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Use of the simplified generalized standard additions method for calibration in solid sampling electrothermal vaporization inductively coupled plasma atomic emission-spectrometry

Sylvie Boonen (UGent) , Peter Verrept, Luc Moens (UGent) and Richard Dams (UGent)
Author
Organization
Abstract
To find a useful calibration strategy for the direct analysis of solid samples by electrothermal vaporization inductively coupled plasma atomic emission spectrometry (ETV-ICP-AES), the simplified generalized standard additions method was investigated. This method leads, by varying both the mass of the solid sample and the amount of analyte (standard solution) added, to a response surface from which the analyte concentration can be deducted by multiple linear regression. The analytical results obtained for Cu, Pb and Cd determinations in a number of biological and environmental reference materials are in good agreement with the certified values. The number of data points required to yield precise results (typical RSD<10%) depends on the sample homogeneity.
Keywords
ELECTROTHERMAL VAPORIZATION, INDUCTIVELY COUPLED PLASMA ATOMIC EMISSION SPECTROMETRY, SOLID SAMPLES, CALIBRATION, STANDARD ADDITIONS

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Chicago
Boonen, Sylvie, Peter Verrept, Luc Moens, and Richard Dams. 1993. “Use of the Simplified Generalized Standard Additions Method for Calibration in Solid Sampling Electrothermal Vaporization Inductively Coupled Plasma Atomic Emission-spectrometry.” Journal of Analytical Atomic Spectrometry 8 (5): 711–714.
APA
Boonen, Sylvie, Verrept, P., Moens, L., & Dams, R. (1993). Use of the simplified generalized standard additions method for calibration in solid sampling electrothermal vaporization inductively coupled plasma atomic emission-spectrometry. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 8(5), 711–714.
Vancouver
1.
Boonen S, Verrept P, Moens L, Dams R. Use of the simplified generalized standard additions method for calibration in solid sampling electrothermal vaporization inductively coupled plasma atomic emission-spectrometry. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY. 1993;8(5):711–4.
MLA
Boonen, Sylvie, Peter Verrept, Luc Moens, et al. “Use of the Simplified Generalized Standard Additions Method for Calibration in Solid Sampling Electrothermal Vaporization Inductively Coupled Plasma Atomic Emission-spectrometry.” JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY 8.5 (1993): 711–714. Print.
@article{203108,
  abstract     = {To find a useful calibration strategy for the direct analysis of solid samples by electrothermal vaporization inductively coupled plasma atomic emission spectrometry (ETV-ICP-AES), the simplified generalized standard additions method was investigated. This method leads, by varying both the mass of the solid sample and the amount of analyte (standard solution) added, to a response surface from which the analyte concentration can be deducted by multiple linear regression. The analytical results obtained for Cu, Pb and Cd determinations in a number of biological and environmental reference materials are in good agreement with the certified values. The number of data points required to yield precise results (typical RSD{\textlangle}10\%) depends on the sample homogeneity.},
  author       = {Boonen, Sylvie and Verrept, Peter and Moens, Luc and Dams, Richard},
  issn         = {0267-9477},
  journal      = {JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY},
  keyword      = {ELECTROTHERMAL VAPORIZATION,INDUCTIVELY COUPLED PLASMA ATOMIC EMISSION SPECTROMETRY,SOLID SAMPLES,CALIBRATION,STANDARD ADDITIONS},
  language     = {eng},
  number       = {5},
  pages        = {711--714},
  title        = {Use of the simplified generalized standard additions method for calibration in solid sampling electrothermal vaporization inductively coupled plasma atomic emission-spectrometry},
  url          = {http://dx.doi.org/10.1039/ja9930800711},
  volume       = {8},
  year         = {1993},
}

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