
Evaluation of hydrogen interactions with defects induced by deformation in the duplex stainless steel microstructure : an internal friction study
- Author
- Liese Vandewalle (UGent) , Lisa Claeys (UGent) , Milan J. Konstantinović, Kim Verbeken (UGent) and Tom Depover (UGent)
- Organization
- Project
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- Elucidating the role of hydrogen on the deformation mechanisms of high entropy alloys: leading to hydrogen-resistant materials?
- Study of the hydrogen-(carbon-)vacancy interactions in iron-based alloys
- Evaluation of the hydrogen/metal interaction via determination of the hydrogen content and thermal desorption spectroscopy
- Impact of CO2 and H2 on material behaviour during electrochemical processes
- Mechanical assessment of metals after gaseous hydrogenation.
- Abstract
- Despite their good corrosion resistance and optimal mechanical properties, duplex stainless steels are affected by hydrogen embrittlement. Therefore, understanding the hydrogen -defect interactions in these steels is crucial. This study uses internal friction to evaluate the interactions of hydrogen with microstructural defects. Analysis of the internal friction spectra of the steels subjected to straining and hydrogen charging, together with thorough microstructural characterization, gives new insights in hydrogen interactions with defects present in the different phases, i.e. ferrite (body centered cubic) and austenite (face centered cubic). While no significant effect of tensile deformation can be observed by thermal desorption spectroscopy, the internal friction spectra show a clear influence of the presence of defects. Detailed analysis of these spectra reveals the interactions in the austenite as dominant, while no indications for hydrogen -dislocation interactions in ferrite are observed. This can be related to limited trapping in ferrite due to the austenite sink action or to limited dislocation formation in ferrite. Indications for hydrogen interactions with dislocations in the austenite are found, possibly suggesting enhanced dislocation mobility when surrounded by hydrogen. Moreover, a pronounced influence of hydrogen charging on the vacancy cluster related peaks is observed, indicating strong interactions between hydrogen and vacancy clusters in austenite. This can be put in contrast to behavior of pure ferritic steels, where dislocations provided the strongest hydrogen interactions. As these specific defects are of primary interest in the hydrogen embrittlement mechanisms, internal friction is concluded to provide important unique insights in hydrogen -defect interactions, even for complicated multiphase microstructures.
- Keywords
- Vacancy clusters, Dislocations, Duplex steel, Hydrogen trapping, Internal friction
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Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-01HYFQ5CS215361ZHVAPCZ66ZF
- MLA
- Vandewalle, Liese, et al. “Evaluation of Hydrogen Interactions with Defects Induced by Deformation in the Duplex Stainless Steel Microstructure : An Internal Friction Study.” ACTA MATERIALIA, vol. 268, 2024, doi:10.1016/j.actamat.2024.119800.
- APA
- Vandewalle, L., Claeys, L., Konstantinović, M. J., Verbeken, K., & Depover, T. (2024). Evaluation of hydrogen interactions with defects induced by deformation in the duplex stainless steel microstructure : an internal friction study. ACTA MATERIALIA, 268. https://doi.org/10.1016/j.actamat.2024.119800
- Chicago author-date
- Vandewalle, Liese, Lisa Claeys, Milan J. Konstantinović, Kim Verbeken, and Tom Depover. 2024. “Evaluation of Hydrogen Interactions with Defects Induced by Deformation in the Duplex Stainless Steel Microstructure : An Internal Friction Study.” ACTA MATERIALIA 268. https://doi.org/10.1016/j.actamat.2024.119800.
- Chicago author-date (all authors)
- Vandewalle, Liese, Lisa Claeys, Milan J. Konstantinović, Kim Verbeken, and Tom Depover. 2024. “Evaluation of Hydrogen Interactions with Defects Induced by Deformation in the Duplex Stainless Steel Microstructure : An Internal Friction Study.” ACTA MATERIALIA 268. doi:10.1016/j.actamat.2024.119800.
- Vancouver
- 1.Vandewalle L, Claeys L, Konstantinović MJ, Verbeken K, Depover T. Evaluation of hydrogen interactions with defects induced by deformation in the duplex stainless steel microstructure : an internal friction study. ACTA MATERIALIA. 2024;268.
- IEEE
- [1]L. Vandewalle, L. Claeys, M. J. Konstantinović, K. Verbeken, and T. Depover, “Evaluation of hydrogen interactions with defects induced by deformation in the duplex stainless steel microstructure : an internal friction study,” ACTA MATERIALIA, vol. 268, 2024.
@article{01HYFQ5CS215361ZHVAPCZ66ZF, abstract = {{Despite their good corrosion resistance and optimal mechanical properties, duplex stainless steels are affected by hydrogen embrittlement. Therefore, understanding the hydrogen -defect interactions in these steels is crucial. This study uses internal friction to evaluate the interactions of hydrogen with microstructural defects. Analysis of the internal friction spectra of the steels subjected to straining and hydrogen charging, together with thorough microstructural characterization, gives new insights in hydrogen interactions with defects present in the different phases, i.e. ferrite (body centered cubic) and austenite (face centered cubic). While no significant effect of tensile deformation can be observed by thermal desorption spectroscopy, the internal friction spectra show a clear influence of the presence of defects. Detailed analysis of these spectra reveals the interactions in the austenite as dominant, while no indications for hydrogen -dislocation interactions in ferrite are observed. This can be related to limited trapping in ferrite due to the austenite sink action or to limited dislocation formation in ferrite. Indications for hydrogen interactions with dislocations in the austenite are found, possibly suggesting enhanced dislocation mobility when surrounded by hydrogen. Moreover, a pronounced influence of hydrogen charging on the vacancy cluster related peaks is observed, indicating strong interactions between hydrogen and vacancy clusters in austenite. This can be put in contrast to behavior of pure ferritic steels, where dislocations provided the strongest hydrogen interactions. As these specific defects are of primary interest in the hydrogen embrittlement mechanisms, internal friction is concluded to provide important unique insights in hydrogen -defect interactions, even for complicated multiphase microstructures.}}, articleno = {{119800}}, author = {{Vandewalle, Liese and Claeys, Lisa and Konstantinović, Milan J. and Verbeken, Kim and Depover, Tom}}, issn = {{1359-6454}}, journal = {{ACTA MATERIALIA}}, keywords = {{Vacancy clusters,Dislocations,Duplex steel,Hydrogen trapping,Internal friction}}, language = {{eng}}, pages = {{14}}, title = {{Evaluation of hydrogen interactions with defects induced by deformation in the duplex stainless steel microstructure : an internal friction study}}, url = {{http://doi.org/10.1016/j.actamat.2024.119800}}, volume = {{268}}, year = {{2024}}, }
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