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Rhodium-catalysed hydroformylation of N-(2-propenyl)-β-lactams as a key step in the synthesis of functionalised N-[4-(2-oxoazetidin-1-yl)but-1-enyl]acetamides

(2010) NEW JOURNAL OF CHEMISTRY. 34(6). p.1079-1083
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Abstract
Biologically relevant functionalised N-[4-(2-oxoazetidin-1-yl)but-1-enyl]acetamides have been prepared in a two-step approach starting from N-(2-propenyl)-beta-lactams, involving initial rhodium-catalysed hydroformylation followed by subjection of the obtained aldehydes to Staudinger reaction conditions after initial imination.
Keywords
BETA-LACTAMS, LACTAM SYNTHON METHOD, ASYMMETRIC-SYNTHESIS, STEREOSELECTIVE-SYNTHESIS, BUILDING-BLOCKS, STAUDINGER REACTION, TRANSFORMATION, CYCLOADDITION, MACROLIDES, COMPLEXES

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Citation

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Chicago
Dekeukeleire, Stijn, Matthias D’hooghe, Christian Müller, Dieter Vogt, and Norbert De Kimpe. 2010. “Rhodium-catalysed Hydroformylation of N-(2-propenyl)-β-lactams as a Key Step in the Synthesis of Functionalised N-[4-(2-oxoazetidin-1-yl)but-1-enyl]acetamides.” New Journal of Chemistry 34 (6): 1079–1083.
APA
Dekeukeleire, S., D’hooghe, M., Müller, C., Vogt, D., & De Kimpe, N. (2010). Rhodium-catalysed hydroformylation of N-(2-propenyl)-β-lactams as a key step in the synthesis of functionalised N-[4-(2-oxoazetidin-1-yl)but-1-enyl]acetamides. NEW JOURNAL OF CHEMISTRY, 34(6), 1079–1083.
Vancouver
1.
Dekeukeleire S, D’hooghe M, Müller C, Vogt D, De Kimpe N. Rhodium-catalysed hydroformylation of N-(2-propenyl)-β-lactams as a key step in the synthesis of functionalised N-[4-(2-oxoazetidin-1-yl)but-1-enyl]acetamides. NEW JOURNAL OF CHEMISTRY. 2010;34(6):1079–83.
MLA
Dekeukeleire, Stijn, Matthias D’hooghe, Christian Müller, et al. “Rhodium-catalysed Hydroformylation of N-(2-propenyl)-β-lactams as a Key Step in the Synthesis of Functionalised N-[4-(2-oxoazetidin-1-yl)but-1-enyl]acetamides.” NEW JOURNAL OF CHEMISTRY 34.6 (2010): 1079–1083. Print.
@article{1091521,
  abstract     = {Biologically relevant functionalised N-[4-(2-oxoazetidin-1-yl)but-1-enyl]acetamides have been prepared in a two-step approach starting from N-(2-propenyl)-beta-lactams, involving initial rhodium-catalysed hydroformylation followed by subjection of the obtained aldehydes to Staudinger reaction conditions after initial imination.},
  author       = {Dekeukeleire, Stijn and D'hooghe, Matthias and M{\"u}ller, Christian and Vogt, Dieter and De Kimpe, Norbert},
  issn         = {1144-0546},
  journal      = {NEW JOURNAL OF CHEMISTRY},
  keyword      = {BETA-LACTAMS,LACTAM SYNTHON METHOD,ASYMMETRIC-SYNTHESIS,STEREOSELECTIVE-SYNTHESIS,BUILDING-BLOCKS,STAUDINGER REACTION,TRANSFORMATION,CYCLOADDITION,MACROLIDES,COMPLEXES},
  language     = {eng},
  number       = {6},
  pages        = {1079--1083},
  title        = {Rhodium-catalysed hydroformylation of N-(2-propenyl)-\ensuremath{\beta}-lactams as a key step in the synthesis of functionalised N-[4-(2-oxoazetidin-1-yl)but-1-enyl]acetamides},
  url          = {http://dx.doi.org/10.1039/c0nj00146e},
  volume       = {34},
  year         = {2010},
}

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