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Qualitative by-product identification of plasma-assisted TCE abatement by mass spectrometry and Fourier-transform infrared spectroscopy

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Abstract
In this study, the formation of by-products resulting from the decomposition of trichloroethylene with a negative DC glow discharge has been investigated. By combining the qualitative data from mass spectrometry and Fourier-transform infrared spectroscopy, the formation of phosgene, dichloroacetylchloride and trichloroacetaldehyde have been confirmed as incomplete oxidation products. Hydrogen chloride, chlorine, carbon monoxide and carbon dioxide were also detected. Also, formation of ozone was found in the outlet stream. Based on this information, it is possible to chose an appropriate catalyst to combine with non thermal plasma. In this way emission of harmful, incomplete oxidation products can be further reduced at a lower energy cost.
Keywords
AIR-POLLUTION CONTROL, WASTE-GAS TREATMENT, VOLATILE ORGANIC-COMPOUNDS, NONTHERMAL PLASMA, ELECTRICAL-DISCHARGE, ATMOSPHERIC-PRESSURE, CATALYTIC COMBUSTION, GLOW-DISCHARGE, DECOMPOSITION, REMOVAL, Non-thermal plasma, VOC, Negative DC glow discharge, By-products, FT-IR, MS

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Chicago
Vandenbroucke, Arne, Minh Tuan Nguyen Dinh , Jean-Marc Giraudon, Rino Morent, Nathalie De Geyter, Jean-Francois Lamonier, and Christophe Leys. 2011. “Qualitative By-product Identification of Plasma-assisted TCE Abatement by Mass Spectrometry and Fourier-transform Infrared Spectroscopy.” Plasma Chemistry and Plasma Processing 31 (5): 707–718.
APA
Vandenbroucke, Arne, Nguyen Dinh , M. T., Giraudon, J.-M., Morent, R., De Geyter, N., Lamonier, J.-F., & Leys, C. (2011). Qualitative by-product identification of plasma-assisted TCE abatement by mass spectrometry and Fourier-transform infrared spectroscopy. PLASMA CHEMISTRY AND PLASMA PROCESSING, 31(5), 707–718.
Vancouver
1.
Vandenbroucke A, Nguyen Dinh MT, Giraudon J-M, Morent R, De Geyter N, Lamonier J-F, et al. Qualitative by-product identification of plasma-assisted TCE abatement by mass spectrometry and Fourier-transform infrared spectroscopy. PLASMA CHEMISTRY AND PLASMA PROCESSING. 2011;31(5):707–18.
MLA
Vandenbroucke, Arne, Minh Tuan Nguyen Dinh , Jean-Marc Giraudon, et al. “Qualitative By-product Identification of Plasma-assisted TCE Abatement by Mass Spectrometry and Fourier-transform Infrared Spectroscopy.” PLASMA CHEMISTRY AND PLASMA PROCESSING 31.5 (2011): 707–718. Print.
@article{1910309,
  abstract     = {In this study, the formation of by-products resulting from the decomposition of trichloroethylene with a negative DC glow discharge has been investigated. By combining the qualitative data from mass spectrometry and Fourier-transform infrared spectroscopy, the formation of phosgene, dichloroacetylchloride and trichloroacetaldehyde have been confirmed as incomplete oxidation products. Hydrogen chloride, chlorine, carbon monoxide and carbon dioxide were also detected. Also, formation of ozone was found in the outlet stream. Based on this information, it is possible to chose an appropriate catalyst to combine with non thermal plasma. In this way emission of harmful, incomplete oxidation products can be further reduced at a lower energy cost.},
  author       = {Vandenbroucke, Arne and Nguyen Dinh , Minh Tuan  and Giraudon, Jean-Marc  and Morent, Rino and De Geyter, Nathalie and Lamonier, Jean-Francois  and Leys, Christophe},
  issn         = {1572-8986},
  journal      = {PLASMA CHEMISTRY AND PLASMA PROCESSING},
  keyword      = {AIR-POLLUTION CONTROL,WASTE-GAS TREATMENT,VOLATILE ORGANIC-COMPOUNDS,NONTHERMAL PLASMA,ELECTRICAL-DISCHARGE,ATMOSPHERIC-PRESSURE,CATALYTIC COMBUSTION,GLOW-DISCHARGE,DECOMPOSITION,REMOVAL,Non-thermal plasma,VOC,Negative DC glow discharge,By-products,FT-IR,MS},
  language     = {eng},
  number       = {5},
  pages        = {707--718},
  title        = {Qualitative by-product identification of plasma-assisted TCE abatement by mass spectrometry and Fourier-transform infrared spectroscopy},
  url          = {http://dx.doi.org/10.1007/s11090-011-9310-7},
  volume       = {31},
  year         = {2011},
}

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