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Poly(ethylene oxide)-b-poly(L-lactide) diblock copolymer/carbon nanotube-based nanocomposites : LiCl as supramolecular structure-directing agent

(2011) BIOMACROMOLECULES. 12(11). p.4086-4094
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Abstract
This work relies on the CNT dispersion in either solution or a polymer matrix through the formation of a three-component supramolecular system composed of PEO-b-PLLA diblock copolymer, carbon nanotubes (CNTs), and lithium chloride. According to a one-pot procedure in solution, the "self-assembly" concept has demonstrated its efficiency using suspension tests of CNTs. Characterizations of the supramolecular system by photon correlation spectroscopy, Raman spectroscopy, and molecular dynamics simulations highlight the charge transfer interaction from the CNTs toward the PEO-b-PLLA/LiCl complex. Finally, this concept was successfully extended in bulk (absence of solvent) via melt-processing techniques by dispersing these complexes in a commercial polylactide (PLA) matrix. Electrical conductivity measurements and transmission electron microscopy attested for the remarkable dispersion of CNTs, confirming the design of high-performance PLA-based materials.
Keywords
FUNCTIONALIZATION, WALLED CARBON NANOTUBES, CHEMISTRY

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Citation

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MLA
Meyer, Franck, et al. “Poly(Ethylene Oxide)-b-Poly(L-Lactide) Diblock Copolymer/Carbon Nanotube-Based Nanocomposites : LiCl as Supramolecular Structure-Directing Agent.” BIOMACROMOLECULES, vol. 12, no. 11, 2011, pp. 4086–94.
APA
Meyer, F., Raquez, J.-M., Verge, P., Martínez de Arenaza, I., Coto, B., Van Der Voort, P., … Dubois, P. (2011). Poly(ethylene oxide)-b-poly(L-lactide) diblock copolymer/carbon nanotube-based nanocomposites : LiCl as supramolecular structure-directing agent. BIOMACROMOLECULES, 12(11), 4086–4094.
Chicago author-date
Meyer, Franck, Jean-Marie Raquez, Pierre Verge, Inger Martínez de Arenaza, Borja Coto, Pascal Van Der Voort, Emilio Meaurio, et al. 2011. “Poly(Ethylene Oxide)-b-Poly(L-Lactide) Diblock Copolymer/Carbon Nanotube-Based Nanocomposites : LiCl as Supramolecular Structure-Directing Agent.” BIOMACROMOLECULES 12 (11): 4086–94.
Chicago author-date (all authors)
Meyer, Franck, Jean-Marie Raquez, Pierre Verge, Inger Martínez de Arenaza, Borja Coto, Pascal Van Der Voort, Emilio Meaurio, Bart Dervaux, Jose-Ramon Sarasua, Filip Du Prez, and Philippe Dubois. 2011. “Poly(Ethylene Oxide)-b-Poly(L-Lactide) Diblock Copolymer/Carbon Nanotube-Based Nanocomposites : LiCl as Supramolecular Structure-Directing Agent.” BIOMACROMOLECULES 12 (11): 4086–4094.
Vancouver
1.
Meyer F, Raquez J-M, Verge P, Martínez de Arenaza I, Coto B, Van Der Voort P, et al. Poly(ethylene oxide)-b-poly(L-lactide) diblock copolymer/carbon nanotube-based nanocomposites : LiCl as supramolecular structure-directing agent. BIOMACROMOLECULES. 2011;12(11):4086–94.
IEEE
[1]
F. Meyer et al., “Poly(ethylene oxide)-b-poly(L-lactide) diblock copolymer/carbon nanotube-based nanocomposites : LiCl as supramolecular structure-directing agent,” BIOMACROMOLECULES, vol. 12, no. 11, pp. 4086–4094, 2011.
@article{1967760,
  abstract     = {This work relies on the CNT dispersion in either solution or a polymer matrix through the formation of a three-component supramolecular system composed of PEO-b-PLLA diblock copolymer, carbon nanotubes (CNTs), and lithium chloride. According to a one-pot procedure in solution, the "self-assembly" concept has demonstrated its efficiency using suspension tests of CNTs. Characterizations of the supramolecular system by photon correlation spectroscopy, Raman spectroscopy, and molecular dynamics simulations highlight the charge transfer interaction from the CNTs toward the PEO-b-PLLA/LiCl complex. Finally, this concept was successfully extended in bulk (absence of solvent) via melt-processing techniques by dispersing these complexes in a commercial polylactide (PLA) matrix. Electrical conductivity measurements and transmission electron microscopy attested for the remarkable dispersion of CNTs, confirming the design of high-performance PLA-based materials.},
  author       = {Meyer, Franck and Raquez, Jean-Marie and Verge, Pierre and Martínez de Arenaza, Inger and Coto, Borja and Van Der Voort, Pascal and Meaurio, Emilio and Dervaux, Bart and Sarasua, Jose-Ramon and Du Prez, Filip and Dubois, Philippe},
  issn         = {1525-7797},
  journal      = {BIOMACROMOLECULES},
  keywords     = {FUNCTIONALIZATION,WALLED CARBON NANOTUBES,CHEMISTRY},
  language     = {eng},
  number       = {11},
  pages        = {4086--4094},
  title        = {Poly(ethylene oxide)-b-poly(L-lactide) diblock copolymer/carbon nanotube-based nanocomposites : LiCl as supramolecular structure-directing agent},
  url          = {http://dx.doi.org/10.1021/bm201149g},
  volume       = {12},
  year         = {2011},
}

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