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One-pot synthesis of cyclopentadienyl endcapped poly(2-ethyl-2-oxazoline) and subsequent ambient temperature Diels-Alder conjugations

Mathias Glassner, Kristian Kempe, Ulrich S Schubert, Richard Hoogenboom UGent and Christopher Barner-Kowollik (2011) CHEMICAL COMMUNICATIONS. 47(38). p.10620-10622
abstract
An efficient method for the preparation of cyclopentadienyl endcapped poly(2-ethyl-2-oxazoline) (PEtOx-Cp) via cationic ring-opening polymerization utilizing sodium cyclopentadienide as a termination agent is presented. Subsequent Diels-Alder reactions with N-substituted maleimides proceed quantitatively at ambient temperature. A block copolymer (PEtOx-b-PEG) is prepared employing maleimide terminated poly(ethylene glycol).
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
CLICK CHEMISTRY, BUILDING-BLOCKS, POLYMERS, POLY(2-OXAZOLINE)S, COPOLYMERS, POLYMERIZATION
journal title
CHEMICAL COMMUNICATIONS
Chem. Commun.
volume
47
issue
38
pages
10620 - 10622
Web of Science type
Article
Web of Science id
000295004300027
JCR category
CHEMISTRY, MULTIDISCIPLINARY
JCR impact factor
6.169 (2011)
JCR rank
17/149 (2011)
JCR quartile
1 (2011)
ISSN
1359-7345
DOI
10.1039/c1cc14075b
language
English
UGent publication?
yes
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
1940348
handle
http://hdl.handle.net/1854/LU-1940348
date created
2011-11-09 08:37:19
date last changed
2016-12-19 15:46:40
@article{1940348,
  abstract     = {An efficient method for the preparation of cyclopentadienyl endcapped poly(2-ethyl-2-oxazoline) (PEtOx-Cp) via cationic ring-opening polymerization utilizing sodium cyclopentadienide as a termination agent is presented. Subsequent Diels-Alder reactions with N-substituted maleimides proceed quantitatively at ambient temperature. A block copolymer (PEtOx-b-PEG) is prepared employing maleimide terminated poly(ethylene glycol).},
  author       = {Glassner, Mathias and Kempe, Kristian and Schubert, Ulrich S and Hoogenboom, Richard and Barner-Kowollik, Christopher},
  issn         = {1359-7345},
  journal      = {CHEMICAL COMMUNICATIONS},
  keyword      = {CLICK CHEMISTRY,BUILDING-BLOCKS,POLYMERS,POLY(2-OXAZOLINE)S,COPOLYMERS,POLYMERIZATION},
  language     = {eng},
  number       = {38},
  pages        = {10620--10622},
  title        = {One-pot synthesis of cyclopentadienyl endcapped poly(2-ethyl-2-oxazoline) and subsequent ambient temperature Diels-Alder conjugations},
  url          = {http://dx.doi.org/10.1039/c1cc14075b},
  volume       = {47},
  year         = {2011},
}

Chicago
Glassner, Mathias, Kristian Kempe, Ulrich S Schubert, Richard Hoogenboom, and Christopher Barner-Kowollik. 2011. “One-pot Synthesis of Cyclopentadienyl Endcapped Poly(2-ethyl-2-oxazoline) and Subsequent Ambient Temperature Diels-Alder Conjugations.” Chemical Communications 47 (38): 10620–10622.
APA
Glassner, M., Kempe, K., Schubert, U. S., Hoogenboom, R., & Barner-Kowollik, C. (2011). One-pot synthesis of cyclopentadienyl endcapped poly(2-ethyl-2-oxazoline) and subsequent ambient temperature Diels-Alder conjugations. CHEMICAL COMMUNICATIONS, 47(38), 10620–10622.
Vancouver
1.
Glassner M, Kempe K, Schubert US, Hoogenboom R, Barner-Kowollik C. One-pot synthesis of cyclopentadienyl endcapped poly(2-ethyl-2-oxazoline) and subsequent ambient temperature Diels-Alder conjugations. CHEMICAL COMMUNICATIONS. 2011;47(38):10620–2.
MLA
Glassner, Mathias, Kristian Kempe, Ulrich S Schubert, et al. “One-pot Synthesis of Cyclopentadienyl Endcapped Poly(2-ethyl-2-oxazoline) and Subsequent Ambient Temperature Diels-Alder Conjugations.” CHEMICAL COMMUNICATIONS 47.38 (2011): 10620–10622. Print.