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Abstract
Optical absorption and luminescence spectra of the Sm3+-doped fluorophosphate glasses 75NaPO(3)-24CaF(2)-1SmF(3) and 75NaPO(3)-24BaF(2)-1 SmF3, the phosphate glass 75NaPO(3)-24.5ZnO-0.5Sm(2)O(3) and the fluoride glass ZBLAN:Sm3+ have been recorded. The dipole strengths of the transitions in the absorption spectrum are parameterized in terms of three phenomenological Judd-Ofelt intensity parameters Omega(lambda) (lambda = 2, 4 and 6). The determination of intensity parameters for Sm3+ has inherent difficulties due to very large number of energy levels lying close to each other. In this case, we can take advantage of the property that both the dipole strengths and the squared reduced matrix elements of overlapping transitions are additive. The relation between the spectral intensities and the glass composition is discussed.
Keywords
glasses, absorption spectroscopy, lanthanides, rare earths, samarium, luminescence, Judd-Ofelt theory, LANTHANIDE IONS, SM3+, FLUORESCENCE, SPECTRA, SM-3+

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Citation

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Chicago
Van Deun, Rik, Koen Binnemans, C Gorller-Walrand, and Jean-Luc Adam. 1999. “Spectroscopic Properties of Trivalent Samarium Ions in Glasses.” In Proceedings of SPIE, the International Society for Optical Engineering, ed. Shibin Jiang and Seppo Honkanen, 3622:175–181. Bellingham, WA, USA: SPIE, the International Society for Optical Engineering.
APA
Van Deun, R., Binnemans, K., Gorller-Walrand, C., & Adam, J.-L. (1999). Spectroscopic properties of trivalent samarium ions in glasses. In S. Jiang & S. Honkanen (Eds.), Proceedings of SPIE, the International Society for Optical Engineering (Vol. 3622, pp. 175–181). Presented at the Conference on Rare-Earth-Doped Materials and Devices III, Bellingham, WA, USA: SPIE, the International Society for Optical Engineering.
Vancouver
1.
Van Deun R, Binnemans K, Gorller-Walrand C, Adam J-L. Spectroscopic properties of trivalent samarium ions in glasses. In: Jiang S, Honkanen S, editors. Proceedings of SPIE, the International Society for Optical Engineering. Bellingham, WA, USA: SPIE, the International Society for Optical Engineering; 1999. p. 175–81.
MLA
Van Deun, Rik, Koen Binnemans, C Gorller-Walrand, et al. “Spectroscopic Properties of Trivalent Samarium Ions in Glasses.” Proceedings of SPIE, the International Society for Optical Engineering. Ed. Shibin Jiang & Seppo Honkanen. Vol. 3622. Bellingham, WA, USA: SPIE, the International Society for Optical Engineering, 1999. 175–181. Print.
@inproceedings{1190436,
  abstract     = {Optical absorption and luminescence spectra of the Sm3+-doped fluorophosphate glasses 75NaPO(3)-24CaF(2)-1SmF(3) and 75NaPO(3)-24BaF(2)-1 SmF3, the phosphate glass 75NaPO(3)-24.5ZnO-0.5Sm(2)O(3) and the fluoride glass ZBLAN:Sm3+ have been recorded. The dipole strengths of the transitions in the absorption spectrum are parameterized in terms of three phenomenological Judd-Ofelt intensity parameters Omega(lambda) (lambda = 2, 4 and 6). The determination of intensity parameters for Sm3+ has inherent difficulties due to very large number of energy levels lying close to each other. In this case, we can take advantage of the property that both the dipole strengths and the squared reduced matrix elements of overlapping transitions are additive. The relation between the spectral intensities and the glass composition is discussed.},
  author       = {Van Deun, Rik and Binnemans, Koen and Gorller-Walrand, C and Adam, Jean-Luc},
  booktitle    = {Proceedings of SPIE, the International Society for Optical Engineering},
  editor       = {Jiang, Shibin and Honkanen, Seppo},
  isbn         = {0-8194-3092-7},
  issn         = {0277-786X},
  keyword      = {glasses,absorption spectroscopy,lanthanides,rare earths,samarium,luminescence,Judd-Ofelt theory,LANTHANIDE IONS,SM3+,FLUORESCENCE,SPECTRA,SM-3+},
  language     = {eng},
  location     = {San Jos{\'e}, CA, USA},
  pages        = {175--181},
  publisher    = {SPIE, the International Society for Optical Engineering},
  title        = {Spectroscopic properties of trivalent samarium ions in glasses},
  url          = {http://dx.doi.org/10.1117/12.344508},
  volume       = {3622},
  year         = {1999},
}

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