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A new sulphonic acid functionalized periodic mesoporous organosilica as a suitable catalyst

Els De Canck (UGent) , Carl Vercaemst (UGent) , Francis Verpoort (UGent) and Pascal Van Der Voort (UGent)
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Abstract
A new solid acid catalyst is developed by the direct sulphonation of the ethene bond of a pure trans ethene bridged Periodic Mesoporous Organosilica. The catalytic activity of this mesoporous material is evaluated in an esterification reaction and compared with ptoluenesulphonic acid. The sulphonated ethene PMO can compete with a homogeneous catalyst and maintains its porosity.
Keywords
Esterification., Periodic Mesoporous Organosilica, Catalyst, ESTERIFICATION, HYBRID

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Chicago
De Canck, Els, Carl Vercaemst, Francis Verpoort, and Pascal Van Der Voort. 2010. “A New Sulphonic Acid Functionalized Periodic Mesoporous Organosilica as a Suitable Catalyst.” In Studies in Surface Science and Catalysis, ed. Eric M Gaigneaux, M Devillers, S Hermans, PA Jacobs, JA Martens, and P Ruiz, 175:365–368. Amsterdam, The Netherlands: Elsevier.
APA
De Canck, E., Vercaemst, C., Verpoort, F., & Van Der Voort, P. (2010). A new sulphonic acid functionalized periodic mesoporous organosilica as a suitable catalyst. In E. M. Gaigneaux, M. Devillers, S. Hermans, P. Jacobs, J. Martens, & P. Ruiz (Eds.), Studies in Surface Science and Catalysis (Vol. 175, pp. 365–368). Presented at the 10th International symposium on Scientific Bases for the Preparation of Heterogeneous Catalysts (PREPA-10), Amsterdam, The Netherlands: Elsevier.
Vancouver
1.
De Canck E, Vercaemst C, Verpoort F, Van Der Voort P. A new sulphonic acid functionalized periodic mesoporous organosilica as a suitable catalyst. In: Gaigneaux EM, Devillers M, Hermans S, Jacobs P, Martens J, Ruiz P, editors. Studies in Surface Science and Catalysis. Amsterdam, The Netherlands: Elsevier; 2010. p. 365–8.
MLA
De Canck, Els, Carl Vercaemst, Francis Verpoort, et al. “A New Sulphonic Acid Functionalized Periodic Mesoporous Organosilica as a Suitable Catalyst.” Studies in Surface Science and Catalysis. Ed. Eric M Gaigneaux et al. Vol. 175. Amsterdam, The Netherlands: Elsevier, 2010. 365–368. Print.
@inproceedings{1013057,
  abstract     = {A new solid acid catalyst is developed by the direct sulphonation of the ethene bond of a pure trans ethene bridged Periodic Mesoporous Organosilica. The catalytic activity of this mesoporous material is evaluated in an esterification reaction and compared with ptoluenesulphonic acid. The sulphonated ethene PMO can compete with a homogeneous catalyst and maintains its porosity.},
  author       = {De Canck, Els and Vercaemst, Carl and Verpoort, Francis and Van Der Voort, Pascal},
  booktitle    = {Studies in Surface Science and Catalysis},
  editor       = {Gaigneaux, Eric M and Devillers, M and Hermans, S and Jacobs, PA and Martens, JA and Ruiz, P},
  isbn         = {9780444536013},
  issn         = {0167-2991},
  keyword      = {Esterification.,Periodic Mesoporous Organosilica,Catalyst,ESTERIFICATION,HYBRID},
  language     = {eng},
  location     = {Louvain la Neuve, Belgium},
  pages        = {365--368},
  publisher    = {Elsevier},
  title        = {A new sulphonic acid functionalized periodic mesoporous organosilica as a suitable catalyst},
  url          = {http://dx.doi.org/10.1016/S0167-2991(10)75061-8},
  volume       = {175},
  year         = {2010},
}

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