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Atomic layer deposition of titanium and vanadium oxide on mesoporous silica and phenol/formaldehyde resins: the effect of the support on the liquid phase epoxidation of cyclohexene

Ilke Muylaert UGent, Jan Musschoot UGent, Karen Leus UGent, Jolien Dendooven UGent, Christophe Detavernier UGent and Pascal Van Der Voort UGent (2012) EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. p.251-260
abstract
Titanium and vanadium oxide layers have been grown in the pores of two 2D hexagonal ordered mesoporous materials: SBA-15 (silica) and FDU-15 (phenol/formaldehyde resin). The deposition of the layers was controlled by the self-limiting reaction of the metal oxide precursor with the hydroxyl surface. Single, multiple and mixed titanium and vanadiumoxide layers have been synthesised, and the influence of the layer type on the catalytic performance in the liquid phase epoxidation of cyclohexene has been evaluated. The effect of the support on the catalytic behaviour is discussed, and a reaction mechanism is proposed. The support–oxygen–metal bond is assumed to be critical for catalytic epoxidation.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
Atomic layer deposition, Supported metal oxides, Epoxidation, Mesoporous materials, Heterogeneous catalysis
journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Eur. J. Inorg. Chem.
issue
2
pages
251 - 260
Web of Science type
Article
Web of Science id
000301489300012
JCR category
CHEMISTRY, INORGANIC & NUCLEAR
JCR impact factor
3.12 (2012)
JCR rank
11/43 (2012)
JCR quartile
2 (2012)
ISSN
1434-1948
DOI
10.1002/ejic.201101000
language
English
UGent publication?
yes
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
1980309
handle
http://hdl.handle.net/1854/LU-1980309
date created
2012-01-07 19:32:45
date last changed
2012-05-24 14:06:25
@article{1980309,
  abstract     = {Titanium and vanadium oxide layers have been grown in the pores of two 2D hexagonal ordered mesoporous materials: SBA-15 (silica) and FDU-15 (phenol/formaldehyde resin). The deposition of the layers was controlled by the self-limiting reaction of the metal oxide precursor with the hydroxyl surface. Single, multiple and mixed titanium and vanadiumoxide layers have been synthesised, and the influence of the layer type on the catalytic performance in the liquid phase epoxidation of cyclohexene has been evaluated. The effect of the support on the catalytic behaviour is discussed, and a reaction mechanism is proposed. The support--oxygen--metal bond is assumed to be critical for catalytic epoxidation.},
  author       = {Muylaert, Ilke and Musschoot, Jan and Leus, Karen and Dendooven, Jolien and Detavernier, Christophe and Van Der Voort, Pascal},
  issn         = {1434-1948},
  journal      = {EUROPEAN JOURNAL OF INORGANIC CHEMISTRY},
  keyword      = {Atomic layer deposition,Supported metal oxides,Epoxidation,Mesoporous materials,Heterogeneous catalysis},
  language     = {eng},
  number       = {2},
  pages        = {251--260},
  title        = {Atomic layer deposition of titanium and vanadium oxide on mesoporous silica and phenol/formaldehyde resins: the effect of the support on the liquid phase epoxidation of cyclohexene},
  url          = {http://dx.doi.org/10.1002/ejic.201101000},
  year         = {2012},
}

Chicago
Muylaert, Ilke, Jan Musschoot, Karen Leus, Jolien Dendooven, Christophe Detavernier, and Pascal Van Der Voort. 2012. “Atomic Layer Deposition of Titanium and Vanadium Oxide on Mesoporous Silica and Phenol/formaldehyde Resins: The Effect of the Support on the Liquid Phase Epoxidation of Cyclohexene.” European Journal of Inorganic Chemistry (2): 251–260.
APA
Muylaert, I., Musschoot, J., Leus, K., Dendooven, J., Detavernier, C., & Van Der Voort, P. (2012). Atomic layer deposition of titanium and vanadium oxide on mesoporous silica and phenol/formaldehyde resins: the effect of the support on the liquid phase epoxidation of cyclohexene. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (2), 251–260.
Vancouver
1.
Muylaert I, Musschoot J, Leus K, Dendooven J, Detavernier C, Van Der Voort P. Atomic layer deposition of titanium and vanadium oxide on mesoporous silica and phenol/formaldehyde resins: the effect of the support on the liquid phase epoxidation of cyclohexene. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2012;(2):251–60.
MLA
Muylaert, Ilke, Jan Musschoot, Karen Leus, et al. “Atomic Layer Deposition of Titanium and Vanadium Oxide on Mesoporous Silica and Phenol/formaldehyde Resins: The Effect of the Support on the Liquid Phase Epoxidation of Cyclohexene.” EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2 (2012): 251–260. Print.