Gold complexes with remote-substituted amino N-heterocyclic carbenes
- Author
- Sofie Vanden Broeck, Nikolaos Tzouras, Marina Saab, Kristof Van Hecke (UGent) , Busra Dereli, Ida Ritacco, Luigi Cavallo, Georgios C. C. Vougioukalakis, Pierre Braunstein, Steven Nolan (UGent) , Andreas A. A. Danopoulos and Catherine Cazin (UGent)
- Organization
- Project
- Abstract
- The 4-RN-1,3-Ar-2-imidazolium salt, R = iPr, tBu, Ar = Mes, Dipp, Mes = mesityl, Dipp = 2,6-bis-diisopropyl-phenyl was metalated by Au-I at the C2-, C5- and 4-RN positions depending on the reactants and conditions employed; a rare direct rearrangement of a Au-I aminide to an abnormal imidazol-5-ylidene Au-I complex was also observed and based on a DFT study it may involve TfO- facilitated H+ transfer.
- Keywords
- REACTIVITY
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Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-01HQ3EAK3R2GGSRHF0SFWQGR6E
- MLA
- Vanden Broeck, Sofie, et al. “Gold Complexes with Remote-Substituted Amino N-Heterocyclic Carbenes.” DALTON TRANSACTIONS, vol. 52, no. 29, 2023, pp. 9908–12, doi:10.1039/d3dt02086j.
- APA
- Vanden Broeck, S., Tzouras, N., Saab, M., Van Hecke, K., Dereli, B., Ritacco, I., … Cazin, C. (2023). Gold complexes with remote-substituted amino N-heterocyclic carbenes. DALTON TRANSACTIONS, 52(29), 9908–9912. https://doi.org/10.1039/d3dt02086j
- Chicago author-date
- Vanden Broeck, Sofie, Nikolaos Tzouras, Marina Saab, Kristof Van Hecke, Busra Dereli, Ida Ritacco, Luigi Cavallo, et al. 2023. “Gold Complexes with Remote-Substituted Amino N-Heterocyclic Carbenes.” DALTON TRANSACTIONS 52 (29): 9908–12. https://doi.org/10.1039/d3dt02086j.
- Chicago author-date (all authors)
- Vanden Broeck, Sofie, Nikolaos Tzouras, Marina Saab, Kristof Van Hecke, Busra Dereli, Ida Ritacco, Luigi Cavallo, Georgios C. C. Vougioukalakis, Pierre Braunstein, Steven Nolan, Andreas A. A. Danopoulos, and Catherine Cazin. 2023. “Gold Complexes with Remote-Substituted Amino N-Heterocyclic Carbenes.” DALTON TRANSACTIONS 52 (29): 9908–9912. doi:10.1039/d3dt02086j.
- Vancouver
- 1.Vanden Broeck S, Tzouras N, Saab M, Van Hecke K, Dereli B, Ritacco I, et al. Gold complexes with remote-substituted amino N-heterocyclic carbenes. DALTON TRANSACTIONS. 2023;52(29):9908–12.
- IEEE
- [1]S. Vanden Broeck et al., “Gold complexes with remote-substituted amino N-heterocyclic carbenes,” DALTON TRANSACTIONS, vol. 52, no. 29, pp. 9908–9912, 2023.
@article{01HQ3EAK3R2GGSRHF0SFWQGR6E,
abstract = {{The 4-RN-1,3-Ar-2-imidazolium salt, R = iPr, tBu, Ar = Mes, Dipp, Mes = mesityl, Dipp = 2,6-bis-diisopropyl-phenyl was metalated by Au-I at the C2-, C5- and 4-RN positions depending on the reactants and conditions employed; a rare direct rearrangement of a Au-I aminide to an abnormal imidazol-5-ylidene Au-I complex was also observed and based on a DFT study it may involve TfO- facilitated H+ transfer.}},
author = {{Vanden Broeck, Sofie and Tzouras, Nikolaos and Saab, Marina and Van Hecke, Kristof and Dereli, Busra and Ritacco, Ida and Cavallo, Luigi and Vougioukalakis, Georgios C. C. and Braunstein, Pierre and Nolan, Steven and Danopoulos, Andreas A. A. and Cazin, Catherine}},
issn = {{1477-9226}},
journal = {{DALTON TRANSACTIONS}},
keywords = {{REACTIVITY}},
language = {{eng}},
number = {{29}},
pages = {{9908--9912}},
title = {{Gold complexes with remote-substituted amino N-heterocyclic carbenes}},
url = {{http://doi.org/10.1039/d3dt02086j}},
volume = {{52}},
year = {{2023}},
}
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