Novel dinuclear NHC-gold(i)-amido complexes and their application in energy transfer photocatalysis
- Author
- Xinyuan Ma, Vladislav Voloshkin (UGent) , Ekaterina Martynova, Marek Beliš (UGent) , Min Peng, Marco Villa, Nikolaos Tzouras, Wim Janssens, Kristof Van Hecke (UGent) , Paola Ceroni and Steven Nolan (UGent)
- Organization
- Project
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- Gold Photocatalysis (PhotAuCat)
- CO2PERATE - Volledig hernieuwbare CCU op basis van mierenzuur geïntegreerd in een industrieel microgrid
- Development of hydrosilylation catalysts
- BOF-ZAP-ambt in homogene katalyse en organometaalchemie
- Study of nucleation and crystal growth of pharmaceuticals by X-ray and harmonic light scattering
- Abstract
- The development of efficient and operationally simple synthetic routes to dinuclear gold(i)-amido complexes bearing aromatic/aliphatic-bridges are reported. This family of complexes was prepared utilizing environmentally friendly and sustainable reagents under mild conditions, resulting in 68-92% yields of the targeted compounds. These novel dinuclear gold(i)-amido complexes were structurally and spectroscopically characterized. Their photophysical properties were also studied. This series of gold complexes are phosphorescent with lifetimes in the hundreds of microseconds range. They exhibit high catalytic activity as photosensitizers in intramolecular cycloaddition and cyclization reactions at catalyst loadings ranging from 0.5 to 2 mol%.
- Keywords
- GOLD NANOPARTICLES, CARBENE, PHOTOEMITTERS, METALS, AMIDES
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Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-01HQ3EAK3ZGVTVNX31HDZA3JBP
- MLA
- Ma, Xinyuan, et al. “Novel Dinuclear NHC-Gold(i)-Amido Complexes and Their Application in Energy Transfer Photocatalysis.” CATALYSIS SCIENCE & TECHNOLOGY, vol. 13, no. 14, 2023, pp. 4168–75, doi:10.1039/d3cy00716b.
- APA
- Ma, X., Voloshkin, V., Martynova, E., Beliš, M., Peng, M., Villa, M., … Nolan, S. (2023). Novel dinuclear NHC-gold(i)-amido complexes and their application in energy transfer photocatalysis. CATALYSIS SCIENCE & TECHNOLOGY, 13(14), 4168–4175. https://doi.org/10.1039/d3cy00716b
- Chicago author-date
- Ma, Xinyuan, Vladislav Voloshkin, Ekaterina Martynova, Marek Beliš, Min Peng, Marco Villa, Nikolaos Tzouras, et al. 2023. “Novel Dinuclear NHC-Gold(i)-Amido Complexes and Their Application in Energy Transfer Photocatalysis.” CATALYSIS SCIENCE & TECHNOLOGY 13 (14): 4168–75. https://doi.org/10.1039/d3cy00716b.
- Chicago author-date (all authors)
- Ma, Xinyuan, Vladislav Voloshkin, Ekaterina Martynova, Marek Beliš, Min Peng, Marco Villa, Nikolaos Tzouras, Wim Janssens, Kristof Van Hecke, Paola Ceroni, and Steven Nolan. 2023. “Novel Dinuclear NHC-Gold(i)-Amido Complexes and Their Application in Energy Transfer Photocatalysis.” CATALYSIS SCIENCE & TECHNOLOGY 13 (14): 4168–4175. doi:10.1039/d3cy00716b.
- Vancouver
- 1.Ma X, Voloshkin V, Martynova E, Beliš M, Peng M, Villa M, et al. Novel dinuclear NHC-gold(i)-amido complexes and their application in energy transfer photocatalysis. CATALYSIS SCIENCE & TECHNOLOGY. 2023;13(14):4168–75.
- IEEE
- [1]X. Ma et al., “Novel dinuclear NHC-gold(i)-amido complexes and their application in energy transfer photocatalysis,” CATALYSIS SCIENCE & TECHNOLOGY, vol. 13, no. 14, pp. 4168–4175, 2023.
@article{01HQ3EAK3ZGVTVNX31HDZA3JBP,
abstract = {{The development of efficient and operationally simple synthetic routes to dinuclear gold(i)-amido complexes bearing aromatic/aliphatic-bridges are reported. This family of complexes was prepared utilizing environmentally friendly and sustainable reagents under mild conditions, resulting in 68-92% yields of the targeted compounds. These novel dinuclear gold(i)-amido complexes were structurally and spectroscopically characterized. Their photophysical properties were also studied. This series of gold complexes are phosphorescent with lifetimes in the hundreds of microseconds range. They exhibit high catalytic activity as photosensitizers in intramolecular cycloaddition and cyclization reactions at catalyst loadings ranging from 0.5 to 2 mol%.}},
author = {{Ma, Xinyuan and Voloshkin, Vladislav and Martynova, Ekaterina and Beliš, Marek and Peng, Min and Villa, Marco and Tzouras, Nikolaos and Janssens, Wim and Van Hecke, Kristof and Ceroni, Paola and Nolan, Steven}},
issn = {{2044-4753}},
journal = {{CATALYSIS SCIENCE & TECHNOLOGY}},
keywords = {{GOLD NANOPARTICLES,CARBENE,PHOTOEMITTERS,METALS,AMIDES}},
language = {{eng}},
number = {{14}},
pages = {{4168--4175}},
title = {{Novel dinuclear NHC-gold(i)-amido complexes and their application in energy transfer photocatalysis}},
url = {{http://doi.org/10.1039/d3cy00716b}},
volume = {{13}},
year = {{2023}},
}
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