Controlled synthesis of crystalline metalated porphyrin covalent organic frameworks through an assembler approach
- Author
- Laurens Bourda, Isaac Dansette, Jena Himanshu (UGent) , Hui Chen, Asif RAZA, Henk Vrielinck (UGent) , Kristof Van Hecke (UGent) , Pascal Van Der Voort (UGent) and Chidharth Krishnaraj
- Organization
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- Tailored crystals on-demand: gaining a full understanding of the crystallization of low-dimsional hybrid perovskites.
- DEFMOD: DEFect-engineering and machine learning MODeling of UiO-66 and its catalytic properties.
- Covalent Organic Framework based Z-scheme Photoelectrochemical cell for total water splitting.
- Magnetische resonantieapparatuur voor gevorderd materiaalonderzoek: moleculaire karakterisering van vaste, zachte, homogene en heterogene materie in de ontwikkeling van geavanceerde functionele materialen en chemische katalyse
- Developing mechanically flexible photoluminescent organic crystals
- Abstract
- Covalent organic frameworks (COFs) have gained a lot of attention in recent years due to their tunable porosity and functionality. Porphyrin-containing COFs have proven effective in several applications such as photo- and electrocatalysis. However, a standard reproducible procedure for the synthesis of crystalline metalated porphyrin COFs remains challenging. In this work, a general procedure using an "assembler" approach based on preorientation is reported. Octahedrally coordinating metal ions were used along with pyridinic ligands in addition to the starting monomers of the COF in a one-pot synthesis method to produce crystalline metalated porphyrin COFs with high surface area and reproducibility. Different metals, assemblers, and assembler loadings were studied, and their performances are compared. This method allows the production of high-quality porphyrin COFs which are useful for a range of applications such as catalysis, sensor technology, energy storage, and photodynamic therapy.
- Keywords
- COORDINATION
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Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-01JDFS7EANV3P2BPV0G7SQQ7WY
- MLA
- Bourda, Laurens, et al. “Controlled Synthesis of Crystalline Metalated Porphyrin Covalent Organic Frameworks through an Assembler Approach.” CHEMISTRY OF MATERIALS, vol. 36, no. 19, 2024, pp. 9526–34, doi:10.1021/acs.chemmater.4c01338.
- APA
- Bourda, L., Dansette, I., Himanshu, J., Chen, H., RAZA, A., Vrielinck, H., … Krishnaraj, C. (2024). Controlled synthesis of crystalline metalated porphyrin covalent organic frameworks through an assembler approach. CHEMISTRY OF MATERIALS, 36(19), 9526–9534. https://doi.org/10.1021/acs.chemmater.4c01338
- Chicago author-date
- Bourda, Laurens, Isaac Dansette, Jena Himanshu, Hui Chen, Asif RAZA, Henk Vrielinck, Kristof Van Hecke, Pascal Van Der Voort, and Chidharth Krishnaraj. 2024. “Controlled Synthesis of Crystalline Metalated Porphyrin Covalent Organic Frameworks through an Assembler Approach.” CHEMISTRY OF MATERIALS 36 (19): 9526–34. https://doi.org/10.1021/acs.chemmater.4c01338.
- Chicago author-date (all authors)
- Bourda, Laurens, Isaac Dansette, Jena Himanshu, Hui Chen, Asif RAZA, Henk Vrielinck, Kristof Van Hecke, Pascal Van Der Voort, and Chidharth Krishnaraj. 2024. “Controlled Synthesis of Crystalline Metalated Porphyrin Covalent Organic Frameworks through an Assembler Approach.” CHEMISTRY OF MATERIALS 36 (19): 9526–9534. doi:10.1021/acs.chemmater.4c01338.
- Vancouver
- 1.Bourda L, Dansette I, Himanshu J, Chen H, RAZA A, Vrielinck H, et al. Controlled synthesis of crystalline metalated porphyrin covalent organic frameworks through an assembler approach. CHEMISTRY OF MATERIALS. 2024;36(19):9526–34.
- IEEE
- [1]L. Bourda et al., “Controlled synthesis of crystalline metalated porphyrin covalent organic frameworks through an assembler approach,” CHEMISTRY OF MATERIALS, vol. 36, no. 19, pp. 9526–9534, 2024.
@article{01JDFS7EANV3P2BPV0G7SQQ7WY,
abstract = {{Covalent organic frameworks (COFs) have gained a lot of attention in
recent years due to their tunable porosity and functionality.
Porphyrin-containing COFs have proven effective in several applications
such as photo- and electrocatalysis. However, a standard reproducible
procedure for the synthesis of crystalline metalated porphyrin COFs
remains challenging. In this work, a general procedure using an
"assembler" approach based on preorientation is reported. Octahedrally
coordinating metal ions were used along with pyridinic ligands in
addition to the starting monomers of the COF in a one-pot synthesis
method to produce crystalline metalated porphyrin COFs with high surface
area and reproducibility. Different metals, assemblers, and assembler
loadings were studied, and their performances are compared. This method
allows the production of high-quality porphyrin COFs which are useful
for a range of applications such as catalysis, sensor technology, energy
storage, and photodynamic therapy.}},
author = {{Bourda, Laurens and Dansette, Isaac and Himanshu, Jena and Chen, Hui and RAZA, Asif and Vrielinck, Henk and Van Hecke, Kristof and Van Der Voort, Pascal and Krishnaraj, Chidharth}},
issn = {{0897-4756}},
journal = {{CHEMISTRY OF MATERIALS}},
keywords = {{COORDINATION}},
language = {{eng}},
number = {{19}},
pages = {{9526--9534}},
title = {{Controlled synthesis of crystalline metalated porphyrin covalent organic frameworks through an assembler approach}},
url = {{http://doi.org/10.1021/acs.chemmater.4c01338}},
volume = {{36}},
year = {{2024}},
}
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