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Poly(2-oxazoline)s based on fatty acids

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Abstract
Poly(2-oxazoline)s are an interesting class of synthetic poly(amide) s that can be prepared by living cationic ring-opening polymerization. The properties of poly(2-oxazoline) s can be tuned by variation of the 2-substituent of the 2-oxazoline monomer. In this contribution the utilization of fatty acids as side chains for poly(2-oxazoline) s is highlighted. The incorporation of such long aliphatic side-chains results in hydrophobic crystalline poly(2-oxazoline) s that are often applied for the preparation of amphiphilic structures as well as for low surface energy and low adhesive coatings. The most popular fatty-acid based poly(2-oxazoline) s are the saturated poly(2-nonyl-2-oxazoline) and poly(2-undecyl-2-oxazoline) as well as the unsaturated poly(2-decenyl-2-oxazoline) and poly(2-"soy alkyl''-2-oxazoline).
Keywords
Fatty acid, Cationic ring-opening polymerization, Green chemistry, Living polymerization, Polymer, Renewable resources, RING-OPENING POLYMERIZATION, CYCLIC IMINO ETHERS, PENDANT PENTAMETHYLDISILOXANYL GROUPS, MICROWAVE-ASSISTED SYNTHESIS, IRON TRIS(BIPYRIDINE)-CENTERED POLYOXAZOLINES, FLUORESCENCE CORRELATION SPECTROSCOPY, CRITICAL SOLUTION TEMPERATURE, UNDECYL OXAZOLINE BLOCK, N-AROYL ETHYLENIMINES), AIR-WATER-INTERFACE

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Citation

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Chicago
Hoogenboom, Richard. 2011. “Poly(2-oxazoline)s Based on Fatty Acids.” European Journal of Lipid Science and Technology 113 (1): 59–71.
APA
Hoogenboom, R. (2011). Poly(2-oxazoline)s based on fatty acids. EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY, 113(1), 59–71. Presented at the 3rd International workshop on Fats and Oils as Renewable Feedstock for the Chemical Industry.
Vancouver
1.
Hoogenboom R. Poly(2-oxazoline)s based on fatty acids. EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY. 2011;113(1):59–71.
MLA
Hoogenboom, Richard. “Poly(2-oxazoline)s Based on Fatty Acids.” EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY 113.1 (2011): 59–71. Print.
@article{1202306,
  abstract     = {Poly(2-oxazoline)s are an interesting class of synthetic poly(amide) s that can be prepared by living cationic ring-opening polymerization. The properties of poly(2-oxazoline) s can be tuned by variation of the 2-substituent of the 2-oxazoline monomer. In this contribution the utilization of fatty acids as side chains for poly(2-oxazoline) s is highlighted. The incorporation of such long aliphatic side-chains results in hydrophobic crystalline poly(2-oxazoline) s that are often applied for the preparation of amphiphilic structures as well as for low surface energy and low adhesive coatings. The most popular fatty-acid based poly(2-oxazoline) s are the saturated poly(2-nonyl-2-oxazoline) and poly(2-undecyl-2-oxazoline) as well as the unsaturated poly(2-decenyl-2-oxazoline) and poly(2-{\textacutedbl}soy alkyl''-2-oxazoline).},
  author       = {Hoogenboom, Richard},
  issn         = {1438-7697},
  journal      = {EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY},
  keyword      = {Fatty acid,Cationic ring-opening polymerization,Green chemistry,Living polymerization,Polymer,Renewable resources,RING-OPENING POLYMERIZATION,CYCLIC IMINO ETHERS,PENDANT PENTAMETHYLDISILOXANYL GROUPS,MICROWAVE-ASSISTED SYNTHESIS,IRON TRIS(BIPYRIDINE)-CENTERED POLYOXAZOLINES,FLUORESCENCE CORRELATION SPECTROSCOPY,CRITICAL SOLUTION TEMPERATURE,UNDECYL OXAZOLINE BLOCK,N-AROYL ETHYLENIMINES),AIR-WATER-INTERFACE},
  language     = {eng},
  location     = {Emden, Germany},
  number       = {1},
  pages        = {59--71},
  title        = {Poly(2-oxazoline)s based on fatty acids},
  url          = {http://dx.doi.org/10.1002/ejlt.201000122},
  volume       = {113},
  year         = {2011},
}

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