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A coordinative saturated vanadium containing metal organic framework that shows a remarkable catalytic activity

Karen Leus (UGent) , Ilke Muylaert (UGent) , Veronique Van Speybroeck (UGent) , Guy Marin (UGent) and Pascal Van Der Voort (UGent)
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Abstract
A completely saturated Metal Organic Framework, MIL-47 was synthesized and tested for its catalytic performance in the oxidation of cyclohexene with tert-butyl hydroperoxide as oxidant. The catalyst was compared to several reference catalysts: namely VAPO-5, supported VOx/SiO2 and the homogeneous catalyst VO(acac)(2). MIL-47 shows a remarkable catalytic activity and preserves its crystalline structure and surface area after a catalytic run. Furthermore MIL-47 exhibits a very high activity in successive runs.
Keywords
Metal Organic Frameworks, vanadium, oxidation, liquid phase, INDUSTRIAL APPLICATIONS, POLYMERS, OXIDATION

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Chicago
Leus, Karen, Ilke Muylaert, Veronique Van Speybroeck, Guy Marin, and Pascal Van Der Voort. 2010. “A Coordinative Saturated Vanadium Containing Metal Organic Framework That Shows a Remarkable Catalytic Activity.” In Studies in Surface Science and Catalysis, ed. Eric M Gaigneaux, M Devillers, S Hermans, PA Jacobs, JA Martens, and P Ruiz, 175:329–332. Amsterdam, The Netherlands: Elsevier.
APA
Leus, K., Muylaert, I., Van Speybroeck, V., Marin, G., & Van Der Voort, P. (2010). A coordinative saturated vanadium containing metal organic framework that shows a remarkable catalytic activity. In E. M. Gaigneaux, M. Devillers, S. Hermans, P. Jacobs, J. Martens, & P. Ruiz (Eds.), Studies in Surface Science and Catalysis (Vol. 175, pp. 329–332). Presented at the 10th International symposium on Scientific Bases for the Preparation of Heterogeneous Catalysts (PREPA-10), Amsterdam, The Netherlands: Elsevier.
Vancouver
1.
Leus K, Muylaert I, Van Speybroeck V, Marin G, Van Der Voort P. A coordinative saturated vanadium containing metal organic framework that shows a remarkable catalytic activity. In: Gaigneaux EM, Devillers M, Hermans S, Jacobs P, Martens J, Ruiz P, editors. Studies in Surface Science and Catalysis. Amsterdam, The Netherlands: Elsevier; 2010. p. 329–32.
MLA
Leus, Karen, Ilke Muylaert, Veronique Van Speybroeck, et al. “A Coordinative Saturated Vanadium Containing Metal Organic Framework That Shows a Remarkable Catalytic Activity.” Studies in Surface Science and Catalysis. Ed. Eric M Gaigneaux et al. Vol. 175. Amsterdam, The Netherlands: Elsevier, 2010. 329–332. Print.
@inproceedings{1013038,
  abstract     = {A completely saturated Metal Organic Framework, MIL-47 was synthesized and tested for its catalytic performance in the oxidation of cyclohexene with tert-butyl hydroperoxide as oxidant. The catalyst was compared to several reference catalysts: namely VAPO-5, supported VOx/SiO2 and the homogeneous catalyst VO(acac)(2). MIL-47 shows a remarkable catalytic activity and preserves its crystalline structure and surface area after a catalytic run. Furthermore MIL-47 exhibits a very high activity in successive runs.},
  author       = {Leus, Karen and Muylaert, Ilke and Van Speybroeck, Veronique and Marin, Guy and Van Der Voort, Pascal},
  booktitle    = {Studies in Surface Science and Catalysis},
  editor       = {Gaigneaux, Eric M and Devillers, M and Hermans, S and Jacobs, PA and Martens, JA and Ruiz, P},
  isbn         = {9780444536013},
  issn         = {0167-2991},
  keyword      = {Metal Organic Frameworks,vanadium,oxidation,liquid phase,INDUSTRIAL APPLICATIONS,POLYMERS,OXIDATION},
  language     = {eng},
  location     = {Louvain la Neuve, Belgium},
  pages        = {329--332},
  publisher    = {Elsevier},
  title        = {A coordinative saturated vanadium containing metal organic framework that shows a remarkable catalytic activity},
  url          = {http://dx.doi.org/10.1016/S0167-2991(10)75053-9},
  volume       = {175},
  year         = {2010},
}

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