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Synergy effects in mixed Bi2O3, MoO3 and V2O5 catalysts for selective oxidation of propylene

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Abstract
In this work, the possible synergy effects between Bi2O3, MoO3 and V2O5, and between Bi2Mo3O12 and BiVO4, were investigated. The catalytic activity of the "mechanical mixture" of these compounds was measured. The mixture containing 36.96 mol% Bi2O3, 39.13 mol% MoO3 and 23.91 mol% V2O5 (21.43 mol% Bi2Mo3O12 and 78.57 mol% BiVO4), corresponding to the compound Bi1-x/3V1-xMoxO4 with x = 0.45 (Bi0.85V0.55Mo0.45O4), exhibited the highest activity for the selective oxidation of propylene to acrolein. The mixed sample prepared chemically by a sol-gel method possessed higher activity than that of mechanical mixtures.
Keywords
Bismuth molybdate, Synergy effect, Bismuth vanado molybdate, Selective oxidation, Propylene, Acrolein, Mechanical mixture, Sol-gel, BISMUTH MOLYBDATE CATALYSTS, SCHEELITE STRUCTURE, METAL-OXIDES, AMMOXIDATION, SURFACE, MOLYBDOVANADATES, DEPOSITION, 1-BUTENE, BEHAVIOR, SYSTEM

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MLA
Nguyen, Tien The et al. “Synergy Effects in Mixed Bi2O3, MoO3 and V2O5 Catalysts for Selective Oxidation of Propylene.” RESEARCH ON CHEMICAL INTERMEDIATES 38 (2012): 829–846. Print.
APA
Nguyen, T. T., Le, T. M., Truong, D. D., Fehrmann, R., Riisager, A., & Van Driessche, I. (2012). Synergy effects in mixed Bi2O3, MoO3 and V2O5 catalysts for selective oxidation of propylene. RESEARCH ON CHEMICAL INTERMEDIATES, 38, 829–846.
Chicago author-date
Nguyen, Tien The, Thang Minh Le, Duc Duc Truong, Rasmus Fehrmann, Anders Riisager, and Isabel Van Driessche. 2012. “Synergy Effects in Mixed Bi2O3, MoO3 and V2O5 Catalysts for Selective Oxidation of Propylene.” Research on Chemical Intermediates 38: 829–846.
Chicago author-date (all authors)
Nguyen, Tien The, Thang Minh Le, Duc Duc Truong, Rasmus Fehrmann, Anders Riisager, and Isabel Van Driessche. 2012. “Synergy Effects in Mixed Bi2O3, MoO3 and V2O5 Catalysts for Selective Oxidation of Propylene.” Research on Chemical Intermediates 38: 829–846.
Vancouver
1.
Nguyen TT, Le TM, Truong DD, Fehrmann R, Riisager A, Van Driessche I. Synergy effects in mixed Bi2O3, MoO3 and V2O5 catalysts for selective oxidation of propylene. RESEARCH ON CHEMICAL INTERMEDIATES. 2012;38:829–46.
IEEE
[1]
T. T. Nguyen, T. M. Le, D. D. Truong, R. Fehrmann, A. Riisager, and I. Van Driessche, “Synergy effects in mixed Bi2O3, MoO3 and V2O5 catalysts for selective oxidation of propylene,” RESEARCH ON CHEMICAL INTERMEDIATES, vol. 38, pp. 829–846, 2012.
@article{1940749,
  abstract     = {In this work, the possible synergy effects between Bi2O3, MoO3 and V2O5, and between Bi2Mo3O12 and BiVO4, were investigated. The catalytic activity of the "mechanical mixture" of these compounds was measured. The mixture containing 36.96 mol% Bi2O3, 39.13 mol% MoO3 and 23.91 mol% V2O5 (21.43 mol% Bi2Mo3O12 and 78.57 mol% BiVO4), corresponding to the compound Bi1-x/3V1-xMoxO4 with x = 0.45 (Bi0.85V0.55Mo0.45O4), exhibited the highest activity for the selective oxidation of propylene to acrolein. The mixed sample prepared chemically by a sol-gel method possessed higher activity than that of mechanical mixtures.},
  author       = {Nguyen, Tien The and Le, Thang Minh and Truong, Duc Duc and Fehrmann, Rasmus and Riisager, Anders and Van Driessche, Isabel},
  issn         = {0922-6168},
  journal      = {RESEARCH ON CHEMICAL INTERMEDIATES},
  keywords     = {Bismuth molybdate,Synergy effect,Bismuth vanado molybdate,Selective oxidation,Propylene,Acrolein,Mechanical mixture,Sol-gel,BISMUTH MOLYBDATE CATALYSTS,SCHEELITE STRUCTURE,METAL-OXIDES,AMMOXIDATION,SURFACE,MOLYBDOVANADATES,DEPOSITION,1-BUTENE,BEHAVIOR,SYSTEM},
  language     = {eng},
  pages        = {829--846},
  title        = {Synergy effects in mixed Bi2O3, MoO3 and V2O5 catalysts for selective oxidation of propylene},
  url          = {http://dx.doi.org/10.1007/s11164-011-0421-9},
  volume       = {38},
  year         = {2012},
}

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