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Solid sampling electrothermal vaporization for sample introduction in inductively coupled plasma atomic emission spectrometry and inductively coupled plasma mass spectrometry

Luc Moens (UGent) , Peter Verrept, Sylvie Boonen (UGent) , Frank Vanhaecke (UGent) and Richard Dams (UGent)
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Abstract
Solid sampling using electrothermal vaporization is an attractive sample introduction method for atomic absorption spectrometry (AAS), inductively coupled plasma atomic emission spectrometry (ICP-AES) and inductively coupled plasma mass spectrometry (ICP-MS). For AAS, the method is well; established. The techniques needed to apply SS-ETV in ICP-based methods are described, with the emphasis on the coupling of different types of ETV-devices to the inductively coupled plasma torch and on the requirements for the spectrometer and the data acquisition and handling system. Though standardization is not straightforward, it is shown that standard addition and external calibration with solid standards yield accurate results. The latter is demonstrated by the analysis of standard reference materials. Figures of merit for SS-ETV-ICP-AES and SS-ETV-ICP-MS are presented. The literature concerning ICP-AES and ICP-MS (methods and applications) is briefly reviewed and new results of SS-ETV-ICP-MS analysis of SRMs are presented.
Keywords
STANDARD ADDITIONS METHOD, PHOTODIODE ARRAY SPECTROMETER, ETV-ICP-AES, GRAPHITE-FURNACE, ABSORPTION SPECTROMETRY, INSERTION DEVICE, ARGON-PLASMA, PNEUMATIC NEBULIZER, LASER ABLATION, POWDER

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Citation

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Chicago
Moens, Luc, Peter Verrept, Sylvie Boonen, Frank Vanhaecke, and Richard Dams. 1995. “Solid Sampling Electrothermal Vaporization for Sample Introduction in Inductively Coupled Plasma Atomic Emission Spectrometry and Inductively Coupled Plasma Mass Spectrometry.” Spectrochimica Acta Part B-atomic Spectroscopy 50 (4-7): 463–475.
APA
Moens, L., Verrept, P., Boonen, S., Vanhaecke, F., & Dams, R. (1995). Solid sampling electrothermal vaporization for sample introduction in inductively coupled plasma atomic emission spectrometry and inductively coupled plasma mass spectrometry. SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 50(4-7), 463–475.
Vancouver
1.
Moens L, Verrept P, Boonen S, Vanhaecke F, Dams R. Solid sampling electrothermal vaporization for sample introduction in inductively coupled plasma atomic emission spectrometry and inductively coupled plasma mass spectrometry. SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY. 1995;50(4-7):463–75.
MLA
Moens, Luc, Peter Verrept, Sylvie Boonen, et al. “Solid Sampling Electrothermal Vaporization for Sample Introduction in Inductively Coupled Plasma Atomic Emission Spectrometry and Inductively Coupled Plasma Mass Spectrometry.” SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY 50.4-7 (1995): 463–475. Print.
@article{194187,
  abstract     = {Solid sampling using electrothermal vaporization is an attractive sample introduction method for atomic absorption spectrometry (AAS), inductively coupled plasma atomic emission spectrometry (ICP-AES) and inductively coupled plasma mass spectrometry (ICP-MS). For AAS, the method is well; established. The techniques needed to apply SS-ETV in ICP-based methods are described, with the emphasis on the coupling of different types of ETV-devices to the inductively coupled plasma torch and on the requirements for the spectrometer and the data acquisition and handling system. Though standardization is not straightforward, it is shown that standard addition and external calibration with solid standards yield accurate results. The latter is demonstrated by the analysis of standard reference materials. Figures of merit for SS-ETV-ICP-AES and SS-ETV-ICP-MS are presented. The literature concerning ICP-AES and ICP-MS (methods and applications) is briefly reviewed and new results of SS-ETV-ICP-MS analysis of SRMs are presented.},
  author       = {Moens, Luc and Verrept, Peter and Boonen, Sylvie and Vanhaecke, Frank and Dams, Richard},
  issn         = {0584-8547},
  journal      = {SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY},
  keyword      = {STANDARD ADDITIONS METHOD,PHOTODIODE ARRAY SPECTROMETER,ETV-ICP-AES,GRAPHITE-FURNACE,ABSORPTION SPECTROMETRY,INSERTION DEVICE,ARGON-PLASMA,PNEUMATIC NEBULIZER,LASER ABLATION,POWDER},
  language     = {eng},
  number       = {4-7},
  pages        = {463--475},
  title        = {Solid sampling electrothermal vaporization for sample introduction in inductively coupled plasma atomic emission spectrometry and inductively coupled plasma mass spectrometry},
  url          = {http://dx.doi.org/10.1016/0584-8547(94)00153-M},
  volume       = {50},
  year         = {1995},
}

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