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Sensitive, simultaneous determination of organomercury, -lead, and -tin compounds with headspace solid phase microextraction capillary gas chromatography combined with inductively coupled plasma mass spectrometry

Luc Moens UGent, Tom De Smaele UGent, Richard Dams, Paul Van Den Broeck and Patrick Sandra UGent (1997) ANALYTICAL CHEMISTRY. 69(8). p.1604-1611
abstract
The use of the solid phase microextraction (SPME) technique for the simultaneous determination of organomercury, -tin, and -lead is described. The organometallic compounds were in situ derivatized with sodium tetraethylborate, sorbed on a poly(dimethylsiloxane)-coated fused silica fiber, and desorbed in the splitless injection port of the GC. The different organometallic compounds were simultaneously determined by an inductively coupled plasma mass spectrometer (ICPMS) coupled to the GC using a transfer line developed in-house. The detection limits obtained with CGC-ICPMS for monobutyl-, dibutyl-, and tributyltin are between 0.34 and 2.1 ng/L as Sn. Analysis of a PACS-1 reference material confirmed the reliability of the combination of SPME as extraction technique with CGC-ICPMS for the analysis of organotin compounds.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
WATER, ETHYLATION, AQUEOUS SAMPLES, HYDRIDE GENERATION, SPECIATION ANALYSIS, ORGANOTIN COMPOUNDS, EMISSION-SPECTROMETRY, BUTYLTIN COMPOUNDS, ATOMIC-ABSORPTION SPECTROMETRY, SODIUM TETRAETHYLBORATE
journal title
ANALYTICAL CHEMISTRY
Anal. Chem.
volume
69
issue
8
pages
1604 - 1611
Web of Science type
Article
ISSN
0003-2700
DOI
10.1021/ac960905o
language
English
UGent publication?
yes
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
182808
handle
http://hdl.handle.net/1854/LU-182808
date created
2004-01-14 13:41:00
date last changed
2018-01-29 12:18:29
@article{182808,
  abstract     = {The use of the solid phase microextraction (SPME) technique for the simultaneous determination of organomercury, -tin, and -lead is described. The organometallic compounds were in situ derivatized with sodium tetraethylborate, sorbed on a poly(dimethylsiloxane)-coated fused silica fiber, and desorbed in the splitless injection port of the GC. The different organometallic compounds were simultaneously determined by an inductively coupled plasma mass spectrometer (ICPMS) coupled to the GC using a transfer line developed in-house. The detection limits obtained with CGC-ICPMS for monobutyl-, dibutyl-, and tributyltin are between 0.34 and 2.1 ng/L as Sn. Analysis of a PACS-1 reference material confirmed the reliability of the combination of SPME as extraction technique with CGC-ICPMS for the analysis of organotin compounds.},
  author       = {Moens, Luc and De Smaele, Tom and Dams, Richard and Van Den Broeck, Paul and Sandra, Patrick},
  issn         = {0003-2700},
  journal      = {ANALYTICAL CHEMISTRY},
  keyword      = {WATER,ETHYLATION,AQUEOUS SAMPLES,HYDRIDE GENERATION,SPECIATION ANALYSIS,ORGANOTIN COMPOUNDS,EMISSION-SPECTROMETRY,BUTYLTIN COMPOUNDS,ATOMIC-ABSORPTION SPECTROMETRY,SODIUM TETRAETHYLBORATE},
  language     = {eng},
  number       = {8},
  pages        = {1604--1611},
  title        = {Sensitive, simultaneous determination of organomercury, -lead, and -tin compounds with headspace solid phase microextraction capillary gas chromatography combined with inductively coupled plasma mass spectrometry},
  url          = {http://dx.doi.org/10.1021/ac960905o},
  volume       = {69},
  year         = {1997},
}

Chicago
Moens, Luc, Tom De Smaele, Richard Dams, Paul Van Den Broeck, and Patrick Sandra. 1997. “Sensitive, Simultaneous Determination of Organomercury, -lead, and -tin Compounds with Headspace Solid Phase Microextraction Capillary Gas Chromatography Combined with Inductively Coupled Plasma Mass Spectrometry.” Analytical Chemistry 69 (8): 1604–1611.
APA
Moens, L., De Smaele, T., Dams, R., Van Den Broeck, P., & Sandra, P. (1997). Sensitive, simultaneous determination of organomercury, -lead, and -tin compounds with headspace solid phase microextraction capillary gas chromatography combined with inductively coupled plasma mass spectrometry. ANALYTICAL CHEMISTRY, 69(8), 1604–1611.
Vancouver
1.
Moens L, De Smaele T, Dams R, Van Den Broeck P, Sandra P. Sensitive, simultaneous determination of organomercury, -lead, and -tin compounds with headspace solid phase microextraction capillary gas chromatography combined with inductively coupled plasma mass spectrometry. ANALYTICAL CHEMISTRY. 1997;69(8):1604–11.
MLA
Moens, Luc, Tom De Smaele, Richard Dams, et al. “Sensitive, Simultaneous Determination of Organomercury, -lead, and -tin Compounds with Headspace Solid Phase Microextraction Capillary Gas Chromatography Combined with Inductively Coupled Plasma Mass Spectrometry.” ANALYTICAL CHEMISTRY 69.8 (1997): 1604–1611. Print.