Advanced search
1 file | 105.42 KB

Inductively coupled plasma mass spectrometry hyphenated to capillary gas chromatography as a detection system for the speciation analysis of organolead compounds in environmental waters

Author
Organization
Abstract
The application of an inductively coupled plasma mass spectrometry detection system to the speciation of organolead compounds in environmental waters is described. Derivatization was carried out by propylation with a Grignard reagent after extraction of the organolead compounds into hexane as their diethyldithiocarbamate complexes. This was followed by separation and detection with capillary gas chromatography and inductively coupled plasma mass spectrometry. Detection limits ranging from 10 fg (0.05 ng l(-1)) (as Pb) for trimethyllead to 16 fg (0.08 ng l(-1)) (as Ph) for diethyllead were achieved. The accuracy of the method was confirmed by additional analysis of the water samples with capillary gas chromatography coupled to microwave-induced plasma atomic emission spectrometry and by the analysis of a reference material from the Standards, Measurements & Testing Programme of the European Union.
Keywords
AAS, GREENLAND SNOW, SAMPLES, INTERFACE, PRECONCENTRATION, LEAD SPECIATION, ABSORPTION SPECTROMETRY, IONIC ALKYLLEAD COMPOUNDS, PERFORMANCE LIQUID-CHROMATOGRAPHY, ATOMIC-EMISSION-SPECTROMETRY, environmental water, gas chromatography inductively coupled plasma mass spectrometry, propylation, speciation, organolead compound

Downloads

  • (...).pdf
    • full text
    • |
    • UGent only
    • |
    • PDF
    • |
    • 105.42 KB

Citation

Please use this url to cite or link to this publication:

Chicago
Heisterkamp, Monika, Tom De Smaele, Jean-Pierre Candelone, Luc Moens, Richard Dams, and Freddy C Adams. 1997. “Inductively Coupled Plasma Mass Spectrometry Hyphenated to Capillary Gas Chromatography as a Detection System for the Speciation Analysis of Organolead Compounds in Environmental Waters.” Journal of Analytical Atomic Spectrometry 12 (9): 1077–1081.
APA
Heisterkamp, M., De Smaele, T., Candelone, J.-P., Moens, L., Dams, R., & Adams, F. C. (1997). Inductively coupled plasma mass spectrometry hyphenated to capillary gas chromatography as a detection system for the speciation analysis of organolead compounds in environmental waters. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 12(9), 1077–1081. Presented at the 1997 European winter conference on Plasma Spectrochemistry.
Vancouver
1.
Heisterkamp M, De Smaele T, Candelone J-P, Moens L, Dams R, Adams FC. Inductively coupled plasma mass spectrometry hyphenated to capillary gas chromatography as a detection system for the speciation analysis of organolead compounds in environmental waters. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY. 1997;12(9):1077–81.
MLA
Heisterkamp, Monika, Tom De Smaele, Jean-Pierre Candelone, et al. “Inductively Coupled Plasma Mass Spectrometry Hyphenated to Capillary Gas Chromatography as a Detection System for the Speciation Analysis of Organolead Compounds in Environmental Waters.” JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY 12.9 (1997): 1077–1081. Print.
@article{185035,
  abstract     = {The application of an inductively coupled plasma mass spectrometry detection system to the speciation of organolead compounds in environmental waters is described. Derivatization was carried out by propylation with a Grignard reagent after extraction of the organolead compounds into hexane as their diethyldithiocarbamate complexes. This was followed by separation and detection with capillary gas chromatography and inductively coupled plasma mass spectrometry. Detection limits ranging from 10 fg (0.05 ng l(-1)) (as Pb) for trimethyllead to 16 fg (0.08 ng l(-1)) (as Ph) for diethyllead were achieved. The accuracy of the method was confirmed by additional analysis of the water samples with capillary gas chromatography coupled to microwave-induced plasma atomic emission spectrometry and by the analysis of a reference material from the Standards, Measurements \& Testing Programme of the European Union.},
  author       = {Heisterkamp, Monika and De Smaele, Tom and Candelone, Jean-Pierre and Moens, Luc and Dams, Richard and Adams, Freddy C},
  issn         = {0267-9477},
  journal      = {JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY},
  keyword      = {AAS,GREENLAND SNOW,SAMPLES,INTERFACE,PRECONCENTRATION,LEAD SPECIATION,ABSORPTION SPECTROMETRY,IONIC ALKYLLEAD COMPOUNDS,PERFORMANCE LIQUID-CHROMATOGRAPHY,ATOMIC-EMISSION-SPECTROMETRY,environmental water,gas chromatography inductively coupled plasma mass spectrometry,propylation,speciation,organolead compound},
  language     = {eng},
  location     = {Ghent, Belgium},
  number       = {9},
  pages        = {1077--1081},
  title        = {Inductively coupled plasma mass spectrometry hyphenated to capillary gas chromatography as a detection system for the speciation analysis of organolead compounds in environmental waters},
  url          = {http://dx.doi.org/10.1039/a701386h},
  volume       = {12},
  year         = {1997},
}

Altmetric
View in Altmetric