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Synthesis, structural characterization, and catalytic performance of a vanadium-based metal–organic framework (COMOC-3)

Ying-Ya Liu UGent, Karen Leus UGent, Maciej Grzywa, David Weinberger UGent, Katrien Strubbe UGent, Henk Vrielinck UGent, Rik Van Deun UGent, Dirk Volkmer, Veronique Van Speybroeck UGent and Pascal Van Der Voort UGent (2012) EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2012(16). p.2819-2827
abstract
A vanadium 2,6-naphthalenedicarboxylate, VIII(OH)(O2C–C10H6–CO2)·H2O, denoted as COMOC-3as (COMOC = Center for Ordered Materials, Organometallics and Catalysis, Ghent University), has been synthesized under hydrothermal conditions by means of both a solvothermal and a microwave synthesis procedure. The structure shows the topology of an aluminium 2,6-naphthalenedicarboxylate, the so-called MIL-69 (MIL = Materials of the Institute Lavoisier). After calcination at 250 °C in air, the VIII center was oxidized to VIV with the structure of VIVO(O2C–C10H6–CO2) (COMOC-3). The oxidation process was verified by cyclic voltammetry and EPR spectroscopy. The crystallinity was investigated by variable-temperature XRD. The title compound is stable against air and moisture. The catalytic performance of COMOC-3 was examined in the liquid-phase oxidation of cyclohexene. COMOC-3 exhibited similar catalytic performance to MIL-47 [VO(O2C–C6H4–CO2)]. The compound is reusable and maintains its catalytic activity through several runs.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
-Vanadium, Metal-organic frameworks, Oxidation, Heterogeneous -catalysis, HYDROCARBON ADSORPTION, MIL-53(AL, OXIDATION, BENZENEDICARBOXYLATE, CONVERSION, MIL-47(V), ACID, CR
journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Eur. J. Inorg. Chem.
volume
2012
issue
16
issue title
Trends in advanced complex inorganic nanomaterials
pages
2819 - 2827
Web of Science type
Article
Web of Science id
000304089700030
JCR category
CHEMISTRY, INORGANIC & NUCLEAR
JCR impact factor
3.12 (2012)
JCR rank
11/43 (2012)
JCR quartile
2 (2012)
ISSN
1434-1948
DOI
10.1002/ejic.201101099
language
English
UGent publication?
yes
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
2019727
handle
http://hdl.handle.net/1854/LU-2019727
date created
2012-02-05 13:05:21
date last changed
2012-06-07 12:39:46
@article{2019727,
  abstract     = {A vanadium 2,6-naphthalenedicarboxylate, VIII(OH)(O2C--C10H6--CO2){\textperiodcentered}H2O, denoted as COMOC-3as (COMOC = Center for Ordered Materials, Organometallics and Catalysis, Ghent University), has been synthesized under hydrothermal conditions by means of both a solvothermal and a microwave synthesis procedure. The structure shows the topology of an aluminium 2,6-naphthalenedicarboxylate, the so-called MIL-69 (MIL = Materials of the Institute Lavoisier). After calcination at 250 {\textdegree}C in air, the VIII center was oxidized to VIV with the structure of VIVO(O2C--C10H6--CO2) (COMOC-3). The oxidation process was verified by cyclic voltammetry and EPR spectroscopy. The crystallinity was investigated by variable-temperature XRD. The title compound is stable against air and moisture. The catalytic performance of COMOC-3 was examined in the liquid-phase oxidation of cyclohexene. COMOC-3 exhibited similar catalytic performance to MIL-47 [VO(O2C--C6H4--CO2)]. The compound is reusable and maintains its catalytic activity through several runs.},
  author       = {Liu, Ying-Ya and Leus, Karen and Grzywa,  Maciej  and Weinberger, David and Strubbe, Katrien and Vrielinck, Henk and Van Deun, Rik and Volkmer, Dirk and Van Speybroeck, Veronique and Van Der Voort, Pascal},
  issn         = {1434-1948},
  journal      = {EUROPEAN JOURNAL OF INORGANIC CHEMISTRY},
  keyword      = {-Vanadium,Metal-organic frameworks,Oxidation,Heterogeneous -catalysis,HYDROCARBON ADSORPTION,MIL-53(AL,OXIDATION,BENZENEDICARBOXYLATE,CONVERSION,MIL-47(V),ACID,CR},
  language     = {eng},
  number       = {16},
  pages        = {2819--2827},
  title        = {Synthesis, structural characterization, and catalytic performance of a vanadium-based metal--organic framework (COMOC-3)},
  url          = {http://dx.doi.org/10.1002/ejic.201101099},
  volume       = {2012},
  year         = {2012},
}

Chicago
Liu, Ying-Ya, Karen Leus, Maciej Grzywa, David Weinberger, Katrien Strubbe, Henk Vrielinck, Rik Van Deun, Dirk Volkmer, Veronique Van Speybroeck, and Pascal Van Der Voort. 2012. “Synthesis, Structural Characterization, and Catalytic Performance of a Vanadium-based Metal–organic Framework (COMOC-3).” European Journal of Inorganic Chemistry 2012 (16): 2819–2827.
APA
Liu, Y.-Y., Leus, K., Grzywa, M., Weinberger, D., Strubbe, K., Vrielinck, H., Van Deun, R., et al. (2012). Synthesis, structural characterization, and catalytic performance of a vanadium-based metal–organic framework (COMOC-3). EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012(16), 2819–2827.
Vancouver
1.
Liu Y-Y, Leus K, Grzywa M, Weinberger D, Strubbe K, Vrielinck H, et al. Synthesis, structural characterization, and catalytic performance of a vanadium-based metal–organic framework (COMOC-3). EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2012;2012(16):2819–27.
MLA
Liu, Ying-Ya, Karen Leus, Maciej Grzywa, et al. “Synthesis, Structural Characterization, and Catalytic Performance of a Vanadium-based Metal–organic Framework (COMOC-3).” EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2012.16 (2012): 2819–2827. Print.