MACROMOLECULAR RAPID COMMUNICATIONS. 2012;33(9):827–32.
MLA
van Kuringen, Huub PC, Victor Retamero De La Rosa, Martin WM Fijten, et al. “Enhanced Selectivity for the Hydrolysis of Block Copoly(2-oxazoline)s in Ethanol-water Resulting in Linear Poly(ethylene Imine) Copolymers.” MACROMOLECULAR RAPID COMMUNICATIONS 33.9 (2012): 827–832. Print.