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Inductively coupled plasma mass spectrometry hyphenated to capillary gas chromatography as a detection system for the speciation analysis of organolead compounds in environmental waters

Monika Heisterkamp, Tom De Smaele UGent, Jean-Pierre Candelone, Luc Moens UGent, Richard Dams and Freddy C Adams (1997) JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY. 12(9). p.1077-1081
abstract
The application of an inductively coupled plasma mass spectrometry detection system to the speciation of organolead compounds in environmental waters is described. Derivatization was carried out by propylation with a Grignard reagent after extraction of the organolead compounds into hexane as their diethyldithiocarbamate complexes. This was followed by separation and detection with capillary gas chromatography and inductively coupled plasma mass spectrometry. Detection limits ranging from 10 fg (0.05 ng l(-1)) (as Pb) for trimethyllead to 16 fg (0.08 ng l(-1)) (as Ph) for diethyllead were achieved. The accuracy of the method was confirmed by additional analysis of the water samples with capillary gas chromatography coupled to microwave-induced plasma atomic emission spectrometry and by the analysis of a reference material from the Standards, Measurements & Testing Programme of the European Union.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (proceedingsPaper)
publication status
published
subject
keyword
AAS, GREENLAND SNOW, SAMPLES, INTERFACE, PRECONCENTRATION, LEAD SPECIATION, ABSORPTION SPECTROMETRY, IONIC ALKYLLEAD COMPOUNDS, PERFORMANCE LIQUID-CHROMATOGRAPHY, ATOMIC-EMISSION-SPECTROMETRY, environmental water, gas chromatography inductively coupled plasma mass spectrometry, propylation, speciation, organolead compound
journal title
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY
J. Anal. At. Spectrom.
volume
12
issue
9
pages
1077 - 1081
conference name
1997 European winter conference on Plasma Spectrochemistry
conference location
Ghent, Belgium
conference start
1997-01-12
conference end
1997-01-17
Web of Science type
Article
ISSN
0267-9477
DOI
10.1039/a701386h
language
English
UGent publication?
yes
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
185035
handle
http://hdl.handle.net/1854/LU-185035
date created
2004-01-14 13:41:00
date last changed
2018-01-29 12:18:31
@article{185035,
  abstract     = {The application of an inductively coupled plasma mass spectrometry detection system to the speciation of organolead compounds in environmental waters is described. Derivatization was carried out by propylation with a Grignard reagent after extraction of the organolead compounds into hexane as their diethyldithiocarbamate complexes. This was followed by separation and detection with capillary gas chromatography and inductively coupled plasma mass spectrometry. Detection limits ranging from 10 fg (0.05 ng l(-1)) (as Pb) for trimethyllead to 16 fg (0.08 ng l(-1)) (as Ph) for diethyllead were achieved. The accuracy of the method was confirmed by additional analysis of the water samples with capillary gas chromatography coupled to microwave-induced plasma atomic emission spectrometry and by the analysis of a reference material from the Standards, Measurements \& Testing Programme of the European Union.},
  author       = {Heisterkamp, Monika and De Smaele, Tom and Candelone, Jean-Pierre and Moens, Luc and Dams, Richard and Adams, Freddy C},
  issn         = {0267-9477},
  journal      = {JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY},
  keyword      = {AAS,GREENLAND SNOW,SAMPLES,INTERFACE,PRECONCENTRATION,LEAD SPECIATION,ABSORPTION SPECTROMETRY,IONIC ALKYLLEAD COMPOUNDS,PERFORMANCE LIQUID-CHROMATOGRAPHY,ATOMIC-EMISSION-SPECTROMETRY,environmental water,gas chromatography inductively coupled plasma mass spectrometry,propylation,speciation,organolead compound},
  language     = {eng},
  location     = {Ghent, Belgium},
  number       = {9},
  pages        = {1077--1081},
  title        = {Inductively coupled plasma mass spectrometry hyphenated to capillary gas chromatography as a detection system for the speciation analysis of organolead compounds in environmental waters},
  url          = {http://dx.doi.org/10.1039/a701386h},
  volume       = {12},
  year         = {1997},
}

Chicago
Heisterkamp, Monika, Tom De Smaele, Jean-Pierre Candelone, Luc Moens, Richard Dams, and Freddy C Adams. 1997. “Inductively Coupled Plasma Mass Spectrometry Hyphenated to Capillary Gas Chromatography as a Detection System for the Speciation Analysis of Organolead Compounds in Environmental Waters.” Journal of Analytical Atomic Spectrometry 12 (9): 1077–1081.
APA
Heisterkamp, M., De Smaele, T., Candelone, J.-P., Moens, L., Dams, R., & Adams, F. C. (1997). Inductively coupled plasma mass spectrometry hyphenated to capillary gas chromatography as a detection system for the speciation analysis of organolead compounds in environmental waters. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 12(9), 1077–1081. Presented at the 1997 European winter conference on Plasma Spectrochemistry.
Vancouver
1.
Heisterkamp M, De Smaele T, Candelone J-P, Moens L, Dams R, Adams FC. Inductively coupled plasma mass spectrometry hyphenated to capillary gas chromatography as a detection system for the speciation analysis of organolead compounds in environmental waters. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY. 1997;12(9):1077–81.
MLA
Heisterkamp, Monika, Tom De Smaele, Jean-Pierre Candelone, et al. “Inductively Coupled Plasma Mass Spectrometry Hyphenated to Capillary Gas Chromatography as a Detection System for the Speciation Analysis of Organolead Compounds in Environmental Waters.” JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY 12.9 (1997): 1077–1081. Print.