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Supramolecular design of high-performance poly(L-lactide)/carbon nanotube nanocomposites : from melt-processing to rheological, morphological and electrical properties

(2011) JOURNAL OF MATERIALS CHEMISTRY. 21(40). p.16190-16196
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Abstract
The ability of omega-imidazolium functionalized poly(L-lactide) (ImPLLA) chains to improve the CNT dispersion within the PLLA matrix was demonstrated in bulk and at elevated temperatures using melt-processing techniques. This approach brings new supramolecular tools to the formation of CNT-based biomaterials derived from renewable resources with outstanding properties for semi-industrial applications. In this work, the PLLA/CNT nanocomposites were prepared using extrusion technology, starting from masterbatches. The rheological, morphological, electrical properties as well as Raman analyses confirmed the establishment of supramolecular cation-pi interactions between ImPLLA and CNT in the melt, leading to a fine dispersion of CNT within PLLA matrix.
Keywords
FUNCTIONALIZATION, CONDUCTIVITY, DISPERSION, WALLED CARBON NANOTUBES, CHARGE-TRANSFER, POLYLACTIDE COMPOSITES, POLYMER BRUSHES, BIOMATERIALS, BLENDS, ACID)

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MLA
Manfredi, Erica, et al. “Supramolecular Design of High-Performance Poly(L-Lactide)/Carbon Nanotube Nanocomposites : From Melt-Processing to Rheological, Morphological and Electrical Properties.” JOURNAL OF MATERIALS CHEMISTRY, vol. 21, no. 40, 2011, pp. 16190–96, doi:10.1039/c1jm12250a.
APA
Manfredi, E., Meyer, F., Verge, P., Raquez, J.-M., Thomassin, J.-M., Alexandre, M., … Dubois, P. (2011). Supramolecular design of high-performance poly(L-lactide)/carbon nanotube nanocomposites : from melt-processing to rheological, morphological and electrical properties. JOURNAL OF MATERIALS CHEMISTRY, 21(40), 16190–16196. https://doi.org/10.1039/c1jm12250a
Chicago author-date
Manfredi, Erica, Franck Meyer, Pierre Verge, Jean-Marie Raquez, Jean-Michel Thomassin, Michael Alexandre, Bart Dervaux, et al. 2011. “Supramolecular Design of High-Performance Poly(L-Lactide)/Carbon Nanotube Nanocomposites : From Melt-Processing to Rheological, Morphological and Electrical Properties.” JOURNAL OF MATERIALS CHEMISTRY 21 (40): 16190–96. https://doi.org/10.1039/c1jm12250a.
Chicago author-date (all authors)
Manfredi, Erica, Franck Meyer, Pierre Verge, Jean-Marie Raquez, Jean-Michel Thomassin, Michael Alexandre, Bart Dervaux, Filip Du Prez, Pascal Van Der Voort, Christine Jerome, and Philippe Dubois. 2011. “Supramolecular Design of High-Performance Poly(L-Lactide)/Carbon Nanotube Nanocomposites : From Melt-Processing to Rheological, Morphological and Electrical Properties.” JOURNAL OF MATERIALS CHEMISTRY 21 (40): 16190–16196. doi:10.1039/c1jm12250a.
Vancouver
1.
Manfredi E, Meyer F, Verge P, Raquez J-M, Thomassin J-M, Alexandre M, et al. Supramolecular design of high-performance poly(L-lactide)/carbon nanotube nanocomposites : from melt-processing to rheological, morphological and electrical properties. JOURNAL OF MATERIALS CHEMISTRY. 2011;21(40):16190–6.
IEEE
[1]
E. Manfredi et al., “Supramolecular design of high-performance poly(L-lactide)/carbon nanotube nanocomposites : from melt-processing to rheological, morphological and electrical properties,” JOURNAL OF MATERIALS CHEMISTRY, vol. 21, no. 40, pp. 16190–16196, 2011.
@article{1937822,
  abstract     = {{The ability of omega-imidazolium functionalized poly(L-lactide) (ImPLLA) chains to improve the CNT dispersion within the PLLA matrix was demonstrated in bulk and at elevated temperatures using melt-processing techniques. This approach brings new supramolecular tools to the formation of CNT-based biomaterials derived from renewable resources with outstanding properties for semi-industrial applications. In this work, the PLLA/CNT nanocomposites were prepared using extrusion technology, starting from masterbatches. The rheological, morphological, electrical properties as well as Raman analyses confirmed the establishment of supramolecular cation-pi interactions between ImPLLA and CNT in the melt, leading to a fine dispersion of CNT within PLLA matrix.}},
  author       = {{Manfredi, Erica and Meyer, Franck and Verge, Pierre and Raquez, Jean-Marie and Thomassin, Jean-Michel and Alexandre, Michael and Dervaux, Bart and Du Prez, Filip and Van Der Voort, Pascal and Jerome, Christine and Dubois, Philippe}},
  issn         = {{0959-9428}},
  journal      = {{JOURNAL OF MATERIALS CHEMISTRY}},
  keywords     = {{FUNCTIONALIZATION,CONDUCTIVITY,DISPERSION,WALLED CARBON NANOTUBES,CHARGE-TRANSFER,POLYLACTIDE COMPOSITES,POLYMER BRUSHES,BIOMATERIALS,BLENDS,ACID)}},
  language     = {{eng}},
  number       = {{40}},
  pages        = {{16190--16196}},
  title        = {{Supramolecular design of high-performance poly(L-lactide)/carbon nanotube nanocomposites : from melt-processing to rheological, morphological and electrical properties}},
  url          = {{http://dx.doi.org/10.1039/c1jm12250a}},
  volume       = {{21}},
  year         = {{2011}},
}

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