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Synergy effects in mixed Bi2O3, MoO3 and V2O5 catalysts for selective oxidation of propylene

Tien The Nguyen, Thang Minh Le, Duc Duc Truong, Rasmus Fehrmann, Anders Riisager and Isabel Van Driessche UGent (2012) RESEARCH ON CHEMICAL INTERMEDIATES. 38. p.829-846
abstract
In this work, the possible synergy effects between Bi2O3, MoO3 and V2O5, and between Bi2Mo3O12 and BiVO4, were investigated. The catalytic activity of the "mechanical mixture" of these compounds was measured. The mixture containing 36.96 mol% Bi2O3, 39.13 mol% MoO3 and 23.91 mol% V2O5 (21.43 mol% Bi2Mo3O12 and 78.57 mol% BiVO4), corresponding to the compound Bi1-x/3V1-xMoxO4 with x = 0.45 (Bi0.85V0.55Mo0.45O4), exhibited the highest activity for the selective oxidation of propylene to acrolein. The mixed sample prepared chemically by a sol-gel method possessed higher activity than that of mechanical mixtures.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (review)
publication status
published
subject
keyword
Bismuth molybdate, Synergy effect, Bismuth vanado molybdate, Selective oxidation, Propylene, Acrolein, Mechanical mixture, Sol-gel, BISMUTH MOLYBDATE CATALYSTS, SCHEELITE STRUCTURE, METAL-OXIDES, AMMOXIDATION, SURFACE, MOLYBDOVANADATES, DEPOSITION, 1-BUTENE, BEHAVIOR, SYSTEM
journal title
RESEARCH ON CHEMICAL INTERMEDIATES
Res. Chem. Intermed.
volume
38
pages
829 - 846
Web of Science type
Review
Web of Science id
000302146500013
JCR category
CHEMISTRY, MULTIDISCIPLINARY
JCR impact factor
0.88 (2012)
JCR rank
101/150 (2012)
JCR quartile
3 (2012)
ISSN
0922-6168
DOI
10.1007/s11164-011-0421-9
language
English
UGent publication?
yes
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
1940749
handle
http://hdl.handle.net/1854/LU-1940749
date created
2011-11-09 14:24:35
date last changed
2012-05-22 11:24:14
@article{1940749,
  abstract     = {In this work, the possible synergy effects between Bi2O3, MoO3 and V2O5, and between Bi2Mo3O12 and BiVO4, were investigated. The catalytic activity of the {\textacutedbl}mechanical mixture{\textacutedbl} of these compounds was measured. The mixture containing 36.96 mol\% Bi2O3, 39.13 mol\% MoO3 and 23.91 mol\% V2O5 (21.43 mol\% Bi2Mo3O12 and 78.57 mol\% BiVO4), corresponding to the compound Bi1-x/3V1-xMoxO4 with x = 0.45 (Bi0.85V0.55Mo0.45O4), exhibited the highest activity for the selective oxidation of propylene to acrolein. The mixed sample prepared chemically by a sol-gel method possessed higher activity than that of mechanical mixtures.},
  author       = {Nguyen, Tien The and Le, Thang Minh and Truong, Duc Duc and Fehrmann, Rasmus and Riisager, Anders and Van Driessche, Isabel},
  issn         = {0922-6168},
  journal      = {RESEARCH ON CHEMICAL INTERMEDIATES},
  keyword      = {Bismuth molybdate,Synergy effect,Bismuth vanado molybdate,Selective oxidation,Propylene,Acrolein,Mechanical mixture,Sol-gel,BISMUTH MOLYBDATE CATALYSTS,SCHEELITE STRUCTURE,METAL-OXIDES,AMMOXIDATION,SURFACE,MOLYBDOVANADATES,DEPOSITION,1-BUTENE,BEHAVIOR,SYSTEM},
  language     = {eng},
  pages        = {829--846},
  title        = {Synergy effects in mixed Bi2O3, MoO3 and V2O5 catalysts for selective oxidation of propylene},
  url          = {http://dx.doi.org/10.1007/s11164-011-0421-9},
  volume       = {38},
  year         = {2012},
}

Chicago
Nguyen, Tien The, Thang Minh Le, Duc Duc Truong, Rasmus Fehrmann, Anders Riisager, and Isabel Van Driessche. 2012. “Synergy Effects in Mixed Bi2O3, MoO3 and V2O5 Catalysts for Selective Oxidation of Propylene.” Research on Chemical Intermediates 38: 829–846.
APA
Nguyen, Tien The, Le, T. M., Truong, D. D., Fehrmann, R., Riisager, A., & Van Driessche, I. (2012). Synergy effects in mixed Bi2O3, MoO3 and V2O5 catalysts for selective oxidation of propylene. RESEARCH ON CHEMICAL INTERMEDIATES, 38, 829–846.
Vancouver
1.
Nguyen TT, Le TM, Truong DD, Fehrmann R, Riisager A, Van Driessche I. Synergy effects in mixed Bi2O3, MoO3 and V2O5 catalysts for selective oxidation of propylene. RESEARCH ON CHEMICAL INTERMEDIATES. 2012;38:829–46.
MLA
Nguyen, Tien The, Thang Minh Le, Duc Duc Truong, et al. “Synergy Effects in Mixed Bi2O3, MoO3 and V2O5 Catalysts for Selective Oxidation of Propylene.” RESEARCH ON CHEMICAL INTERMEDIATES 38 (2012): 829–846. Print.