Project: Rationalizing dynamic nanoparticle restructuring as probed by advanced in situ X-ray scattering
2023-01-01 – 2026-12-31
- Abstract
Metal nanoparticle (NP) catalysts are the key enablers of durable chemical technologies, opening the road towards carbon circularity. The atomic structure of NPs, and in particular the surface configuration, governs reactivity where adding or removing a single atom can have profound impact. To date, however, state-of-the-art characterization tools do not allow facile investigation of the 3D NP structure under relevant (reaction) conditions. This impedes foundational understanding of NP formation and functioning, crucial to tailoring the properties and performance of metal catalysts. Herein, we will explore sophisticated X-ray characterization tools to gain access to the in situ/operando 3D NP structure under relevant gas conditions, both during NP formation and functioning.
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Exploring nucleation of ALD-fabricated Pt nanoparticles through X-ray total scattering
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Een Röntgen-vizier op katalysatoren
(2025) 18/02/2025. -
An X-ray lens on catalysts
(2025) -
- Journal Article
- A1
- open access
Selectively monitoring the operando temperature of active metal nanoparticles during catalytic reactions by X-ray absorption nanothermometry
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ALD-fabricated MgO-overcoats to control sintering of model Pt nanoparticle catalysts : the power of synchrotron X-ray scattering tools
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Operando monitoring the temperature of active metal nanoparticles during catalytic CO2 conversion
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Operando monitoring the temperature of active metal nanoparticles during catalytic CO2 conversion
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Chemical triggers behind Pt nanoparticle growth during post-deposition O2 annealing by in situ near-ambient pressure X-ray photoelectron spectroscopy
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- Journal Article
- A1
- open access
In vacuo XPS study on Pt growth by atomic layer deposition using MeCpPtMe3 and N2/NH3 plasma
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- Journal Article
- A1
- open access
Role of the oxidizing co-reactant in Pt growth by atomic layer deposition using MeCpPtMe3 and O2/O3/O2-plasma