@article{01HSBC0J3N9CFDRVJJVM0PR1Y1,
  abstract     = {{The choice of reducing agents and their impact on catalytic performance are important aspects of selective catalytic reduction (SCR) technology. Marking the inaugural use of C3H6 as a reducing agent with the BTC catalyst, a bimetallic organic framework (xCu-Mn-BTC) was prepared and tested as a catalyst for NOx reduction under oxygen-enriched conditions. The results showed that NO conversion was influenced by the ratio of Cu and Mn metals, among which 3.2Cu-Mn-BTC exhibited the highest denitrification performance (80 % NOx conversion and 94 % N2 selectivity) at 300 degrees C. From the characterization results, Cu was successfully incorporated into the BTC framework and 3.2Cu-Mn-BTC became spherical grains with smaller particle sizes. The high catalytic activity of 3.2Cu-Mn-BTC was due to the presence of more adsorbed oxygen O alpha (89.7 %) and Cu2+ (63 %) species than in the other catalysts. The TPR peak of xCu-Mn-BTC shifted to a lower temperature and showed better reducibility. The Py-FTIR study shows that xCu-Mn-BTC contained more Lewis acid but no Br & oslash;nsted acid, because Cu increased the concentration of Lewis acid on the catalytic surface (42 to 46 mmol/g), and Lewis acid plays an important role in the C3H6-SCR of NOx.
}},
  articleno    = {{131508}},
  author       = {{Liu, Quan and Kashif, Muhammad and Deng, Wenyi and Zhao, Bingtao and Heynderickx, Philippe and Su, Yaxin}},
  issn         = {{0016-2361}},
  journal      = {{FUEL}},
  keywords     = {{NOx,Metal-organic frameworks (MOFs),xCu-Mn-BTC catalysts,METAL-ORGANIC FRAMEWORK,LEWIS ACIDITY,CU,TEMPERATURE,PERFORMANCE,EFFICIENT,REMOVAL,OXIDES,MN,CO}},
  language     = {{eng}},
  pages        = {{12}},
  title        = {{Exploring the role of Cu/Mn-BTC catalyst in the selective catalytic reduction of NOx by C3H6 : synthesis to In-situ DRIFTS study}},
  url          = {{http://doi.org/10.1016/j.fuel.2024.131508}},
  volume       = {{367}},
  year         = {{2024}},
}

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