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A detailed study of the catalytic performance of V, Co and Cu MOFs in the oxidation of cyclohexene

Karen Leus UGent, Ilke Muylaert UGent, An Verberckmoes UGent, Guy Marin UGent, Ying-Ya Liu UGent, Veronique Van Speybroeck UGent and Pascal Van Der Voort UGent (2010) Metal Organic Frameworks, Book of abstracts. p.266-266
abstract
In this research, the catalytic performance of V-, Co- and Cu-MOFs, prepared with 1,4-benzenedicarboxylic (BDC) and/or 1,3,5-benzenetricarboxylic (BTC) ligands, is discussed for the oxidation of cyclohexene. Several parameters have been examined, for example: solvent, temperature and oxidans. The detailed product distributions and recyclability of these materials are discussed. Surprisingly, the highest conversions and highest yields of epoxide are achieved with the coordinatively saturared V-MOF, MIL-47. Indeed, these MOFs have a completely different geometry and coordination of the metal centre, which will be discussed in relation to the catalytic results. The Cu-MOFs studied have a Cu2 or Co2 paddle-wheel structure in which the metal centres have a square coordination to bidentate carboxylate ligands. The latter can be unsaturated (activated CuBTC and CuBDC) or saturated (CoBDC-DABCO). The studied V-MOF, MIL-47, has a three-dimensional orthorhombic structure in which every V centre is completely saturated [1].
Please use this url to cite or link to this publication:
author
organization
year
type
conference
publication status
published
subject
in
Metal Organic Frameworks, Book of abstracts
pages
266 - 266
conference name
Metal Organic Frameworks (MOF 2010)
conference location
Marseille, France
conference start
2010-09-05
conference end
2010-09-08
language
English
UGent publication?
yes
classification
C3
copyright statement
I have retained and own the full copyright for this publication
id
1077541
handle
http://hdl.handle.net/1854/LU-1077541
date created
2010-11-22 09:33:56
date last changed
2011-05-18 11:16:30
@inproceedings{1077541,
  abstract     = {In this research, the catalytic performance of V-, Co- and Cu-MOFs, prepared with 1,4-benzenedicarboxylic (BDC) and/or 1,3,5-benzenetricarboxylic (BTC) ligands, is discussed for the oxidation of cyclohexene. Several parameters have been examined, for example: solvent, temperature and oxidans. The detailed product distributions and recyclability of these materials are discussed. Surprisingly, the highest conversions and highest yields of epoxide are achieved with the coordinatively saturared V-MOF, MIL-47. Indeed, these MOFs have a completely different geometry and coordination of the metal centre, which will be discussed in relation to the catalytic results. The Cu-MOFs studied have a Cu2 or Co2 paddle-wheel structure in which the metal centres have a square coordination to bidentate carboxylate ligands. The latter can be unsaturated (activated CuBTC and CuBDC) or saturated (CoBDC-DABCO). The studied V-MOF, MIL-47, has a three-dimensional orthorhombic structure in which every V centre is completely saturated [1].},
  author       = {Leus, Karen and Muylaert, Ilke and Verberckmoes, An and Marin, Guy and Liu, Ying-Ya and Van Speybroeck, Veronique and Van Der Voort, Pascal},
  booktitle    = {Metal Organic Frameworks, Book of abstracts},
  language     = {eng},
  location     = {Marseille, France},
  pages        = {266--266},
  title        = {A detailed study of the catalytic performance of V, Co and Cu MOFs in the oxidation of cyclohexene},
  year         = {2010},
}

Chicago
Leus, Karen, Ilke Muylaert, An Verberckmoes, Guy Marin, Ying-Ya Liu, Veronique Van Speybroeck, and Pascal Van Der Voort. 2010. “A Detailed Study of the Catalytic Performance of V, Co and Cu MOFs in the Oxidation of Cyclohexene.” In Metal Organic Frameworks, Book of Abstracts, 266–266.
APA
Leus, K., Muylaert, I., Verberckmoes, A., Marin, G., Liu, Y.-Y., Van Speybroeck, V., & Van Der Voort, P. (2010). A detailed study of the catalytic performance of V, Co and Cu MOFs in the oxidation of cyclohexene. Metal Organic Frameworks, Book of abstracts (pp. 266–266). Presented at the Metal Organic Frameworks (MOF 2010).
Vancouver
1.
Leus K, Muylaert I, Verberckmoes A, Marin G, Liu Y-Y, Van Speybroeck V, et al. A detailed study of the catalytic performance of V, Co and Cu MOFs in the oxidation of cyclohexene. Metal Organic Frameworks, Book of abstracts. 2010. p. 266–266.
MLA
Leus, Karen, Ilke Muylaert, An Verberckmoes, et al. “A Detailed Study of the Catalytic Performance of V, Co and Cu MOFs in the Oxidation of Cyclohexene.” Metal Organic Frameworks, Book of Abstracts. 2010. 266–266. Print.