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Capillary GC determination of amines in aqueous samples using sorptive preconcentration on polydimethylsiloxane and polyacrylate phases

E Baltussen, Frank David (UGent) , Patrick Sandra (UGent) , HG Janssen and C Cramers
(1998) HRC-JOURNAL OF HIGH RESOLUTION CHROMATOGRAPHY. 21(12). p.645-648
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Abstract
The use of sorptive extraction/thermal desorption (SE/TD) for the enrichment of amines from aqueous samples was investigated. The amines were derivatized in situ in the water sample by pentafluorobenzoyl chloride and subsequently enriched onto the SE cartridge, Two SE/TD cartridges were used, a commercially available polydimethylsiloxane (PDMS) packed cartridge and a similar cartridge prepared with newly synthesized poly(butyl acrylate) (PBA), Blank profiles of PEA were not as good as those obtained from the PDMS phase. A complex chromatogram was obtained using mass spectrometric detection. Fortunately, the use of a nitrogen-phosphorus detector (NPD) resulted in clean blanks. The PEA phase showed superior performance for the enrichment of the polar amine derivatives from water samples compared to the PDMS material. Using a CGC-NPD set-up and only 1 mL samples, detection limits are in the sub-ppb range.
Keywords
gas chromatography (GC), nitrogen-phosphorus detection (NPD), sorptive extraction thermal desorption (SE/TD), amines, in-situ derivatization, CHROMATOGRAPHY MASS-SPECTROMETRY, SECONDARY ALIPHATIC-AMINES, GAS-CHROMATOGRAPHY, WATER, DERIVATIZATION

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MLA
Baltussen, E., et al. “Capillary GC Determination of Amines in Aqueous Samples Using Sorptive Preconcentration on Polydimethylsiloxane and Polyacrylate Phases.” HRC-JOURNAL OF HIGH RESOLUTION CHROMATOGRAPHY, vol. 21, no. 12, 1998, pp. 645–48.
APA
Baltussen, E., David, F., Sandra, P., Janssen, H., & Cramers, C. (1998). Capillary GC determination of amines in aqueous samples using sorptive preconcentration on polydimethylsiloxane and polyacrylate phases. HRC-JOURNAL OF HIGH RESOLUTION CHROMATOGRAPHY, 21(12), 645–648.
Chicago author-date
Baltussen, E, Frank David, Patrick Sandra, HG Janssen, and C Cramers. 1998. “Capillary GC Determination of Amines in Aqueous Samples Using Sorptive Preconcentration on Polydimethylsiloxane and Polyacrylate Phases.” HRC-JOURNAL OF HIGH RESOLUTION CHROMATOGRAPHY 21 (12): 645–48.
Chicago author-date (all authors)
Baltussen, E, Frank David, Patrick Sandra, HG Janssen, and C Cramers. 1998. “Capillary GC Determination of Amines in Aqueous Samples Using Sorptive Preconcentration on Polydimethylsiloxane and Polyacrylate Phases.” HRC-JOURNAL OF HIGH RESOLUTION CHROMATOGRAPHY 21 (12): 645–648.
Vancouver
1.
Baltussen E, David F, Sandra P, Janssen H, Cramers C. Capillary GC determination of amines in aqueous samples using sorptive preconcentration on polydimethylsiloxane and polyacrylate phases. HRC-JOURNAL OF HIGH RESOLUTION CHROMATOGRAPHY. 1998;21(12):645–8.
IEEE
[1]
E. Baltussen, F. David, P. Sandra, H. Janssen, and C. Cramers, “Capillary GC determination of amines in aqueous samples using sorptive preconcentration on polydimethylsiloxane and polyacrylate phases,” HRC-JOURNAL OF HIGH RESOLUTION CHROMATOGRAPHY, vol. 21, no. 12, pp. 645–648, 1998.
@article{181069,
  abstract     = {{The use of sorptive extraction/thermal desorption (SE/TD) for the enrichment of amines from aqueous samples was investigated. The amines were derivatized in situ in the water sample by pentafluorobenzoyl chloride and subsequently enriched onto the SE cartridge, Two SE/TD cartridges were used, a commercially available polydimethylsiloxane (PDMS) packed cartridge and a similar cartridge prepared with newly synthesized poly(butyl acrylate) (PBA), Blank profiles of PEA were not as good as those obtained from the PDMS phase. A complex chromatogram was obtained using mass spectrometric detection. Fortunately, the use of a nitrogen-phosphorus detector (NPD) resulted in clean blanks. The PEA phase showed superior performance for the enrichment of the polar amine derivatives from water samples compared to the PDMS material. Using a CGC-NPD set-up and only 1 mL samples, detection limits are in the sub-ppb range.}},
  author       = {{Baltussen, E and David, Frank and Sandra, Patrick and Janssen, HG and Cramers, C}},
  issn         = {{0935-6304}},
  journal      = {{HRC-JOURNAL OF HIGH RESOLUTION CHROMATOGRAPHY}},
  keywords     = {{gas chromatography (GC),nitrogen-phosphorus detection (NPD),sorptive extraction thermal desorption (SE/TD),amines,in-situ derivatization,CHROMATOGRAPHY MASS-SPECTROMETRY,SECONDARY ALIPHATIC-AMINES,GAS-CHROMATOGRAPHY,WATER,DERIVATIZATION}},
  language     = {{eng}},
  number       = {{12}},
  pages        = {{645--648}},
  title        = {{Capillary GC determination of amines in aqueous samples using sorptive preconcentration on polydimethylsiloxane and polyacrylate phases}},
  volume       = {{21}},
  year         = {{1998}},
}
Web of Science
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