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Access to a new type of homo-C-nucleosides with a 'split' 8-deazapurine via a 1,3-dipolar cycloaddition reaction

(1997) NUCLEOSIDES & NUCLEOTIDES. 16(3). p.291-300
Author
Organization
Abstract
Upon a 1,3-dipolar addition reaction with trimethylsilyl acetylene, azides (R,S)-7 were converted to the triazoles (R,S)-8. These diastereoisomers were separated and individually protodesilylated to yield (R)- and (S)-9, fully characterized by NMR. Structural assignments of unsaturated side compounds were deduced from a QUIET-NOESY experiment. Compounds (R)-and (S)-9 represent a new type of homo-C-nucleosides with a ''split'' 8-azapurine base moiety.
Keywords
PYRAZOFURINS, SELECTIVE PULSES, DERIVATIVES

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Citation

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Chicago
Van Calenbergh, Serge, André De Bruyn, Jan Schraml, Norbert Blaton, Oswald Peeters, Denis De Keukeleire, Robert Busson, and Piet Herdewijn. 1997. “Access to a New Type of homo-C-nucleosides with a ‘Split’ 8-deazapurine via a 1,3-dipolar Cycloaddition Reaction.” Nucleosides & Nucleotides 16 (3): 291–300.
APA
Van Calenbergh, S., De Bruyn, A., Schraml, J., Blaton, N., Peeters, O., De Keukeleire, D., Busson, R., et al. (1997). Access to a new type of homo-C-nucleosides with a “split” 8-deazapurine via a 1,3-dipolar cycloaddition reaction. NUCLEOSIDES & NUCLEOTIDES, 16(3), 291–300.
Vancouver
1.
Van Calenbergh S, De Bruyn A, Schraml J, Blaton N, Peeters O, De Keukeleire D, et al. Access to a new type of homo-C-nucleosides with a “split” 8-deazapurine via a 1,3-dipolar cycloaddition reaction. NUCLEOSIDES & NUCLEOTIDES. 1997;16(3):291–300.
MLA
Van Calenbergh, Serge, André De Bruyn, Jan Schraml, et al. “Access to a New Type of homo-C-nucleosides with a ‘Split’ 8-deazapurine via a 1,3-dipolar Cycloaddition Reaction.” NUCLEOSIDES & NUCLEOTIDES 16.3 (1997): 291–300. Print.
@article{183059,
  abstract     = {Upon a 1,3-dipolar addition reaction with trimethylsilyl acetylene, azides (R,S)-7 were converted to the triazoles (R,S)-8. These diastereoisomers were separated and individually protodesilylated to yield (R)- and (S)-9, fully characterized by NMR. Structural assignments of unsaturated side compounds were deduced from a QUIET-NOESY experiment. Compounds (R)-and (S)-9 represent a new type of homo-C-nucleosides with a ''split'' 8-azapurine base moiety.},
  author       = {Van Calenbergh, Serge and De Bruyn, Andr{\'e} and Schraml, Jan and Blaton, Norbert and Peeters, Oswald and De Keukeleire, Denis and Busson, Robert and Herdewijn, Piet},
  issn         = {0732-8311},
  journal      = {NUCLEOSIDES \& NUCLEOTIDES},
  keyword      = {PYRAZOFURINS,SELECTIVE PULSES,DERIVATIVES},
  language     = {eng},
  number       = {3},
  pages        = {291--300},
  title        = {Access to a new type of homo-C-nucleosides with a 'split' 8-deazapurine via a 1,3-dipolar cycloaddition reaction},
  url          = {http://dx.doi.org/10.1080/07328319708001349},
  volume       = {16},
  year         = {1997},
}

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