Turning 3D covalent organic frameworks into luminescent ratiometric temperature sensors
- Author
- Laurens Bourda (UGent) , Anna Kaczmarek (UGent) , Min Peng (UGent) , Sonali Mohanty (UGent) , Hannes Rijckaert (UGent) , Pascal Van Der Voort (UGent) and Kristof Van Hecke (UGent)
- Organization
- Project
- Abstract
- In this study, we report hybrid crystalline lanthanide-containing 3D covalent organic framework (Ln@3D COF) materials that are suitablefor temperature sensing applications. Different routes to obtain thesehybrid materials were tested and compared for material quality andthermometric properties. In the first approach, a bipyridine-containing3D COF (Bipy COF) was grafted with a range of visible emitting lanthanide(Eu3+, Tb3+, Dy3+, and Eu3+/Tb3+) & beta;-diketonate complexes. In the second approach,a novel nanocomposite material was prepared by embedding NaYF4:Er,Yb nanoparticles on the surface of a nonfunctionalized3D COF (COF-300). To the best of our knowledge, the luminescent materialsdeveloped here are the first 3D COFs to be tested as ratiometric temperaturesensors. In fact, for the Bipy COF, two different types of thermometerswere tested (the Eu3+/Tb3+ system and a rareDy(3+) system), with both showing excellent temperature sensing properties. The reported NaYF4:Er,Yb/COF-300 nanocompositematerial combines upconverting nanoparticles with 3D COFs, similarto previously reported metal organic framework (MOF) nanocompositematerials; however, this type of hybrid material has not yet beenexplored for COFs. As such, our findings open a new pathway towardpotential multifunctional materials that can combine thermometry withother modalities, such as catalysis or drug delivery, in just onenanocomposite material.
- Keywords
- Covalent Organic Frameworks, Lanthanides, RatiometricThermometers, Upconverting Nanoparticles, Post-Modification, THERMOMETRY, CRYSTALLINE, CO2
Downloads
-
Ln@COF MS-7 KVH.pdf
- full text (Accepted manuscript)
- |
- open access
- |
- |
- 1.13 MB
-
(...).pdf
- full text (Published version)
- |
- UGent only
- |
- |
- 6.25 MB
Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-01H96KQK7ES7ZY99QH0D7X35WA
- MLA
- Bourda, Laurens, et al. “Turning 3D Covalent Organic Frameworks into Luminescent Ratiometric Temperature Sensors.” ACS APPLIED MATERIALS & INTERFACES, vol. 15, no. 31, 2023, pp. 37696–705, doi:10.1021/acsami.3c07544.
- APA
- Bourda, L., Kaczmarek, A., Peng, M., Mohanty, S., Rijckaert, H., Van Der Voort, P., & Van Hecke, K. (2023). Turning 3D covalent organic frameworks into luminescent ratiometric temperature sensors. ACS APPLIED MATERIALS & INTERFACES, 15(31), 37696–37705. https://doi.org/10.1021/acsami.3c07544
- Chicago author-date
- Bourda, Laurens, Anna Kaczmarek, Min Peng, Sonali Mohanty, Hannes Rijckaert, Pascal Van Der Voort, and Kristof Van Hecke. 2023. “Turning 3D Covalent Organic Frameworks into Luminescent Ratiometric Temperature Sensors.” ACS APPLIED MATERIALS & INTERFACES 15 (31): 37696–705. https://doi.org/10.1021/acsami.3c07544.
- Chicago author-date (all authors)
- Bourda, Laurens, Anna Kaczmarek, Min Peng, Sonali Mohanty, Hannes Rijckaert, Pascal Van Der Voort, and Kristof Van Hecke. 2023. “Turning 3D Covalent Organic Frameworks into Luminescent Ratiometric Temperature Sensors.” ACS APPLIED MATERIALS & INTERFACES 15 (31): 37696–37705. doi:10.1021/acsami.3c07544.
- Vancouver
- 1.Bourda L, Kaczmarek A, Peng M, Mohanty S, Rijckaert H, Van Der Voort P, et al. Turning 3D covalent organic frameworks into luminescent ratiometric temperature sensors. ACS APPLIED MATERIALS & INTERFACES. 2023;15(31):37696–705.
- IEEE
- [1]L. Bourda et al., “Turning 3D covalent organic frameworks into luminescent ratiometric temperature sensors,” ACS APPLIED MATERIALS & INTERFACES, vol. 15, no. 31, pp. 37696–37705, 2023.
@article{01H96KQK7ES7ZY99QH0D7X35WA,
abstract = {{In this study, we report hybrid crystalline lanthanide-containing 3D covalent organic framework (Ln@3D COF) materials that are suitablefor temperature sensing applications. Different routes to obtain thesehybrid materials were tested and compared for material quality andthermometric properties. In the first approach, a bipyridine-containing3D COF (Bipy COF) was grafted with a range of visible emitting lanthanide(Eu3+, Tb3+, Dy3+, and Eu3+/Tb3+) & beta;-diketonate complexes. In the second approach,a novel nanocomposite material was prepared by embedding NaYF4:Er,Yb nanoparticles on the surface of a nonfunctionalized3D COF (COF-300). To the best of our knowledge, the luminescent materialsdeveloped here are the first 3D COFs to be tested as ratiometric temperaturesensors. In fact, for the Bipy COF, two different types of thermometerswere tested (the Eu3+/Tb3+ system and a rareDy(3+) system), with both showing excellent temperature sensing properties. The reported NaYF4:Er,Yb/COF-300 nanocompositematerial combines upconverting nanoparticles with 3D COFs, similarto previously reported metal organic framework (MOF) nanocompositematerials; however, this type of hybrid material has not yet beenexplored for COFs. As such, our findings open a new pathway towardpotential multifunctional materials that can combine thermometry withother modalities, such as catalysis or drug delivery, in just onenanocomposite material.}},
author = {{Bourda, Laurens and Kaczmarek, Anna and Peng, Min and Mohanty, Sonali and Rijckaert, Hannes and Van Der Voort, Pascal and Van Hecke, Kristof}},
issn = {{1944-8244}},
journal = {{ACS APPLIED MATERIALS & INTERFACES}},
keywords = {{Covalent Organic Frameworks,Lanthanides,RatiometricThermometers,Upconverting Nanoparticles,Post-Modification,THERMOMETRY,CRYSTALLINE,CO2}},
language = {{eng}},
number = {{31}},
pages = {{37696--37705}},
title = {{Turning 3D covalent organic frameworks into luminescent ratiometric temperature sensors}},
url = {{http://doi.org/10.1021/acsami.3c07544}},
volume = {{15}},
year = {{2023}},
}
- Altmetric
- View in Altmetric
- Web of Science
- Times cited: