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Synthesis of the azocino[cd]indole framework through Pd-catalyzed intramolecular acetylene hydroarylation

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Abstract
The regio- and stereoselective construction of the azocino[cd]indole core was achieved by applying a Pd-catalyzed intramolecular acetylene hydroarylation protocol. The applicability of a similar strategy for the synthesis of the azepino[b]indole framework is demonstrated.
Keywords
Cyclization, C-C coupling, Nitrogen heterocycles, Medium-ring compounds, Palladium, CYCLIZATION, ALKALOIDS, HECK, EFFICIENT, ALKYNES, INDOLES, ANALOGS, GOLD

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Chicago
Peshkov, Vsevolod A, Sofie Van Hove, Pavel A Donets, Olga P Pereshivko, Kristof Van Hecke, Luc Van Meervelt, and Erik V Van der Eycken. 2011. “Synthesis of the Azocino[cd]indole Framework Through Pd-catalyzed Intramolecular Acetylene Hydroarylation.” European Journal of Inorganic Chemistry (10): 1837–1840.
APA
Peshkov, V. A., Van Hove, S., Donets, P. A., Pereshivko, O. P., Van Hecke, K., Van Meervelt, L., & Van der Eycken, E. V. (2011). Synthesis of the azocino[cd]indole framework through Pd-catalyzed intramolecular acetylene hydroarylation. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (10), 1837–1840.
Vancouver
1.
Peshkov VA, Van Hove S, Donets PA, Pereshivko OP, Van Hecke K, Van Meervelt L, et al. Synthesis of the azocino[cd]indole framework through Pd-catalyzed intramolecular acetylene hydroarylation. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2011;(10):1837–40.
MLA
Peshkov, Vsevolod A, Sofie Van Hove, Pavel A Donets, et al. “Synthesis of the Azocino[cd]indole Framework Through Pd-catalyzed Intramolecular Acetylene Hydroarylation.” EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 10 (2011): 1837–1840. Print.
@article{2045505,
  abstract     = {The regio- and stereoselective construction of the azocino[cd]indole core was achieved by applying a Pd-catalyzed intramolecular acetylene hydroarylation protocol. The applicability of a similar strategy for the synthesis of the azepino[b]indole framework is demonstrated.},
  author       = {Peshkov, Vsevolod A and Van Hove, Sofie and Donets, Pavel A and Pereshivko, Olga P and Van Hecke, Kristof and Van Meervelt, Luc and Van der Eycken, Erik V},
  issn         = {1434-193X},
  journal      = {EUROPEAN JOURNAL OF INORGANIC CHEMISTRY},
  keyword      = {Cyclization,C-C coupling,Nitrogen heterocycles,Medium-ring compounds,Palladium,CYCLIZATION,ALKALOIDS,HECK,EFFICIENT,ALKYNES,INDOLES,ANALOGS,GOLD},
  language     = {eng},
  number       = {10},
  pages        = {1837--1840},
  title        = {Synthesis of the azocino[cd]indole framework through Pd-catalyzed intramolecular acetylene hydroarylation},
  url          = {http://dx.doi.org/10.1002/ejoc.201001669},
  year         = {2011},
}

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