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Structure of dinitrato(2-thia-5,8-diazaoctane)copper II

Author
Organization
Abstract
[Cu(NO3)2(C5H14N2S)], M(r) = 321.79, orthorhombic, P2(1)2(1)2(1), a = 14.883 (4), b = 8.936 (3), c = 8.917 (3) angstrom, V = 1185.9 (6) angstrom3, Z = 4, D(m) = 1.79, D(x) = 1.802 g cm-3, lambda(Mo K-alpha) = 0.7107 angstrom, mu = 20.362 cm-1, F(000) = 660, room temperature, R = 0.036, wR = 0.038 for 2201 reflections with I greater-than-or-equal-to 3-sigma(I). The structure consists of monomeric molecules [Cu{2,2-NNS(Me)}(NO3)2], where 2,2-NNS(Me) = 2-thia-5,8-diazaoctane. The coordination polyhedron of Cu(II) is a tetragonal bipyramid: the tridentate, meridionally coordinated 2,2-NNS(Me) ligand, one bidentate and one monodentate nitrate ligand form a [CuN2O3S] chromophore.
Keywords
NITROGEN CHELATING-AGENTS, COPPER(II) COMPLEXES

Citation

Please use this url to cite or link to this publication:

MLA
Koman, M, D Valigura, G Ondrejovic, et al. “Structure of Dinitrato(2-thia-5,8-diazaoctane)copper II.” ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS 47.6 (1991): 1202–1204. Print.
APA
Koman, M., Valigura, D., Ondrejovic, G., Goeminne, A., Herman, G., & Van Der Kelen, G. (1991). Structure of dinitrato(2-thia-5,8-diazaoctane)copper II. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 47(6), 1202–1204.
Chicago author-date
Koman, M, D Valigura, G Ondrejovic, André Goeminne, Gerrit Herman, and Gustaaf Van Der Kelen. 1991. “Structure of Dinitrato(2-thia-5,8-diazaoctane)copper II.” Acta Crystallographica Section C-crystal Structure Communications 47 (6): 1202–1204.
Chicago author-date (all authors)
Koman, M, D Valigura, G Ondrejovic, André Goeminne, Gerrit Herman, and Gustaaf Van Der Kelen. 1991. “Structure of Dinitrato(2-thia-5,8-diazaoctane)copper II.” Acta Crystallographica Section C-crystal Structure Communications 47 (6): 1202–1204.
Vancouver
1.
Koman M, Valigura D, Ondrejovic G, Goeminne A, Herman G, Van Der Kelen G. Structure of dinitrato(2-thia-5,8-diazaoctane)copper II. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS. 1991;47(6):1202–4.
IEEE
[1]
M. Koman, D. Valigura, G. Ondrejovic, A. Goeminne, G. Herman, and G. Van Der Kelen, “Structure of dinitrato(2-thia-5,8-diazaoctane)copper II,” ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, vol. 47, no. 6, pp. 1202–1204, 1991.
@article{221046,
  abstract     = {[Cu(NO3)2(C5H14N2S)], M(r) = 321.79, orthorhombic, P2(1)2(1)2(1), a = 14.883 (4), b = 8.936 (3), c = 8.917 (3) angstrom, V = 1185.9 (6) angstrom3, Z = 4, D(m) = 1.79, D(x) = 1.802 g cm-3, lambda(Mo K-alpha) = 0.7107 angstrom, mu = 20.362 cm-1, F(000) = 660, room temperature, R = 0.036, wR = 0.038 for 2201 reflections with I greater-than-or-equal-to 3-sigma(I). The structure consists of monomeric molecules [Cu{2,2-NNS(Me)}(NO3)2], where 2,2-NNS(Me) = 2-thia-5,8-diazaoctane. The coordination polyhedron of Cu(II) is a tetragonal bipyramid: the tridentate, meridionally coordinated 2,2-NNS(Me) ligand, one bidentate and one monodentate nitrate ligand form a [CuN2O3S] chromophore.},
  author       = {Koman, M and Valigura, D and Ondrejovic, G and Goeminne, André and Herman, Gerrit and Van Der Kelen, Gustaaf},
  issn         = {0108-2701},
  journal      = {ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS},
  keywords     = {NITROGEN CHELATING-AGENTS,COPPER(II) COMPLEXES},
  language     = {eng},
  number       = {6},
  pages        = {1202--1204},
  title        = {Structure of dinitrato(2-thia-5,8-diazaoctane)copper II},
  url          = {http://dx.doi.org/10.1107/S0108270190013919},
  volume       = {47},
  year         = {1991},
}

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