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Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III)

Rik Van Deun UGent, Pascal Van Der Voort UGent, Isabel Van Driessche UGent and Kristof Van Hecke UGent (2012) ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE. 68(2). p.m111-m112
abstract
The title compound, (C8H20N)[Tb(C5HF6O2)(4)], is a tetrakis beta-diketonate complex of hexafluoroacetylacetone with terbium(III), and tetraethylammonium as the counter-ion. This compound shows typical green terbium(III) luminescence upon excitation at about 335 nm. The coordination geometry around the Tb-III atom is a slightly distorted square antiprism. One hexafluoroacetylacetone ligand has a disordered CF3 group [occupancies of 0.575 (4) and 0.425 (4)]. A three-dimensional network is built up by linkage of Tb-III complexes via C-H center dot center dot center dot F interactions.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
COMPLEXES, NEAR-INFRARED PHOTOLUMINESCENCE
journal title
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
Acta Crystallogr. Sect. E.-Struct Rep. Online
volume
68
issue
2
pages
m111 - m112
Web of Science type
Article
Web of Science id
000301059000021
ISSN
1600-5368
DOI
10.1107/S1600536811055437
project
GOA 01G00710
language
English
UGent publication?
yes
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
2077615
handle
http://hdl.handle.net/1854/LU-2077615
date created
2012-03-30 10:40:42
date last changed
2012-04-03 14:07:04
@article{2077615,
  abstract     = {The title compound, (C8H20N)[Tb(C5HF6O2)(4)], is a tetrakis beta-diketonate complex of hexafluoroacetylacetone with terbium(III), and tetraethylammonium as the counter-ion. This compound shows typical green terbium(III) luminescence upon excitation at about 335 nm. The coordination geometry around the Tb-III atom is a slightly distorted square antiprism. One hexafluoroacetylacetone ligand has a disordered CF3 group [occupancies of 0.575 (4) and 0.425 (4)]. A three-dimensional network is built up by linkage of Tb-III complexes via C-H center dot center dot center dot F interactions.},
  author       = {Van Deun, Rik and Van Der Voort, Pascal and Van Driessche, Isabel and Van Hecke, Kristof},
  issn         = {1600-5368},
  journal      = {ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE},
  keyword      = {COMPLEXES,NEAR-INFRARED PHOTOLUMINESCENCE},
  language     = {eng},
  number       = {2},
  pages        = {m111--m112},
  title        = {Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III)},
  url          = {http://dx.doi.org/10.1107/S1600536811055437},
  volume       = {68},
  year         = {2012},
}

Chicago
Van Deun, Rik, Pascal Van Der Voort, Isabel Van Driessche, and Kristof Van Hecke. 2012. “Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III).” Acta Crystallographica Section E-structure Reports Online 68 (2): m111–m112.
APA
Van Deun, R., Van Der Voort, P., Van Driessche, I., & Van Hecke, K. (2012). Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III). ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 68(2), m111–m112.
Vancouver
1.
Van Deun R, Van Der Voort P, Van Driessche I, Van Hecke K. Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III). ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE. 2012;68(2):m111–m112.
MLA
Van Deun, Rik, Pascal Van Der Voort, Isabel Van Driessche, et al. “Tetraethylammonium tetrakis(1,1,1,5,5,5-hexafluoroacetylacetonato)terbate(III).” ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE 68.2 (2012): m111–m112. Print.