Advanced search
1 file | 161.80 KB

Hydroxy functional acrylates: enzymatic synthesis and free radical polymerization

Author
Organization
Abstract
Hydroxy functional acrylates were prepared via transacylation of methyl acrylate with 1,2,6-hexanetriol catalyzed by Candida antarctica lipase B. Under the applied reaction conditions, 70% of the substrate was converted into hydroxy functional acrylates. In a subsequent step, after filtration of the enzyme, the monomer mixture containing methyl acrylate and the new monomers was polymerized via free radical polymerization resulting in a functional copolymer with M-n = 14500 g/mol.
Keywords
DRUG-DELIVERY, TEMPERATURE, radical polymerization, functional monomers and polymers, enzyme-catalyzed transacylation, candida antarctica lipase-B

Downloads

  • (...).pdf
    • full text
    • |
    • UGent only
    • |
    • PDF
    • |
    • 161.80 KB

Citation

Please use this url to cite or link to this publication:

Chicago
Popescu, Dragos, Richard Hoogenboom, Helmut Keul, and Martin Möller. 2010. “Hydroxy Functional Acrylates: Enzymatic Synthesis and Free Radical Polymerization.” In Macromolecular Symposia, ed. F Stelzer and E Wiesbrock, 296:49–52. Weinheim, Germany: Wiley-VCH.
APA
Popescu, D., Hoogenboom, R., Keul, H., & Möller, M. (2010). Hydroxy functional acrylates: enzymatic synthesis and free radical polymerization. In F. Stelzer & E. Wiesbrock (Eds.), Macromolecular Symposia (Vol. 296, pp. 49–52). Presented at the 12th European Polymer Federation Congress, Weinheim, Germany: Wiley-VCH.
Vancouver
1.
Popescu D, Hoogenboom R, Keul H, Möller M. Hydroxy functional acrylates: enzymatic synthesis and free radical polymerization. In: Stelzer F, Wiesbrock E, editors. Macromolecular Symposia. Weinheim, Germany: Wiley-VCH; 2010. p. 49–52.
MLA
Popescu, Dragos, Richard Hoogenboom, Helmut Keul, et al. “Hydroxy Functional Acrylates: Enzymatic Synthesis and Free Radical Polymerization.” Macromolecular Symposia. Ed. F Stelzer & E Wiesbrock. Vol. 296. Weinheim, Germany: Wiley-VCH, 2010. 49–52. Print.
@inproceedings{1202298,
  abstract     = {Hydroxy functional acrylates were prepared via transacylation of methyl acrylate with 1,2,6-hexanetriol catalyzed by Candida antarctica lipase B. Under the applied reaction conditions, 70\% of the substrate was converted into hydroxy functional acrylates. In a subsequent step, after filtration of the enzyme, the monomer mixture containing methyl acrylate and the new monomers was polymerized via free radical polymerization resulting in a functional copolymer with M-n = 14500 g/mol.},
  author       = {Popescu, Dragos and Hoogenboom, Richard and Keul, Helmut and M{\"o}ller, Martin},
  booktitle    = {Macromolecular Symposia},
  editor       = {Stelzer, F and Wiesbrock, E},
  issn         = {1022-1360},
  keyword      = {DRUG-DELIVERY,TEMPERATURE,radical polymerization,functional monomers and polymers,enzyme-catalyzed transacylation,candida antarctica lipase-B},
  language     = {eng},
  location     = {Graz, Austria},
  pages        = {49--52},
  publisher    = {Wiley-VCH},
  title        = {Hydroxy functional acrylates: enzymatic synthesis and free radical polymerization},
  url          = {http://dx.doi.org/10.1002/masy.201051008},
  volume       = {296},
  year         = {2010},
}

Altmetric
View in Altmetric
Web of Science
Times cited: