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Hydrothermal synthesis, crystal structure and properties of Ag(I)-4f compounds based on 1H-benzimidazole-5,6-dicarboxylic acid

Yaquang Sun, Yong-Li Wu, Gang Xiong, Philippe Smet UGent, Fu Ding, Mei-yan Guo, Ming-chang Zhu, En-jun Gao, Dirk Poelman UGent and Francis Verpoort UGent (2010) DALTON TRANSACTIONS. 39(47). p.11383-11395
abstract
Seven novel heterometallic coordination polymers [CeAg(Hbidc)(2)(H2O)(2)](1) and [LnAg(Hbidc)(2)]center dot 3(H2O)[Ln = Sm (2), Gd (3), Tb (4), Dy (5), Ho (6), Er (7), H(3)bidc = 1H-benzimidazole-5,6-dicarboxylic acid] have been synthesized under hydrothermal conditions and characterized by elemental analysis, FT-IR, TG analysis, and single crystal X-ray diffraction. X-Ray analysis revealed that the seven complexes present two different types of three-dimensional (3D) structures. Complex 1 crystallized in an orthorhombic manner having a Pna2(1) space group, consisting of a 3D framework with a 1D heterometallic chain. Polymers 2-7 are isostructural and crystallized in an orthorhombic fashion having a Pccn space group existing of a two-fold interpenetrating 3D framework. The luminescence properties and the magnetic properties of all polymers were investigated.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
MAGNETIC-PROPERTIES, HYDROGEN STORAGE, O-DONOR LIGANDS, METAL-ORGANIC FRAMEWORKS, HETEROMETALLIC COORDINATION POLYMERS, ZEOLITIC IMIDAZOLATE FRAMEWORKS, BUILDING-BLOCKS, N-DONOR, LANTHANIDE, LN
journal title
DALTON TRANSACTIONS
Dalton Trans.
volume
39
issue
47
pages
11383 - 11395
Web of Science type
Article
Web of Science id
000284541600012
JCR category
CHEMISTRY, INORGANIC & NUCLEAR
JCR impact factor
3.647 (2010)
JCR rank
7/43 (2010)
JCR quartile
1 (2010)
ISSN
1477-9226
DOI
10.1039/c0dt00579g
language
English
UGent publication?
yes
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
1234552
handle
http://hdl.handle.net/1854/LU-1234552
date created
2011-05-24 16:19:49
date last changed
2018-01-29 12:12:58
@article{1234552,
  abstract     = {Seven novel heterometallic coordination polymers [CeAg(Hbidc)(2)(H2O)(2)](1) and [LnAg(Hbidc)(2)]center dot 3(H2O)[Ln = Sm (2), Gd (3), Tb (4), Dy (5), Ho (6), Er (7), H(3)bidc = 1H-benzimidazole-5,6-dicarboxylic acid] have been synthesized under hydrothermal conditions and characterized by elemental analysis, FT-IR, TG analysis, and single crystal X-ray diffraction. X-Ray analysis revealed that the seven complexes present two different types of three-dimensional (3D) structures. Complex 1 crystallized in an orthorhombic manner having a Pna2(1) space group, consisting of a 3D framework with a 1D heterometallic chain. Polymers 2-7 are isostructural and crystallized in an orthorhombic fashion having a Pccn space group existing of a two-fold interpenetrating 3D framework. The luminescence properties and the magnetic properties of all polymers were investigated.},
  author       = {Sun, Yaquang and Wu, Yong-Li and Xiong, Gang and Smet, Philippe and Ding, Fu and Guo, Mei-yan and Zhu, Ming-chang and Gao, En-jun and Poelman, Dirk and Verpoort, Francis},
  issn         = {1477-9226},
  journal      = {DALTON TRANSACTIONS},
  keyword      = {MAGNETIC-PROPERTIES,HYDROGEN STORAGE,O-DONOR LIGANDS,METAL-ORGANIC FRAMEWORKS,HETEROMETALLIC COORDINATION POLYMERS,ZEOLITIC IMIDAZOLATE FRAMEWORKS,BUILDING-BLOCKS,N-DONOR,LANTHANIDE,LN},
  language     = {eng},
  number       = {47},
  pages        = {11383--11395},
  title        = {Hydrothermal synthesis, crystal structure and properties of Ag(I)-4f compounds based on 1H-benzimidazole-5,6-dicarboxylic acid},
  url          = {http://dx.doi.org/10.1039/c0dt00579g},
  volume       = {39},
  year         = {2010},
}

Chicago
Sun, Yaquang, Yong-Li Wu, Gang Xiong, Philippe Smet, Fu Ding, Mei-yan Guo, Ming-chang Zhu, En-jun Gao, Dirk Poelman, and Francis Verpoort. 2010. “Hydrothermal Synthesis, Crystal Structure and Properties of Ag(I)-4f Compounds Based on 1H-benzimidazole-5,6-dicarboxylic Acid.” Dalton Transactions 39 (47): 11383–11395.
APA
Sun, Yaquang, Wu, Y.-L., Xiong, G., Smet, P., Ding, F., Guo, M., Zhu, M., et al. (2010). Hydrothermal synthesis, crystal structure and properties of Ag(I)-4f compounds based on 1H-benzimidazole-5,6-dicarboxylic acid. DALTON TRANSACTIONS, 39(47), 11383–11395.
Vancouver
1.
Sun Y, Wu Y-L, Xiong G, Smet P, Ding F, Guo M, et al. Hydrothermal synthesis, crystal structure and properties of Ag(I)-4f compounds based on 1H-benzimidazole-5,6-dicarboxylic acid. DALTON TRANSACTIONS. 2010;39(47):11383–95.
MLA
Sun, Yaquang, Yong-Li Wu, Gang Xiong, et al. “Hydrothermal Synthesis, Crystal Structure and Properties of Ag(I)-4f Compounds Based on 1H-benzimidazole-5,6-dicarboxylic Acid.” DALTON TRANSACTIONS 39.47 (2010): 11383–11395. Print.