Advanced search
1 file | 684.48 KB

One-pot synthesis of cyclopentadienyl endcapped poly(2-ethyl-2-oxazoline) and subsequent ambient temperature Diels-Alder conjugations

(2011) CHEMICAL COMMUNICATIONS. 47(38). p.10620-10622
Author
Organization
Abstract
An efficient method for the preparation of cyclopentadienyl endcapped poly(2-ethyl-2-oxazoline) (PEtOx-Cp) via cationic ring-opening polymerization utilizing sodium cyclopentadienide as a termination agent is presented. Subsequent Diels-Alder reactions with N-substituted maleimides proceed quantitatively at ambient temperature. A block copolymer (PEtOx-b-PEG) is prepared employing maleimide terminated poly(ethylene glycol).
Keywords
CLICK CHEMISTRY, BUILDING-BLOCKS, POLYMERS, POLY(2-OXAZOLINE)S, COPOLYMERS, POLYMERIZATION

Downloads

  • (...).pdf
    • full text
    • |
    • UGent only
    • |
    • PDF
    • |
    • 684.48 KB

Citation

Please use this url to cite or link to this publication:

Chicago
Glassner, Mathias, Kristian Kempe, Ulrich S Schubert, Richard Hoogenboom, and Christopher Barner-Kowollik. 2011. “One-pot Synthesis of Cyclopentadienyl Endcapped Poly(2-ethyl-2-oxazoline) and Subsequent Ambient Temperature Diels-Alder Conjugations.” Chemical Communications 47 (38): 10620–10622.
APA
Glassner, M., Kempe, K., Schubert, U. S., Hoogenboom, R., & Barner-Kowollik, C. (2011). One-pot synthesis of cyclopentadienyl endcapped poly(2-ethyl-2-oxazoline) and subsequent ambient temperature Diels-Alder conjugations. CHEMICAL COMMUNICATIONS, 47(38), 10620–10622.
Vancouver
1.
Glassner M, Kempe K, Schubert US, Hoogenboom R, Barner-Kowollik C. One-pot synthesis of cyclopentadienyl endcapped poly(2-ethyl-2-oxazoline) and subsequent ambient temperature Diels-Alder conjugations. CHEMICAL COMMUNICATIONS. 2011;47(38):10620–2.
MLA
Glassner, Mathias, Kristian Kempe, Ulrich S Schubert, et al. “One-pot Synthesis of Cyclopentadienyl Endcapped Poly(2-ethyl-2-oxazoline) and Subsequent Ambient Temperature Diels-Alder Conjugations.” CHEMICAL COMMUNICATIONS 47.38 (2011): 10620–10622. Print.
@article{1940348,
  abstract     = {An efficient method for the preparation of cyclopentadienyl endcapped poly(2-ethyl-2-oxazoline) (PEtOx-Cp) via cationic ring-opening polymerization utilizing sodium cyclopentadienide as a termination agent is presented. Subsequent Diels-Alder reactions with N-substituted maleimides proceed quantitatively at ambient temperature. A block copolymer (PEtOx-b-PEG) is prepared employing maleimide terminated poly(ethylene glycol).},
  author       = {Glassner, Mathias and Kempe, Kristian and Schubert, Ulrich S and Hoogenboom, Richard and Barner-Kowollik, Christopher},
  issn         = {1359-7345},
  journal      = {CHEMICAL COMMUNICATIONS},
  keyword      = {CLICK CHEMISTRY,BUILDING-BLOCKS,POLYMERS,POLY(2-OXAZOLINE)S,COPOLYMERS,POLYMERIZATION},
  language     = {eng},
  number       = {38},
  pages        = {10620--10622},
  title        = {One-pot synthesis of cyclopentadienyl endcapped poly(2-ethyl-2-oxazoline) and subsequent ambient temperature Diels-Alder conjugations},
  url          = {http://dx.doi.org/10.1039/c1cc14075b},
  volume       = {47},
  year         = {2011},
}

Altmetric
View in Altmetric
Web of Science
Times cited: