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Structure of [UO2Cl4](2-) in acetonitrile

Kelly Servaes, Christoph Hennig, Rik Van Deun UGent and Christiane Görller-Walrand (2005) INORGANIC CHEMISTRY. 44(22). p.7705-7707
abstract
The complex formation of uranyl UO22+ with chloride ions in acetonitrile was studied by UV-vis and U L-III EXAFS spectroscopy. The investigations unambiguously point to the existence of a [UO2Cl4](2-) species in solution with D-4h symmetry. The distances in the U(VI) coordination sphere are U-O-ax = 1.77 +/- 0.01 angstrom and U-Cl = 2.68 +/- 0.01 angstrom.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
CHLORO COMPLEXES, ELECTRONIC-STRUCTURE, SPECTROSCOPY, SPECTRA, EXAFS, AQUO
journal title
INORGANIC CHEMISTRY
Inorg. Chem.
volume
44
issue
22
pages
7705 - 7707
Web of Science type
Article
Web of Science id
000232898800006
JCR category
CHEMISTRY, INORGANIC & NUCLEAR
JCR impact factor
3.851 (2005)
JCR rank
6/43 (2005)
JCR quartile
1 (2005)
ISSN
0020-1669
DOI
10.1021/ic051098r
language
English
UGent publication?
no
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
1190204
handle
http://hdl.handle.net/1854/LU-1190204
date created
2011-03-16 16:13:27
date last changed
2018-01-29 12:12:59
@article{1190204,
  abstract     = {The complex formation of uranyl UO22+ with chloride ions in acetonitrile was studied by UV-vis and U L-III EXAFS spectroscopy. The investigations unambiguously point to the existence of a [UO2Cl4](2-) species in solution with D-4h symmetry. The distances in the U(VI) coordination sphere are U-O-ax = 1.77 +/- 0.01 angstrom and U-Cl = 2.68 +/- 0.01 angstrom.},
  author       = {Servaes, Kelly and Hennig, Christoph and Van Deun, Rik and G{\"o}rller-Walrand, Christiane},
  issn         = {0020-1669},
  journal      = {INORGANIC CHEMISTRY},
  keyword      = {CHLORO COMPLEXES,ELECTRONIC-STRUCTURE,SPECTROSCOPY,SPECTRA,EXAFS,AQUO},
  language     = {eng},
  number       = {22},
  pages        = {7705--7707},
  title        = {Structure of [UO2Cl4](2-) in acetonitrile},
  url          = {http://dx.doi.org/10.1021/ic051098r},
  volume       = {44},
  year         = {2005},
}

Chicago
Servaes, Kelly, Christoph Hennig, Rik Van Deun, and Christiane Görller-Walrand. 2005. “Structure of [UO2Cl4](2-) in Acetonitrile.” Inorganic Chemistry 44 (22): 7705–7707.
APA
Servaes, K., Hennig, C., Van Deun, R., & Görller-Walrand, C. (2005). Structure of [UO2Cl4](2-) in acetonitrile. INORGANIC CHEMISTRY, 44(22), 7705–7707.
Vancouver
1.
Servaes K, Hennig C, Van Deun R, Görller-Walrand C. Structure of [UO2Cl4](2-) in acetonitrile. INORGANIC CHEMISTRY. 2005;44(22):7705–7.
MLA
Servaes, Kelly, Christoph Hennig, Rik Van Deun, et al. “Structure of [UO2Cl4](2-) in Acetonitrile.” INORGANIC CHEMISTRY 44.22 (2005): 7705–7707. Print.