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Temperature induced solubility transitions of various poly(2-oxazoline)s in ethanol-water solvent mixtures

Hanneke ML Lambermont-Thijs, Huub PC Van Kuringen, Jeroen PW van der Put, Ulrich S Schubert and Richard Hoogenboom UGent (2010) POLYMERS. 2(3). p.188-199
abstract
The solution behavior of a series of poly(2-oxazoline)s with different side chains, namely methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, pentyl, hexyl, heptyl, octyl, nonyl, phenyl and benzyl, are reported in ethanol-water solvent mixtures based on turbidimetry investigations. The LCST transitions of poly(2-oxazoline) s with propyl side chains and the UCST transitions of the poly(2-oxazoline) s with more hydrophobic side chains are discussed in relation to the ethanol-water solvent composition and structure. The poly(2-alkyl-2-oxazoline) s with side chains longer than propyl only dissolved during the first heating run, which is discussed and correlated to the melting transition of the polymers.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
UCST, LCST, thermoresponsiveness, solubility transitions, ethanol-water, poly(2-oxazoline)
journal title
POLYMERS
Polymers
volume
2
issue
3
issue title
Novel stimuli responsive (co)polymers
pages
188 - 199
Web of Science type
Article
Web of Science id
000208601000005
ISSN
2073-4360
DOI
10.3390/polym2030188
language
English
UGent publication?
yes
classification
A1
copyright statement
I have retained and own the full copyright for this publication
id
1021414
handle
http://hdl.handle.net/1854/LU-1021414
date created
2010-08-12 09:07:36
date last changed
2014-09-23 13:27:05
@article{1021414,
  abstract     = {The solution behavior of a series of poly(2-oxazoline)s with different side chains, namely methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, pentyl, hexyl, heptyl, octyl, nonyl, phenyl and benzyl, are reported in ethanol-water solvent mixtures based on turbidimetry investigations. The LCST transitions of poly(2-oxazoline) s with propyl side chains and the UCST transitions of the poly(2-oxazoline) s with more hydrophobic side chains are discussed in relation to the ethanol-water solvent composition and structure. The poly(2-alkyl-2-oxazoline) s with side chains longer than propyl only dissolved during the first heating run, which is discussed and correlated to the melting transition of the polymers.},
  author       = {Lambermont-Thijs, Hanneke ML and Van Kuringen, Huub PC  and van der Put, Jeroen PW and Schubert, Ulrich S and Hoogenboom, Richard},
  issn         = {2073-4360},
  journal      = {POLYMERS},
  keyword      = {UCST,LCST,thermoresponsiveness,solubility transitions,ethanol-water,poly(2-oxazoline)},
  language     = {eng},
  number       = {3},
  pages        = {188--199},
  title        = {Temperature induced solubility transitions of various poly(2-oxazoline)s in ethanol-water solvent mixtures},
  url          = {http://dx.doi.org/10.3390/polym2030188},
  volume       = {2},
  year         = {2010},
}

Chicago
Lambermont-Thijs, Hanneke ML, Huub PC Van Kuringen, Jeroen PW van der Put, Ulrich S Schubert, and Richard Hoogenboom. 2010. “Temperature Induced Solubility Transitions of Various Poly(2-oxazoline)s in Ethanol-water Solvent Mixtures.” Polymers 2 (3): 188–199.
APA
Lambermont-Thijs, H. M., Van Kuringen, H. P., van der Put, J. P., Schubert, U. S., & Hoogenboom, R. (2010). Temperature induced solubility transitions of various poly(2-oxazoline)s in ethanol-water solvent mixtures. POLYMERS, 2(3), 188–199.
Vancouver
1.
Lambermont-Thijs HM, Van Kuringen HP, van der Put JP, Schubert US, Hoogenboom R. Temperature induced solubility transitions of various poly(2-oxazoline)s in ethanol-water solvent mixtures. POLYMERS. 2010;2(3):188–99.
MLA
Lambermont-Thijs, Hanneke ML, Huub PC Van Kuringen, Jeroen PW van der Put, et al. “Temperature Induced Solubility Transitions of Various Poly(2-oxazoline)s in Ethanol-water Solvent Mixtures.” POLYMERS 2.3 (2010): 188–199. Print.