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Hydroxy functional acrylates: enzymatic synthesis and free radical polymerization

Dragos Popescu, Richard Hoogenboom UGent, Helmut Keul and Martin Möller (2010) Macromolecular Symposia. In MACROMOLECULAR SYMPOSIA 296. p.49-52
abstract
Hydroxy functional acrylates were prepared via transacylation of methyl acrylate with 1,2,6-hexanetriol catalyzed by Candida antarctica lipase B. Under the applied reaction conditions, 70% of the substrate was converted into hydroxy functional acrylates. In a subsequent step, after filtration of the enzyme, the monomer mixture containing methyl acrylate and the new monomers was polymerized via free radical polymerization resulting in a functional copolymer with M-n = 14500 g/mol.
Please use this url to cite or link to this publication:
author
organization
year
type
conference (proceedingsPaper)
publication status
published
subject
keyword
DRUG-DELIVERY, TEMPERATURE, radical polymerization, functional monomers and polymers, enzyme-catalyzed transacylation, candida antarctica lipase-B
in
Macromolecular Symposia
editor
F Stelzer and E Wiesbrock
series title
MACROMOLECULAR SYMPOSIA
volume
296
issue title
Modern trends in polymer science EPF '09
pages
49 - 52
publisher
Wiley-VCH
place of publication
Weinheim, Germany
conference name
12th European Polymer Federation Congress
conference location
Graz, Austria
conference start
2009-07-12
conference end
2009-07-17
Web of Science type
Proceedings Paper
Web of Science id
000288040600008
ISSN
1022-1360
DOI
10.1002/masy.201051008
language
English
UGent publication?
no
classification
P1
copyright statement
I have transferred the copyright for this publication to the publisher
id
1202298
handle
http://hdl.handle.net/1854/LU-1202298
date created
2011-04-05 12:13:59
date last changed
2017-01-02 09:52:26
@inproceedings{1202298,
  abstract     = {Hydroxy functional acrylates were prepared via transacylation of methyl acrylate with 1,2,6-hexanetriol catalyzed by Candida antarctica lipase B. Under the applied reaction conditions, 70\% of the substrate was converted into hydroxy functional acrylates. In a subsequent step, after filtration of the enzyme, the monomer mixture containing methyl acrylate and the new monomers was polymerized via free radical polymerization resulting in a functional copolymer with M-n = 14500 g/mol.},
  author       = {Popescu, Dragos and Hoogenboom, Richard and Keul, Helmut and M{\"o}ller, Martin},
  booktitle    = {Macromolecular Symposia},
  editor       = {Stelzer, F and Wiesbrock, E},
  issn         = {1022-1360},
  keyword      = {DRUG-DELIVERY,TEMPERATURE,radical polymerization,functional monomers and polymers,enzyme-catalyzed transacylation,candida antarctica lipase-B},
  language     = {eng},
  location     = {Graz, Austria},
  pages        = {49--52},
  publisher    = {Wiley-VCH},
  title        = {Hydroxy functional acrylates: enzymatic synthesis and free radical polymerization},
  url          = {http://dx.doi.org/10.1002/masy.201051008},
  volume       = {296},
  year         = {2010},
}

Chicago
Popescu, Dragos, Richard Hoogenboom, Helmut Keul, and Martin Möller. 2010. “Hydroxy Functional Acrylates: Enzymatic Synthesis and Free Radical Polymerization.” In Macromolecular Symposia, ed. F Stelzer and E Wiesbrock, 296:49–52. Weinheim, Germany: Wiley-VCH.
APA
Popescu, D., Hoogenboom, R., Keul, H., & Möller, M. (2010). Hydroxy functional acrylates: enzymatic synthesis and free radical polymerization. In F. Stelzer & E. Wiesbrock (Eds.), Macromolecular Symposia (Vol. 296, pp. 49–52). Presented at the 12th European Polymer Federation Congress, Weinheim, Germany: Wiley-VCH.
Vancouver
1.
Popescu D, Hoogenboom R, Keul H, Möller M. Hydroxy functional acrylates: enzymatic synthesis and free radical polymerization. In: Stelzer F, Wiesbrock E, editors. Macromolecular Symposia. Weinheim, Germany: Wiley-VCH; 2010. p. 49–52.
MLA
Popescu, Dragos, Richard Hoogenboom, Helmut Keul, et al. “Hydroxy Functional Acrylates: Enzymatic Synthesis and Free Radical Polymerization.” Macromolecular Symposia. Ed. F Stelzer & E Wiesbrock. Vol. 296. Weinheim, Germany: Wiley-VCH, 2010. 49–52. Print.