Project: Circular Thermoset Materials: How to exploit Precision Engineered Macromolecules in their Bottom-up Design?
2021-11-01 – 2027-04-30
- Abstract
Polymers have revolutionised fields from aerospace and wind energy to food packaging and adhesives. When their end of life is reached, though, some are more challenging than others to deal with sustainably. Thermoplastic polymers like those used in plastic bottles are flexible and elastic (they have plasticity), and they are easily recyclable. Thermoset polymers become ‘set’ in place when heated and moulded – great for applications requiring strength, rigidity and structural integrity but a barrier to recycling. Covalent adaptable networks (CAN), polymer networks with reversible covalent crosslinks, could be the solution. The EU-funded CiMaC project is engineering novel CAN precursors that could overcome barriers and enhance control of CAN properties.
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- Journal Article
- A1
- open access
Low-viscosity, dynamic amidoamine hardeners with tunable curing kinetics for epoxy adhesives
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Scalable β-aminoester-based covalent adaptable networks for wind turbine blade composites
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- Journal Article
- A1
- open access
Eliminating creep in vitrimers using temperature-resilient siloxane exchange chemistry and N-heterocyclic carbenes
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- Journal Article
- A2
- open access
Debondable phenoxy-based structural adhesives with β-amino amide containing reversible crosslinkers
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- Journal Article
- A1
- open access
Taking dynamic covalent chemistry out of the lab and into reprocessable industrial thermosets
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Upscaling and applications of sequence-defined polymers using uniform soluble supports
(2025) -
Enabling the reprocessability and debonding of epoxy thermosets using dynamic poly(β-amino amide) curing agents
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- Journal Article
- A1
- open access
Activated phenyl ester vitrimers
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- Journal Article
- A1
- open access
Interlaminar fracture toughness behaviour of a repairable glass-fibre-reinforced vitrimer for wind-energy applications
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- Journal Article
- A1
- open access
Debondable epoxy-acrylate adhesives using β-amino ester chemistry