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Synthesis of 2-fluoro-1,4-benzoxazines and 2-fluoro-1,4-benzoxazepin-5-ones by exploring the nucleophilic vinylic substitution (SNV) reaction of gem-difluoroenamides
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Nucleophile-directed selective transformation of cis-1-tosyl-2-toxyloxymethyl-3-(trifluoromethyl)aziridine into aziridines, azetidines, and benzo-fused dithianes, oxathianes, dioxanes, and (thio)morpholines
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Synthesis of 1-alkyl-2-(trifluoromethyl)azetidines and their regiospecific ring opening toward diverse α-(trifluoromethyl)amines via intermediate azetidinium salts
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Synthesis of 2-aryl-3-hydroxymethyl-5,5-difluoropiperidines
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- Journal Article
- A1
- open access
Straightforward synthesis of 1-alkyl-2-(trifluoromethyl)aziridines starting from 1,1,1-trifluoroacetone
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Synthesis of 3-amino-4-fluoropyrazoles
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Synthesis of substituted β-carbolines via gold(III)-catalyzed cycloisomerization of N-propargylamides
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Improved Arndt-Eistert synthesis of alpha-diazoketones requiring minimal diazomethane in the presence of calcium oxide as acid scavenger
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Morpholinosulfur trifluoride (Morph-DAST)-mediated rearrangement in the fluorination of cyclic α,α-dialkoxy detones toward 1,2-dialkoxy-1,2-difluorinated compounds
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New synthesis of fluorinated pyrazoles