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Thermal, mechanical, and surface properties of poly(2-N-alkyl-2-oxazoline)s

Erik F-J Rettler, Johannes M Kranenburg, Hanneke ML Lambermont-Thijs, Richard Hoogenboom UGent and Ulrich S Schubert (2010) MACROMOLECULAR CHEMISTRY AND PHYSICS. 211(22). p.2443-2448
abstract
Thermal, mechanical, and surface properties of a library of poly(2-oxazoline)s are investigated. These polymers are suitable to study structure/property relationships as their cationic ROP and the relative facile monomer synthesis allow for control over the molecular structure. The number of carbon atoms in the linear side-chain is systematically varied from methyl to nonyl. Relations between chemical structures, thermal transitions, surface energies, and elastic moduli are discussed. It is shown that the mechanical and thermal properties of the polymers depend on the presence of a crystalline phase in the material. The amorphous polymers reveal a decrease in the reduced moduli along with a decrease in their respective glass transition temperature with increasing length of the side-chain.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
surface properties, structure-property relationships, polyoxazoline, HARDNESS, LIBRARY, POLYMERIZATION, COMBINATORIAL, INDENTATION, COPOLY(2-OXAZOLINE)S, HIGH-THROUGHPUT, ELASTIC-MODULUS, thermal properties, CYCLIC IMINO ETHERS
journal title
MACROMOLECULAR CHEMISTRY AND PHYSICS
Macromol. Chem. Phys.
volume
211
issue
22
pages
2443 - 2448
Web of Science type
Article
Web of Science id
000284210600009
JCR category
POLYMER SCIENCE
JCR impact factor
2.437 (2010)
JCR rank
19/78 (2010)
JCR quartile
1 (2010)
ISSN
1022-1352
DOI
10.1002/macp.201000338
language
English
UGent publication?
no
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
1072572
handle
http://hdl.handle.net/1854/LU-1072572
date created
2010-11-09 21:48:29
date last changed
2016-12-19 15:44:31
@article{1072572,
  abstract     = {Thermal, mechanical, and surface properties of a library of poly(2-oxazoline)s are investigated. These polymers are suitable to study structure/property relationships as their cationic ROP and the relative facile monomer synthesis allow for control over the molecular structure. The number of carbon atoms in the linear side-chain is systematically varied from methyl to nonyl. Relations between chemical structures, thermal transitions, surface energies, and elastic moduli are discussed. It is shown that the mechanical and thermal properties of the polymers depend on the presence of a crystalline phase in the material. The amorphous polymers reveal a decrease in the reduced moduli along with a decrease in their respective glass transition temperature with increasing length of the side-chain.},
  author       = {Rettler, Erik F-J and Kranenburg, Johannes M and Lambermont-Thijs, Hanneke ML and Hoogenboom, Richard and Schubert, Ulrich S},
  issn         = {1022-1352},
  journal      = {MACROMOLECULAR CHEMISTRY AND PHYSICS},
  keyword      = {surface properties,structure-property relationships,polyoxazoline,HARDNESS,LIBRARY,POLYMERIZATION,COMBINATORIAL,INDENTATION,COPOLY(2-OXAZOLINE)S,HIGH-THROUGHPUT,ELASTIC-MODULUS,thermal properties,CYCLIC IMINO ETHERS},
  language     = {eng},
  number       = {22},
  pages        = {2443--2448},
  title        = {Thermal, mechanical, and surface properties of poly(2-N-alkyl-2-oxazoline)s},
  url          = {http://dx.doi.org/10.1002/macp.201000338},
  volume       = {211},
  year         = {2010},
}

Chicago
Rettler, Erik F-J, Johannes M Kranenburg, Hanneke ML Lambermont-Thijs, Richard Hoogenboom, and Ulrich S Schubert. 2010. “Thermal, Mechanical, and Surface Properties of poly(2-N-alkyl-2-oxazoline)s.” Macromolecular Chemistry and Physics 211 (22): 2443–2448.
APA
Rettler, E. F.-J., Kranenburg, J. M., Lambermont-Thijs, H. M., Hoogenboom, R., & Schubert, U. S. (2010). Thermal, mechanical, and surface properties of poly(2-N-alkyl-2-oxazoline)s. MACROMOLECULAR CHEMISTRY AND PHYSICS, 211(22), 2443–2448.
Vancouver
1.
Rettler EF-J, Kranenburg JM, Lambermont-Thijs HM, Hoogenboom R, Schubert US. Thermal, mechanical, and surface properties of poly(2-N-alkyl-2-oxazoline)s. MACROMOLECULAR CHEMISTRY AND PHYSICS. 2010;211(22):2443–8.
MLA
Rettler, Erik F-J, Johannes M Kranenburg, Hanneke ML Lambermont-Thijs, et al. “Thermal, Mechanical, and Surface Properties of poly(2-N-alkyl-2-oxazoline)s.” MACROMOLECULAR CHEMISTRY AND PHYSICS 211.22 (2010): 2443–2448. Print.